Herbicidal sulfonamides

ABSTRACT

Herbicidal sulfonamides having the general formula ##STR1## wherein J, W, R and A are more particularly described herein, such compounds and agricultural compositions containing them being useful as preemergent or postemergent herbicides or both, or as plant growth regulants, including the manner of their use.

CROSS-REFERENCE TO RELATED APPLICATION

This is a continuation-in-part of the application bearing U.S. Ser. No. 078,191 filed on July 27, 1987, now abandoned.

BACKGROUND OF THE INVENTION

The following publications disclose herbicidal sulfonylureas related to the sulfonamides of this invention in that substantially all disclosed compounds contain the characteristic sulfonylurea moiety. There are sufficient distinctions, however, to render these representative publications more useful as a backdrop against which to appreciate the instant invention rather than as suggestive of it.

    ______________________________________                                         U.S. 4,370,480       EP-A-79,772                                               U.S. 4,435,206       EP-A-87,780                                               U.S. 4,481,029       EP-A-95,925                                               U.S. 4,549,898       EP-A-126,711                                              U.S. 4,618,363       EP-A-203,825                                              U.S. 4,638,004       EP-A-245,058                                              U.S. 4,659,366       SA 85/2603                                                                     SA 83/3850.                                               ______________________________________                                    

SUMMARY OF THE INVENTION

This invention pertains to compounds of Formula I, including their agriculturally suitable salts, herbicidal compositions containing said compounds and use thereof as preemergent herbicides, postemergent herbicides and/or plant growth regulants. For the sake of brevity, the compounds will be described and claimed with respect to Formula I, it being understood that all salts are included as well. The compounds are: ##STR2## wherein J is selected from ##STR3## E is a single bond or --CH₂ --; Q¹ is --C(T¹)═N--O--Alk;

T¹ is selected from CN, F, Cl, Br, SCN, N₃, C₁ to C₂ alkoxy, C₁ to C₂ thioalkyl, NH(C₁ to C₂ alkyl), N(C₁ to C₂ alkyl)₂, N(OCH₃)CH₃ and N(CH₂)₃ or 4 ;

Alk is selected from C₁ to C₃ alkyl, optionally substituted with CN, OCH₃, SCH₃ or halogen; and CH₂ CH═CH₂ ;

Q² is --C(T²)═N--O--Alk;

T² is selected from H; C₁ to C₃ alkyl optionally substituted with CN, OCH₃, SCH₃ or halogen; cyclopropyl; F; Cl; Br; CN; SCN; N₃ ; C₁ to C₂ alkoxy; C₁ to C₂ thioalkyl; NH(C₁ to C₂ alkyl); N(C₁ to C₂ alkyl)₂ ; N(OCH₃)CH₃ and N(CH₂)₃ or 4 ;

R¹ is selected from H, C₁ to C₃ alkyl, C₁ to C₃ haloalkyl, halogen, CN, nitro, C₁ to C₃ alkoxy, C₁ to C₃ haloalkoxy, C₁ to C₃ alkylthio, C₁ to C₃ alkylsulfinyl, C₁ to C₃ alkylsulfonyl, SCF₂ H, NH₂, NHCH₃, N(CH₃)₂ or C₁ to C₂ alkyl substituted with one C₁ to C₂ alkoxy, C₁ to C₂ haloalkoxy, SH, SCH₃, CN or OH;

R² is selected from H, F, Cl, Br, C₁ to C₂ alkyl, C₁ to C₂ haloalkyl or C₁ to C₂ alkoxy;

R³ is selected from H, C₁ to C₃ alkyl, C₁ to C₂ haloalkyl, C₃ to C₄ alkenyl, C₃ to C₄ alkynyl, CH₂ CN, phenyl and phenyl substituted by F, Cl, CH₃ or OCH₃ ;

n is 0 or 1;

R is H or CH₃ ;

W is O or S;

A is selected from ##STR4## X is selected from H, C₁ to C₄ alkyl, C₁ to C₄ alkoxy, C₁ to C₄ haloalkoxy, C₁ to C₄ haloalkyl, C₁ to C₄ haloalkylthio, C₁ to C₄ alkylthio, halogen, C₂ to C₅ alkoxyalkyl, C₂ to C₅ alkoxyalkoxy, amino, C₁ to C₃ alkylamino, di(C₁ to C₃ alkyl)amino or C₃ to C₅ cycloalkyl;

Y is selected from H, C₁ to C₄ alkyl, C₁ to C₄ alkoxy, C₁ to C₄ haloalkoxy, C₁ to C₄ haloalkylthio, C₁ to C₄ alkylthio, C₂ to C₅ alkoxyalkyl, C₂ to C₅ alkoxyalkoxy, amino, C₁ to C₃ alkylamino, di(C₁ to C₃ alkyl)amino, C₃ to C₄ alkenyloxy, C₃ to C₄ alkynyloxy, C₂ to C₅ alkylthioalkyl, C₁ to C₄ haloalkyl, C₂ to C₄ alkynyl, azido, cyano, C₂ to C₅ alkylsulfinylalkyl, C₂ to C₅ alkylsulfonylalkyl, ##STR5## and N(OCH₃)CH₃ ; m is 2 or 3;

L₁ and L₂ are independently O or S;

R_(a) is H or C₁ to C₃ alkyl;

R_(b) and R_(c) are independently C₁ to C₃ alkyl;

Z is CH or N;

Z₁ is CH or N;

Y₁ is O or CH₂ ;

X₁ is CH₃, OCH₃ OC₂ H₅ or OCF₂ H;

X₂ is CH₃, C₂ H₅ or CH₂ CF₃ ;

Y₂ is OCH₃, OC₂ H₅, SCH₃, SC₂ H₅, CH₃ or CH₂ CH₃ ;

X₃ is CH₃ or OCH₃ ;

Y₃ is H or CH₃ ;

X₄ is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃ or Cl; and

Y₄ is CH₃, OCH₃, OC₂ H₅ or Cl; provided that

(i) when X is Cl, F, Br or I, then Z is CH and Y is OCH₃, OC₂ H₅, N(OCH₃)CH₃, NHCH₃, N(CH₃)₂ or OCF₂ H;

(ii) when X or Y is C₁ haloalkoxy, then Z is CH;

(iii) X₄ and Y₄ are not simultaneously Cl;

(iv) when W is S, then R is H, A is A-1 and Y is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, C₂ H₅, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH(OCH₃)₂ or 1,3-dioxolan-2-yl;

(v) when the total number of carbons of X and Y is greater than four, the number of carbon atoms of Q₁ or Q₂ is less than or equal to four;

(vi) when J is J-6, J-7, J-8 or J-9, and A is A-7, then Z₁ is CH; and

(vii) when J is J-6, J-7, J-8 or J-9, and A is A-1, and X and Y are haloalkoxy or haloalkylthio, then T² is F, Cl, Br, CN, SCN, N₃, C₁ to C₂ alkoxy, C₁ to C₂ thioalkyl, NH(C₁ to C₂ alkyl), N(C₁ to C₂ alkyl)₂, N(OCH₃)CH₃ or N(CH₂)₃ or 4.

In the above definitions, the term "alkyl", used either alone or in compound words such as "alkylthio" or "haloalkyl," denotes straight chain or branched alkyl, such as methyl, ethyl, n-propyl, isopropyl or the different butyl and pentyl isomers.

Alkoxy denotes methoxy, ethoxy, n-propyloxy, isopropyloxy and the different butyl isomers.

Alkenyl denotes straight chain or branched alkenes, such as 1-propenyl, 2-propenyl, 3-propenyl and the different butenyl and pentenyl isomers.

Alkynyl denotes straight chain or branched alkynes, such as ethynyl, 1-propynyl, 2-propynyl and the different butynyl and pentynyl isomers.

Alkylsulfonyl denotes methylsulfonyl, ethylsulfonyl and the different propylsulfonyl isomers.

Preferred Compounds A are compounds of Formula I wherein:

E is a single bond; and

W is O.

Preferred Compounds B are compounds of Formula I wherein:

E is CH₂ or J is J-6; and

W is O.

Preferred Compounds C are compounds A wherein:

R¹ is selected from H, F, Cl, Br, CH₂ CN, CH₃, OCH₃, SCH₃ or OCF₂ H;

R² is selected from H, F, Cl, Br or CH₃ ;

R³ is selected from H, C₁ to C₃ alkyl, phenyl, CH₂ CF₃ and CH₂ CH═CH₂ ;

X is selected from C₁ to C₂ alkyl, C₁ to C₂ alkoxy, Cl, F, Br, I, OCF₂ H, CH₂ F, CF₃, OCH₂ CH₂ F, OCH₂ CHF₂ OCH₂ CF₃, CH₂ Cl and CH₂ Br;

Y is selected from H, C₁ to C₂ alkyl, C₁ to C₂ alkoxy, CH₂ OCH₃ CH₂ OCH₂ CH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH₂ SCH₃, ##STR6## OCF₂ H, OCF₂ Br, SCF₂ H, cyclopropyl, C.tbd.CH or C.tbd.CCH₃ ; and

R_(b) and R_(c) are C₁ to C₂ alkyl.

Preferred Compounds D are compounds C wherein:

A is A-1;

n is O;

X is selected from CH₃, OCH₃, OCH₂ CH₃, Cl or OCF₂ H; and

Y is selected from CH₃, OCH₃, C₂ H₅, CH₂ OCH₃, NHCH₃, CH(OCH₃)₂ and cyclopropyl.

Preferred Compounds E are compounds D wherein:

R is H;

T¹ is selected from CN, Cl and C₁ to C₂ alkoxy; and

T² is selected from H, C₁ to C₃ alkyl, cyclopropyl, Cl, CN and C₁ to C₂ alkoxy.

Other preferred compounds are Compounds E wherein:

J is J-1 to J-5 and J-7 to J-13.

Specifically preferred compounds are:

2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-N-methoxybenzenecarboximidoyl chloride, Compound 28,

2-[(cyano)(methoxyimino)methyl]-N-[[(4-methoxy-6-methyl-2-pyrimidinyl)amino]carbonyl]benzenesulfonamide, Compound 2, and

N-methoxy-2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzenecarboximidoyl chloride, Compound 29.

DETAILS OF THE INVENTION

Compounds of Formula I are prepared by the methods shown below in Equations 1, 2, 3 and 4, wherein J, W, A and R are as previously defined. The method of choice for the individual compounds of Formula I will be readily apparent to those skilled in the art.

Equation 1 illustrates the reaction of sulfonamides II with the phenol ester of the appropriate carbamic acid or thiocarbamic acid of Formula III in the presence of a tertiary amine base such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). Similar coupling methods are described in EPA 70,804.

Equation 1 ##STR7##

The reaction of Equation 1 is best carried out at about -5° to 25° C. is an inert solvent such as dioxane or acetonitrile for 1 to 24 hours, optionally under an inert atmosphere and in the presence of an equimolar quantity of DBU. The desired products of Formula I can be conveniently isolated by acidifying the reaction solution with aqueous hydrochloric acid or acetic acid and filtration. Alternatively, the aqueous layer can be extracted with a solvent such as methylene chloride. Drying and evaporating the solvent affords the desired product.

The phenylcarbamate and phenylthiocarbamate intermediates of Formula III can be prepared by methods, or obvious modifications thereof, described in South African Patent Application 82/5671 and South African Patent Application 82/5045.

Equation 2 illustrates the reaction of sulfonylisocyanates and sulfonylisothiocyanates of Formula IV with the appropriate heterocyclic amines of Formula V.

Equation 2 ##STR8##

The reaction of Equation 2 is best carried out in an inert solvent such as methylene chloride, tetrahydrofuran, toluene or acetonitrile at a temperature between about 0° and 80° C. A catalytic amount of 1,4-diazabicyclo[2.2.2]octane (DABCO) can be used to accelerate the reaction. In cases where the products are insoluble in the reaction solvent, they can be isolated by simple filtration. Soluble products can be isolated by evaporation of the solvent and trituration of the residue with solvents such as 1-chlorobutane, diethyl ether or ethyl acetate, and filtration.

Sulfonyl isocyanates IV (W═O) can be prepared directly from the corresponding sulfonamides II according to the procedures described in Ulrich et al., Newer Methods of Preparative Organic Chemistry, Vol. VI, page 223 to 241, Academic Press, New York and London, W. Foerst Ed. By this two-step procedure, sulfonamides are converted to isolatable n-butylsulfonylureas which are reacted further with phosgene and a tertiary amine catalyst to form sulfonyl isocyanates. The analogous one-step procedure can be employed by using the method described in U.S. Pat. No. 4,238,621. Alternatively, sulfonamides can be reacted with thionyl chloride to form intermediate N-sulfinylsulfonamides, which upon exposure to phosgene in the presence of a catalytic amount of pyridine, provide sulfonyl isocyanates. For additional details, see Ulrich et al., J. Org. Chem., 34, pages 3200 to 3202 (1969).

Sulfonyl isothiocyanates (iv, w═s) are prepared from the corresponding sulfonamides by reaction with carbon disulfide and potassium hydroxide followed by treatment of the resulting dipotassium salt with phosgene. Such a procedure is described in Arch. Pharm., 299, 174 (1966).

Equation 3 illustrates the reaction of a sulfonyl carbamate or thiocarbamate of Formula VI with an appropriate heterocyclic amine V.

Equation 3 ##STR9##

The reaction of Equation 3 is carried out at about 20° to 100° C. in an inert solvent such as p-dioxane for 0.5 to 24 hours. Additional details concerning the general coupling reaction to prepare sulfonylureas can be found in EPA 44,807. The product is isolated by evaporation of the reaction solvent and purified by trituration of the residue with solvents such as 1-chlorobutane or ethyl ether, and filtration, or by chromatography procedures on silica gel.

Phenylcarbamates and phenylthiocarbamates of Formula VI are prepared by methods described, or obvious modifications thereof, in U.S. Pat. No. 4,443,243, EPA 44,808 or South African Patent Application 82/5042.

Equation 4 illustrates the reaction of sulfonamides of Formula Ia with appropriate salts or amines to form corresponding sulfonamides of Formula Ib.

Equation 4 ##STR10## wherein P is ##STR11## A, Alk, R and R₁ are as previously defined; M is Na⁺ or K⁺ ;

Ta is CN, SCN, N₃, C₁ to C₃ alkoxy, C₁ to C₂ thioalkyl, or F;

Tb is NH(C₁ to C₂ alkyl), N(C₁ to C₂ alkyl)₂, N(OCH₃)CH₃, or N(CH₂)₃ or 4 ; and

Tc is Ta or Tb.

The reaction of Equation 4 is effected by reacting Ia with at least one molar equivalent of salt M-Ta (at least two molar equivalents when Ta is an alkoxide or mercaptide) in an inert solvent such as acetone, methyl ethyl ketone, tetrahydrofuran, dioxane, methanol, dimethylformamide (DMF), dimethylsulfone or dimethylsulfoxide. The reaction is carried out at about 20° to 140° C. for 1 to 24 hours, and optionally in the presence of a phase transfer catalyst such as a crown ether. Products Ib (Tc is Ta) are isolated by addition of water, acidification if Ta is alkoxide or mercaptide, and filtration. Alternatively, the aqueous suspension is extracted with a solvent such as methylene chloride, dried and the solvent evaporated to yield crude Ib. Product Ib can be purified further by trituration with a solvent such as 1-chlorobutane, ethyl acetate or diethyl ether, and filtration, or by chromatography procedures on silica gel. Similarly, products Ib (Tc is Tb) can be prepared by reacting Ia with amines, H-Tb, preferably an excess of about 2 to 20 mole equivalents, in an inert solvent such as tetrahydrofuran, p-dioxane, methanol, methylene chloride or DMF. The reactions are carried out at about 0° C. to 100° C. for 1 to 24 hours. Work-up is as described above.

In analogous manner, other compounds of Formula I can be prepared using procedures described in Equation 4, from appropriate corresponding compounds of Formula I, wherein J is J₂ to J₁₃ and Q¹ or Q² is C(Cl)═NOAlk.

As illustrated in Equation 5, the intermediate sulfonamides of Formula II are conveniently prepared by amination of the corresponding sulfonyl chlorides with anhydrous ammonia or aqueous ammonium hydroxide by general methods known in the art, e.g., Crossley et al., J. Am. Chem. Soc., 60, pages 2223 to 2224 (1938); Pailer, Monatsh, 92, pages 677 to 683 (1961); and U.S. Pat. No. 4,511,392.

Equation 5 ##STR12##

As illustrated in Equation 6, sulfonamides of Formula II can also be prepared by deprotection of t-butylsulfonamides of Formula VIII.

Equation 6 ##STR13##

The reaction of Equation 6 is conveniently carried out in excess trifluoroacetic acid (TFA) according to the procedure of Catt et al., J. Org. Chem., 39, pages 566 to 568 (1974), or with polyphosphoric acid (PPA) according to procedures of Lomardino, J. Org. Chem., 36, pages 1843 to 1845 (1971). Alternatively, t-butylsulfonamide VIII can be treated with a catalytic amount of p-toluene sulfonic acid (p-TSA) in a solvent such as toluene or xylenes at reflux temperatures for 1 to 24 hours to yield II.

Intermediate sulfonyl chlorides of Formula VIIa are preferably prepared by oxidative-chlorination of an appropriate thioether of Formula IX, as shown below in Equation 7.

Equation 7 ##STR14## wherein J is as previously defined, E is a single bond, and R₄ is C₂ to C₃ alkyl or benzyl.

The reaction of Equation 7 is carried out by contacting a suspension of thioether IX in a solvent such as acetic or propionic acid in the presence of at least 2.5 equivalents of water and 3.0 equivalents of chlorine at about -20° to 30° C. for 0.2 to 5 hours. The reaction mixture is poured into ice-water and the product is isolated by filtration or extraction with a solvent such as methylene chloride. The extraction product is optionally washed with aqueous sodium bicarbonate until neutral or slightly basic to litmus, then dried, and the solvent is evaporated to yield a product sufficiently pure to be carried directly on to the next step.

Alternatively, reaction of thioether IX, wherein R₄ is benzyl or hydrogen, with a hypochlorite solution, i.e., NaOCl, can provide sulfonyl chloride VIIa. For additional details, see analogous reactions in South African Patent Application No. 84/8845 and 84/8844. Mercaptans or thioethers can also be transformed to sulfonyl fluorides by reaction with chlorine and potassium hydrogen difluoride, which on further reaction with ammonia or ammonium hydroxide can provide sulfonamides; see, e.g., Brown et al., J. Chem. Soc. Perkins Trans I, pages 522 to 527 (1972).

Sulfonyl chlorides, VIIa, can also be prepared by diazotization reactions, as illustrated in Equation 8.

Equation 8 ##STR15##

The amine hydrochloride salt is diazotized with an alkylnitrite in an organic solvent, such as acetonitrile or acetone, and the resulting diazonium salt is reacted with sulfur dioxide and cupric chloride to yield VIIa. Doyle, J. Org. Chem., 42, pages 2426 to 2431 (1977) and ibid, pages 2431 to 2436, describe conditions for analogous reactions. Alternatively, sulfonyl chlorides VIIa can be prepared by aqueous diazotization; for additional details, see EPA 83,975 and 85,476. Aromatic amines of Formual X can be prepared from the corresponding nitro compounds by various known reduction procedures, e.g., Preparative Organic Chemistry, 4 Ed., pages 557 to 563, John Wiley and Sons, New York and London, Hilgetag et al., Eds., and EPA 207,894.

Sulfonyl chlorides of Formula VIIb can be prepared from compounds of Formula XI as shown in Equation 9 and described in U.S. Pat. No. 4,420,325.

Equation 9 ##STR16## wherein J is as previously defined and [X] is a suitable halogenating agent, such as N-bromosuccinimide.

Thioethers of Formula IX are important intermediates for preparing compounds of this invention and can be prepared by a variety of general methods known in the art. Several such procedures are described below in Equations 10 through 15.

Equation 10 illustrates the preparation of thioethers of Formula IXa, containing an alpha-chlorooxime moiety, from carboxylic acids of Formula XII. Subsequent reaction of IXa with appropriate salts, M-Ta, or amines, H-Tb, provides thioethers of Formula IXb.

Equation 10 ##STR17## wherein R₁, R₄, Alk, M, Ta, Tb and Tc are as previously defined; and [X] is as defined below.

In Equation 10a, carboxylic acids XII are converted to acid chlorides which in turn are converted to isolatable N-alkoxyamides by known methods. Subsequent reaction of the amides with suitable halogenating agents, [X], provides compounds of Formula IXa. Suitable halogenating agents include phosphorous pentachloride or phosphorous pentabromide in an inert solvent such as benzene or chloroform at about 5° to 40° C. for 1 to 24 hours; or phosgene, preferably, or thionyl chloride and a catalytic amount of DMF in an inert solvent such as methylene chloride, benzene or chlorobenzene at about 10° to 130° C. for 0.5 to 24 hours; or more preferably equimolar amounts of triphenylphosphine and carbon tetrachloride (or carbon tetrabromide) in an inert solvent such as acetonitrile at about 0° C. to 80° C. for 1 to 24 hours. Compounds of Formula IXa are isolated by evaporation of reaction media under vacuum and can be purified by optionally treatment with water followed by chromatography procedures on silica gel.

The reactions of Equation 10b are carried out by the general procedures described in Equation 4.

Equation 11 illustrates the preparation of thioethers of Formula IXc, containing an alpha-cyanooxime moiety, from corresponding aldehydes of Formula XIII.

Equation 11 ##STR18## wherein R₁, R₄, M and Alk are as previously defined.

The reactions (1) to (4) of Equation 11 are carried out by generally known methods, to provide uncapped oximes of Formula IXc, wherein Alk is H. Subsequent reaction of the uncapped oximes by generally known methods with a suitable base and reagents, M-Alk, in an inert solvent provides capped oximes IXc. Suitable bases and solvents include potassium tert-butoxide in DMF or sodium methoxide in methanol. Reactions (4) and (5) of Equation 11 are further illustrated in Example 7.

In an analogous manner to reactions described in Equations 10 and 11, other thioethers of Formula IX can be prepared, wherein J is J₂ to J₁₃, by carrying out reactions on appropriate corresponding carboxylic acids or aldehydes.

Equation 12 illustrates the preparation of aldooximes and ketooximes of Formula IXd.

Equation 12 ##STR19## wherein: R₂, R₄ and Alk are as previously defined;

T_(d) is C₁ to C₃ alkyl, optionally substituted with OCH₃ or SCH₃ ; or cyclopropyl;

Td' is Td or CF₃, CF₂ CF₃, CF₂ CF₂ CF₃, or H;

T_(e) is T_(d) ' or CO₂ H; and

T_(e) ' is T_(d) '.

In Equation 12a, 2-fluoropyridine XIV is metallated with lithium diisopropyl amide (LDA) according to the procedure of Gungor, et al., J. Organomet. Chem., 215, pages 139 to 150 (1981), followed by treatment with an acid chloride or a N,N-dimethylamide (or carbon dioxide and H₃ O) by known methods to yield corresponding ketones or aldehydes (or carboxylic acids). In Equation 12b, reaction of halopyridine XV with an appropriate mercaptide in a solvent such as DMF yields the corresponding thioethers, which on reaction with an alkoxyamine by known methods yields compounds of Formula IXd. U.S. Pat. No. 4,456,469 discloses analogous halopyridine-mercaptide reactions.

Also, by known methods, aldo or keto-thioethers in Equation 12b can be reacted with hydroxylamine followed by a suitable base and an alkylating reagent, M-Alk, to provide capped oximes Ixd. Suitable bases and solvents are described in Equation 11. For details on the reaction of trifluoromethyl ketones with hydroxylamine see, for example, Rosenfeld, U.S. Pat. No. 3,748,361 and R. L. Salvador et al., J. Med. Chem., 15, pages 646 to 650 (1972).

Oximes of Formula IXd, wherein Te' is CH₂ CN, can be prepared in a two-step procedure from an appropriate 2-benzylthio-3-pyridyl-carboxylate ester using generally known methods. Thus, reaction of the ester with a suitable base such as sodium hydride and acetonitrile in an inert solvent such as tetrahydrofuran can provide the corresponding 3-ketoacetonitrile, which on subsequent reaction with an appropriate alkoxyamine, or more preferably, its hydrochloride salt, in an inert solvent such as methanol or DMF can provide IXd (Te' is CH₂ CN).

Pyridyl alkyl ketones described in Equations 12a and 12b can also be prepared by reaction of appropriate pyridyl acid chlorides with alkyl Grignard reagents. For details see, for example, Japanese Patent Application 60-253,531.

Marsais, et al., J. Orgmet. Chem., 216, pages 139 to 147 (1981) describes the preparation of 3,4 and 2,3-disubstituted pyridines by reacting 3-chloropyridine with, respectively, lithium dialkylamides in tetrahydrofuran or butyl lithium in diethyl ether. By reacting such lithium intermediates with reagents described in Equation 12a followed by Equation 12b, the corresponding 3,4- and 2,3-isomers of IXd can be obtained.

For further details pertaining to the synthesis of pyridines, see Beritmaier, et al., Tetrahedron, 26, 5907 (1970); Blank, et al., J. Med. Chem., 17, pages 1065 to 1071 (1974); Mallet, et al., Tetrahedron, 41, 3433 (1985); and Delarge, et al., Annales Pharm. France, 36, 369 (1978); and R. L. Salvador et al., Tetrahedron, 27, pages 1221 to 1226 (1971). The N-oxidation of pyridine sulfonamides of Formula II, wherein J is J-6 to J-9, is carried out according to known methods for the oxidation of pyridine compounds.

Equations 13 and 14 illustrate the preparation of thiophene carboxylic acids of Formula IXe and IXf. The acids can be used as intermediates for preparing compounds analogous to those described in Equation 10. Also, reduction of the acids or their esters can provide methyl alcohols for analogous reactions described in Equation 11.

Equation 13 ##STR20##

Equation 14 ##STR21##

In Equations 13 and 14, metal-halogen exchange or metallation with carbon dioxide or a disulfide by known methods provides carboxylic acids IXe and IXf. Starting with 3,4-dibromo-thiophene, and carrying out the reactions of Equation 13, can provide the 3,4-substituted isomer of acid IXe. Further details pertaining to the preparation and functional group manipulation of thiophenes are found in U.S. Pat. No. 4,481,029 and Knight, et al., J. Chem. Soc. Perkin Trans I, pages 791 to 794, (1983).

Equation 15 illustrates the preparation of some pyrazolethioethers of Formula IXg, which can undergo further reactions analogous to those described in Equations 10, 11 and 12.

Equation 15 ##STR22## wherein Tf is H, C₁ to C₃ alkyl, optionally substituted with OCH₃, SCH₃ or halogen; cyclopropyl, OH or OCH₃, and R₂, R₃ and R₄ are as previously defined.

The compounds of Formula XVI in Equation 15 are known or can be prepared by known methods; see, for example, Kviko et al., Zhurnal Org. Khimi, 5, pages 1685 to 1692 (1969); Koshelev et al., Ibid, 8, pages 1750 to 1754 (1972); and Japanese Patent Application 57-228261.

The t-butylsulfonamides of Formulas XIX, XXI and XXIII are useful intermediates for preparing compounds of this invention and they can be prepared by known methods or simple modifications thereof. Several such methods are illustrated in Equations 16, 17 and 18.

Equation 16 ##STR23## wherein Tf is as previously defined.

Preparation of intermediates such as bromide XVIII can be found in EPA 95,925. Exposure of bromide XVIII to BuL; followed by treatment with an appropriate acid chloride, DMF or carbon dioxide yields XIX.

Equation 17 ##STR24##

In Equation 17, the isomeric 5-keto-4-sulfonamide is prepared as outlined, while in Equation 18, the isomeric 4-keto-3-sulfonamide XXIII is prepared as outlined.

Equation 18 ##STR25##

Intermediate compounds of Formula XIX, XXI and XXIII in Equations 16, 17 and 18 can undergo further reactions analogous to those described in Equations 10, 11 and 12.

For further details pertaining to the synthesis of pyrazoles see, for example, EPA 87,780; South African Patent Application 833,350, EPA 95,925; and Jacobs, "Heterocycloc Compounds", Elderfield ed., Vol. 5, pages 45 to 161, Wiley, New York, 1957.

Chemical compatibility of the wide variety of reactions, reactants and reaction conditions described throughout this disclosure with respect to J, R₁ to R₃, Q₁ and Q₂ must be evaluated and judicious choices made; one skilled in the art, having this disclosure before him, will be able to readily make such evaluations and choices without undue difficulty. In addition, incompatibility can readily be avoided in certain instances by suitable selection of a protecting group as will be obvious to one skilled in the art. For a compilation of references describing the wide variety of such protecting groups available, see Greene et al., "Protective Groups in Organic Synthesis", John Wiley and Sons, Inc., New York, 1981.

The heterocyclic amines of Formula V in Equation 2 above can be prepared by methods known in the literature, or simple modifications thereof, by those skilled in the art. For instance, EPA 84,224 and Braker et al., J. Chem. Soc., 69, 3072 (1947), describe methods for preparing aminopyridines and triazines substituted by acetal groups such as dialkoxymethyl or 1,3-dioxolan-2-yl, among other groups. Also, South African Patent Application Nos. 82/5045 and 82/5671 describe methods for preparing aminopyrimidines and triazines substituted by haloalkyl or haloalkylthio groups such as OCH₂ CH₂ F, OCH₂ CF₃, SCF₂ H, and OCF₂ H. South African Patent Application 83/7434 describes methods for the synthesis of cyclopropylpyrimidines and triazines substituted by such groups as alkyl, haloalkyl, alkoxy, haloalkoxy, alkylamino, dialkylamino or alkoxyalkyl.

The 5,6-dihydrofuro[2,3-d]pyrimidine-2-amines, the cyclopenta[d]pyrimidines-2-amines (V, A is A-2) and the 6,7-dihydro-5H-pyrano[2,3-d]pyrimidin-2-amines (V, A is A-3) can be prepared as described in EPA 15,683. The furo[2,3-d]pyrimidin-2-amines (V, A is A-4) are described in EPA 46,677. Compounds of Formula V, where A is A-7, are described in EPA 125,864.

Compounds of Formula V, where A is A-5, are described in EPA 73,562. Compounds of Formula V where A is A-6, are described in EPA 94,260.

In addition, general methods for preparing aminopyrimidines and triazines have been reviewed in the following publications: "The Chemistry of Heterocyclic Compounds", a series published by Interscience Publ., New York and London; "Pyrimidines", Vol. 16 of the same series by Brown; "s-Triazines and Derivatives", Vol. 13 of the same series of Smolin et al.,; U.S. Pat. No. 3,154,547; and Huffman et al., J. Org. Chem., 28, pages 1812 to 1816 (1963), which describes the synthesis of triazines.

Agriculturally suitable salts of compounds of Formula I are also useful herbicides and can be prepared in a number of ways known to the art. For example, metal salts can be made by contacting compounds of Formula I with a solution of an alkali or alkaline earth metal salt having a sufficiently basic anion (e.g., hydroxide, alkoxide, or carbonate). Quaternary amine salts can be made by similar techniques.

Salts of compounds of Formula I can also be prepared by exchange of one cation for another. Cationic exchange can be effected by direct contact of an aqueous solution of a salt of a compound of Formula I (e.g., alkali or quaternary amine salt) with a solution containing the cation to be exchanged. This method is most effective when the desired salt containing the exchanged cation is insoluble in water and can be separated by filtration.

Exchange can also be effected by passing an aqueous solution of a salt of a compound of Formula I (e.g., an alkali metal or quaternary amine salt) through a column packed with a cation exchange resin containing the cation to be exchanged for that of the original salt and the desired product is eluted from the column. This method is particularly useful when the desired salt is water-soluble, e.g., a potassium, sodium or calcium salt.

Acid addition salts, useful in this invention, can be obtained by reacting a compound of Formula I with a suitable acid, e.g., p-toluenesulfonic acid, trichloroacetic acid or the like.

The preparation of the compounds of this invention is further illustrated by the following specific examples. Unless otherwise indicated, temperatures are in degrees Celsius.

EXAMPLE 1 N-Methoxy-2-[(phenylmethyl)thio]benzamide

A suspension of 100 g of 2-[(phenylmethyl)thio]benzoic acid and 97.6 g of thionyl chloride in 800 ml of benzene was refluxed for about three hours then evaporated to dryness under vacuum. The residue was triturated with hexane to yield 101.2 g of 2-[(phenylmethyl)thio]benzoyl chloride, m.p. 113° to 116° C.

To a suspension of 80.2 g of potassium carbonate in 500 ml of water and 200 ml of methylene chloride, cooled at less than 5° C. with external cooling, was added, portionwise, 48.2 of methoxylamine hydrochloride followed, after about 10 minutes, by the dropwise addition of 101 g of the above acid chloride dissolved in 700 ml of methylene chloride. After the suspension was stirred at 0° C. for one hour, then two hours without external cooling, the organic layer was separated, dried (MgSO₄), and evaporated to dryness under vacuum. The residue was recrystallized from 1-chlorobutane to yield 79 g of the subject compound, m.p. 100° to 105° C.

EXAMPLE 2 N-Methoxy-2-[(phenylmethyl)thio]benzene carboximidoyl chloride

To a suspension of 79 g of the product of Example 1 in 1500 ml of benzene under a N₂ atmosphere, cooled at 20° to 30° C. with external cooling, was added, portionwise, 60.2 g of phosphorous pentachloride. After stirring at 25° C. for about 24 hours, the suspension was warmed at 40° C. for about four hours, then cooled to 25° C. and filtered. The filtrate was evaporated at less than 40° C. under vacuum, and residue was chromatographed on silica gel with methylene chloride at eluant to yield 47 g of the subject compound as a crude yellow oil.

NMR(CDCl₃): ppm 4.15 (m, 3H, OCH₃) 4.6 (s, 2H, CH₂) 7.4 (m, 9H, Ar).

EXAMPLE 3 2-(Chlorosulfonyl)-N-methoxybenzenecarboximidoyl chloride

To a solution of 10 g of the product of Example 2 and 1.9 g of water in 125 ml of glacial acetic acid, cooled at about 13° C. with external cooling, was added, dropwise, 8.6 ml of chlorine. After stirring at 10° to 15° C. for one hour, the suspension was poured into excess ice-water, and the mixture was extracted with 1-chlorobutane. The extraction was washed with water, twice with saturated aqueous sodium bicarbonate, then again with water, then dried (MgSO₄) and evaporated at less than 40° C. under vacuum to yield the subject compound as a crude oil.

EXAMPLE 4 2-(Aminosulfonyl)-N-methoxybenzenecarboximidoyl chloride

To a solution of the oil prepared in Example 3 in 100 ml of tetrahydrofuran, cooled at -30° C. with external cooling, was added dropwise 1.7 ml of ammonia. After stirring at -30° C. for about 15 minutes, the suspension was purged with N₂ to remove excess ammonia, then evaporated at less than 30° C. under vacuum. After adding ice-water to the residue, the suspension was extracted with methylene chloride, dried (MgSO₄) and evaporated under vacuum. The residue was triturated with hexane to yield 2.5 g of the subject compound as a crude solid, m.p. 155° to 158° C., NMR(CDCl₃ +DMSO):

ppm 4.2 (s, 3H, OCH₃) 6.6 (bs, 2H, NH₂) 7.8 (m, 4H, Ar).

EXAMPLE 5 2-[[(4-Methoxy-6-methyl-2-pyrimidinyl)aminocarbonyl]aminosulfonyl]-N-methoxybenzenecarboximidoyl chloride

To a suspension of 0.4 g of the product of Example 4 and 0.46 g of phenyl(4-methoxy-6-methylpyrimidin-2-yl)carbamate in 10 ml of dry acetonitrile was added 0.25 g of DBU. The suspension was stirred for about two hours at room temperature, then diluted with excess water and filtered. The filtrate was acidified with concentrated hydrochloric acid to yield a precipitate. After filtration, the residue was washed with excess water and suction-dried to yield 0.35 g of the subject compound, m.p. 178° to 179° C.;

IR(Nujol): 1700 cm⁻¹ (C═O);

NMR(CDCl₃): PPM 2.4 (s, 3H, CH₃), 3.9 (s, 3H, OCH₃), 3.95 (s, 3H, NOCH₃), 6.3 (s, 1H, py-H), 7.3 (m, 1H, NH), 7.5 (m, 1H, Ar), 7.7 (m, 2H, Ar), 8.4 (m, 1H, Ar), 13.2 (bs, 1H, NH).

EXAMPLE 6 N-Methoxy-2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzenecarboximidoyl chloride

By the procedure of Example 5, 0.4 g of the product of Example 4 was reacted with 0.46 g of phenyl(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamate and 0.25 g of DBU. The resulting suspension was acidified, without prior filtration, with concentrated hydrochloric acid and filtered. The residue was washed with excess water and suction-dried to yield 0.45 g of the subject compound, m.p. 182° to 184° C.

IR(Nujol): 1700 cm⁻¹ (C═O)

NMR(CDCl₃): ppm 2.6 (s, 3H, CH₃), 3.95 (s, 3H, NOCH₃), 4.1 (s, 3H, OCH₃), 7.4 (bs, 1H, NH), 7.5 (m, 1H, Ar), 7.7 (m, 2H, Ar), 8.4 (m, 1H, Ar), 12.4 (bs, 1H, NH).

EXAMPLE 7 Alpha-(Methoxyimino)-2-[(phenylmethyl)thio]benzeneacetonitrile

A suspension of 41 g of 2-[(phenylmethyl)thio]benzeneacetonitrile and 9.4 g of sodium methoxide in 350 ml of methanol, under a N₂ atmosphere, was stirred at 25° C. for one hour, then refluxed one hour and cooled to 10° C. Then, n-butyl nitrite (17.7 g) was added dropwise and the suspension was stirred at about 25° C. for 16 hours, then evaporated under vacuum. Excess water was added to the residue and the emulsion was washed with methylene chloride to yield a 3-phase water-oil-methylene chloride mixture. The oil layer was separated and acidified in water with concentrated hydrochloric acid. The suspension was extracted with methylene chloride, dried (MgSO₄), and evaporated under vacuum to yield 26.9 g of crude alpha-(hydroxyimino)-2-[(phenylmethyl)thio]benzeneacetonitrile as an oil.

To 15 g of the above oil in 125 ml of DMF, under N₂, was added 6.6 of potassium tert-butoxide. After stirring for one hour, the suspension was heated at 50° C. for one hour, then 7.1 g of dimethyl sulfate was added dropwise at 40° C. The suspension was stirred at 25° C. overnight, diluted with excess water, extracted with diethyl ether, and the extracts dried (MgSO₄) and evaporated under vacuum. The residue was chromatographed on silica gel with methylene chloride to yield 13 g of the subject compound as an oil.

NMR(CDCl₃): ppm 4.0-4.2 (m, 5H, OCH₃, CH₂) 7.4 (m, 9H, Ar).

EXAMPLE 8 2-[Cyano(methoxyimino)methyl]benzenesulfonamide

By the procedure of Example 3, 11 g of the product of Example 7 was reacted with 2.2 g of water and 9.9 ml of chlorine in 125 ml of glacial acetic acid. After work-up, 2-[cyano(methoxyimino)methyl]benzenesulfonyl chloride was obtained as a crude oil.

By the procedure of Example 4, all of the above oil was reacted with 1.7 ml of ammonia in 100 ml of tetrahydrofuran. Following work-up, the residue was triturated with hexane and recrystallized from 1-chlorobutane to yield 2 g of the subject compound; m.p. 82° to 90° C.;

NMR(CDCl₃): ppm 4.3 (s, 3H, OCH₃), 5.4 (bs, 2H, NH₂), 7.7 (m, 3H, Ar), 8.2 (m, 1H, Ar).

EXAMPLE 9 2-[(Cyano)(methoxyimino)methyl]-N-[[4,6-dimethoxy-1,3,5-triazin-2-yl)amino]carbonyl]benzenesulfonamide

By the procedure of Example 5, 0.4 g of the product of Example 8 was reacted with 0.51 g of phenyl(4,6-dimethoxy-1,3,5-triazin-2-yl)carbamate and 0.28 g of DBU in 10 ml of dry acetonitrile to yield 0.6 g of the subject compound; m.p. 191° to 194° C.

IR(Nujol): 1710 cm⁻¹ (C═O).

NMR(CDCl₃): ppm 4.1 (s, 6H, OCH₃), 4.2 (s, 3H, NOCH₃), 7.4 (bs, 1H, NH), 7.6 (m, 1H, Ar), 7.8 (m, 2H, Ar), 8.5 (m, 1H, Ar), 12.3 (bs, 1H, NH).

Using the techniques described in Equations 1 through 18 and Examples 5, 6 and 9, or simple modifications thereof, the following compounds in Tables 1 through 9 can be made.

    ______________________________________                                         General Formulas for Tables 1 to 9                                             ______________________________________                                         General Formula 1                                                                             ##STR26##                                                       General Formula 2                                                                             ##STR27##                                                       General Formula 3                                                                             ##STR28##                                                       General Formula 4                                                                             ##STR29##                                                       General Formula 5                                                                             ##STR30##                                                       General Formula 6                                                                             ##STR31##                                                       General Formula 7                                                                             ##STR32##                                                       General Formula 8                                                                             ##STR33##                                                       General Formula 9                                                                             ##STR34##                                                       ______________________________________                                    

                                      TABLE 1                                      __________________________________________________________________________     General Formula 1                                                              J          E  R  R.sup.1 /R.sup.2                                                                    T.sup.1 /T.sup.2                                                                        Alk     X       Y                               __________________________________________________________________________     J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    Cl       CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               Br      OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               H       CH.sub.3                        J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              H                               J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OC.sub.2 H.sub.5       J-1        -- H  H    Cl       CH.sub.3                                                                               OCF.sub.2 H                                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              CH(OCH.sub.3).sub.2             J-1        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               OC.sub.2 H.sub.5                J-1        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       CH.sub.3                                                                               C.sub.2 H.sub.5                                                                        OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OC.sub.2 H.sub.5                                                                       OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               CF.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               CH.sub.2 F                                                                             OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               CH.sub.2 Cl                                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               CH.sub.2 Br                                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               F       OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               I       OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.2 CH.sub.2 F                                                                   OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.2 CH.sub.2 CF.sub.3                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.2 CHF.sub.2                                                                    CH.sub.3                        J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     CH.sub.3                        J-1        -- H  H    Cl       CH.sub.3                                                                               Cl      OC.sub.2 H.sub.5                J-1        -- H  H    Cl       CH.sub.3                                                                               OC.sub. 2 H.sub.5                                                                      NCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 SCH.sub.3              J-1        -- H  H    Cl       CH.sub.3                                                                               OCF.sub.2 H                                                                            CH.sub.3                        J-1        -- H  H    Cl       CH.sub.3                                                                               Cl      OCF.sub.2 H                     J-1        CH.sub.2                                                                          H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        CH.sub.2                                                                          H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        Cl      OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        Br      OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               H                               J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              H                               J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              CH.sub.2 OC.sub.2 H.sub.5       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCF.sub.2 H                                                                            OCH.sub.3                       J-1        -- H  H    Cl       C.sub. 2 H.sub.5                                                                       OCH.sub.3                                                                              CH(OCH.sub.3).sub.2             J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OC.sub.2 H.sub.5                J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              C.sub.2 H.sub.5                 J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OC.sub.2 5                                                                             OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.2 CF.sub.3                                                                     OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CF.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.2 F                                                                             OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.2 Cl                                                                            OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        CH.sub.2 Br                                                                            OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        F       OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        I       OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.2 CH.sub.                                                                      OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.2 CH.sub.2 CF.sub.3                                                            OCH.sub.3                       J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.2 CHF.sub.2                                                                    CH.sub.3                        J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.2 CF.sub.3                                                                     CH.sub.3                        J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        Cl      OC.sub.2 H.sub.5                J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OC.sub.2 H.sub.5                                                                       NHCH.sub.3                      J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              CH.sub.2 SCH.sub.3              J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        OCF.sub.2 H                                                                            CH.sub.3                        J-1        -- H  H    Cl       C.sub.2 H.sub.5                                                                        Cl      OCF.sub.2 H                     J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      Cl      OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      Br      OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               H                               J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              H                               J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              CH.sub.2 OC.sub.2 H.sub.5       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCF.sub.2 H                                                                            OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              CH(OCH.sub.3).sub.2             J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               OC.sub.2 H.sub.5                J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              C.sub.2 H.sub.5                 J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OC.sub.2 H.sub.5                                                                       OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.2 CF.sub.3                                                                     OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CF.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.2 F                                                                             OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.2 Cl                                                                            OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      CH.sub.2 Br                                                                            OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      F       OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      I       OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.2 CH.sub.2 F                                                                   OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.2 CH.sub.2 CF.sub.3                                                            OCH.sub.3                       J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.2 CHF.sub.2                                                                    CH.sub.3                        J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.2 CF.sub.3                                                                     CH.sub.3                        J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      Cl      OC.sub.2 H.sub.5                J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OC.sub.2 H.sub.5                                                                       NHCH.sub.3                      J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              CH.sub.2 SCH.sub.3              J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      OCF.sub.2 H                                                                            CH.sub.3                        J-1        -- H  H    Cl       n-C.sub.3 H.sub.7                                                                      Cl      OCF.sub.2 H                     J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     Cl      OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     Br      OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               H                               J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              H                               J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              CH.sub.2 OC.sub.2 H.sub.5       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCF.sub.2 H                                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              CH(OCH.sub.3).sub.2             J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               OC.sub.2 H.sub.5                J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              CH.sub.2 OCH.sub.3              J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              C.sub. 2 H.sub.5                J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OC.sub.2 H.sub.5                                                                       OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.2 CF.sub.3                                                                     OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CF.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.2 F                                                                             OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.2 Cl                                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     CH.sub.2 Br                                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     F       OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     I       OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.2 CH.sub.2 F                                                                   OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.2 CH.sub.2 CF.sub.3                                                            OCH.sub.3                       J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.2 CHF.sub.2                                                                    CH.sub.3                        J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.2 CF.sub.3                                                                     CH.sub.3                        J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     Cl      OC.sub.2 H.sub.5                J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OC.sub.2 H.sub.5                                                                       NHCH.sub.3                      J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              CH.sub.2 SCH.sub.3              J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     OCF.sub.2                                                                              CH.sub.3                        J-1        -- H  H    Cl       CH(CH.sub.3).sub.2                                                                     Cl      OCF.sub.2 H                     J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    CN       CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               Br      OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               H                               J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              H                               J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OC.sub.2 H.sub.5       J-1        -- H  H    CN       CH.sub.3                                                                               OCF.sub.2 H                                                                            OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              CH(OCH.sub.2).sub.2             J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               OC.sub.2 H.sub.5                J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.2 OCH.sub.3              J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OCH.sub.3              J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              C.sub.2 H.sub.5                 J-1        -- H  H    CN       CH.sub.3                                                                               OC.sub.2 H.sub.5                                                                       OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               CF.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.2 F                                                                             OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.2 Cl                                                                            OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               CH.sub.2 Br                                                                            OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               F       OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               I       OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.2 CH.sub.2 F                                                                   OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.2 CH.sub.2 CF.sub.3                                                            OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.2 CHF.sub.2                                                                    CH.sub.3                        J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     CH.sub. 3                       J-1        -- H  H    CN       CH.sub.3                                                                               Cl      OC.sub.2 H.sub.5                J-1        -- H  H    CN       CH.sub.3                                                                               OC.sub.2 H.sub.5                                                                       NHCH.sub.3                      J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 SCH.sub.3              J-1        -- H  H    CN       CH.sub.3                                                                               OCF.sub.2                                                                              CH.sub.3                        J-1        -- H  H    CN       CH.sub.3                                                                               Cl      OCF.sub.2 H                     J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               Br      OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               H                               J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              H                               J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OC.sub.2 H.sub.5       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCF.sub.2 H                                                                            OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              CH(OCH.sub.2).sub.2             J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               OC.sub.2 H.sub.5                J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.2 OCH.sub.3              J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OCH.sub.3              J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              C.sub.2 H.sub.5                 J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OC.sub.2 H.sub.5                                                                       OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CF.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.2 F                                                                             OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.2 Cl                                                                            OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.2 Br                                                                            OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               F       OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               I       OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.2 CH.sub.2 F                                                                   OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.2 CH.sub.2 CF.sub.3                                                            OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.2 CHF.sub.2                                                                    CH.sub.3                        J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     CH.sub.3                        J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               Cl      OC.sub.2 H.sub.5                J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OC.sub.2 H.sub.5                                                                       NHCH.sub.3                      J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 SCH.sub.3              J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCF.sub.2 H                                                                            CH.sub.3                        J-1        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               Cl      OCF.sub.2 H                     J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               Br      OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               H                               J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              H                               J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OC.sub.2 H.sub.5       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCF.sub.2 H                                                                            OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              CH(OCH.sub.2).sub.2             J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               OC.sub.2 H.sub.5                J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.2 OCH.sub.3              J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 OCH.sub.3              J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              C.sub.2 H.sub.5                 J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OC.sub.2 H.sub.5                                                                       OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CF.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.2 F                                                                             OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.2 Cl                                                                            OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.2 Br                                                                            OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               F       OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               I       OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.2 CH.sub.2 F                                                                   OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.2 CH.sub.2 CF.sub.3                                                            OCH.sub.3                       J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.2 CHF.sub.2                                                                    CH.sub.3                        J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                     CH.sub.3                        J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               Cl      OC.sub.2 H.sub.5                J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OC.sub.2 H.sub.5                                                                       NHCH.sub.3                      J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              CH.sub.2 SCH.sub.3              J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCF.sub.2                                                                              CH.sub.3                        J-1        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               Cl      OCF.sub.2 H                     J-1        -- H  H    CN       C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    CN       C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    CN       C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    CN       C.sub.2 H.sub.5                                                                        Cl      OCH.sub.3                       J-1        -- H  H    CN       n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    CN       n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    CN       n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    CN       n-C.sub.3 H.sub.7                                                                      Cl      OCH.sub.3                       J-1        -- H  H    CN       CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    CN       CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    CN       CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    CN       CH(CH.sub.3).sub.2                                                                     Cl      OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OCH.sub.3                                                                               C.sub.2 H.sub.5                                                                        Cl      OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                                -n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                                -n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                                -n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OCH.sub.3                                                                                -n-C.sub.3 H.sub.7                                                                    Cl      OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                               CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OCH.sub.3                                                                               CH(CH.sub.3).sub.2                                                                     Cl      OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               Cl      OCH.sub. 3                      J-1        -- H  H    OC.sub.2 H.sub.5                                                                        C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OC.sub.2 H.sub.5                                                                         -n-C.sub.3 H.sub.7                                                                    Cl      OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                         -n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OC.sub.3 H.sub.5                                                                         -n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OCH.sub.3                                                                                -n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH(CH.sub.3).sub.2                                                                     Cl      OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    OC.sub.2 H.sub.5                                                                        CH(CH.sub.3).sub.2                                                                     Cl      OCH.sub.3                       J-1        -- H  H    SCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    SCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    SCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    SCH.sub.3                                                                               CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    SC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    SC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    SC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    SC.sub.2 H.sub.5                                                                        CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    SCN      CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    Br       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    N.sub.3  CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    NHCH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    NHC.sub.2 H.sub.5                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    N(CH.sub.3)C.sub.2 H.sub.5                                                              CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    N(C.sub.2 H.sub.5).sub. 2                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    N(OCH.sub.3)CH.sub.3                                                                    CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    N(OCH.sub.3)CH.sub.3                                                                    CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    N(OCH.sub.3)CH.sub.3                                                                    CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    N(OCH.sub.3)CH.sub.3                                                                    CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    N(CH.sub.2).sub.3                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    N(CH.sub.2).sub.4                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-7        -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    H        CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    H        CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    H        CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    H        C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    H        C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    H        C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    H        C.sub.2 H.sub.5                                                                        Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    H         -n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    H        CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    C.sub.2 H.sub.5                                                                         CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H     -n-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH(CH.sub.3).sub.2                                                                      CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    cyclopropyl                                                                             CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    cyclopropyl                                                                             CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    cyclopropyl                                                                             CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    cyclopropyl                                                                             CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    Cl       CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CN       CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=1)                                                                          J-7        -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=1)                                                                          J-2        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-2        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-2        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-2        -- H  H    Cl       CH.sub.3                                                                               Cl      OCH.sub.3                       J-2        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-2        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-2        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-2        -- H  H    CN       CH.sub.3                                                                               Cl      OCH.sub.3                       J-2        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-2        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-2        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-2        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               Cl      OCH.sub.3                       J-2        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-2        -- H  H    N(CH.sub.3).sub. 2                                                                      CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-2        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-2        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               Cl      OCH.sub.3                       J-3        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-3        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-3        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-3        -- H  H    Cl       CH.sub.3                                                                               Cl      OCH.sub.3                       J-3        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-3        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-3        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-3        -- H  H    CN       CH.sub.3                                                                               Cl      OCH.sub.3                       J-3        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-3        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-3        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-3        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               Cl      OCH.sub.3                       J-3        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-3        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-3        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-3        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               Cl      OCH.sub.3                       J-4        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-4        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-4        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-4        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-5        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-5        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-5        -- H  H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-5        -- H  H    Cl       CH.sub.3                                                                               Cl      OCH.sub.3                       J-5        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-5        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-5        -- H  H    CN       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-5        -- H  H    CN       CH.sub.3                                                                               Cl      OCH.sub.3                       J-5        -- H  H    OCH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-5        -- H  H    N(CH.sub.3).sub.2                                                                       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-6        -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-6        -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=1)                                                                          J-8        -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-8        -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=1)                                                                          J-9        -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-10       -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-10       -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-10       -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-11       -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-11       -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-11       -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-12       -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-12       -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-12       -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-13       -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-13       -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-13       -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-12       -- H  CH.sub.3                                                                            H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =C.sub.2 H.sub.5)                                                     J-11       -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH(CH.sub.3).sub.2                                                   J-10       -- H  H    cyclopropyl                                                                             CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 = -n-C.sub.3 H.sub.7)                                                 J-12       -- H  CH.sub.3                                                                            H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =C.sub.6 H.sub.5)                                                     J-11       -- H  H    CH.sub.3 CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.2 CF.sub.3)                                                   J-12       -- H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.2 CH═CH.sub.2)                                            J-1        -- H  H    Cl       CH.sub.3                                                                               NH.sub.2                                                                               OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               n-C.sub.3 H.sub.7                                                                      OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               NHCH.sub.3                                                                             OCH.sub.3                       J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              SCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              SCF.sub.2 H                     J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.2 C.tbd.CH              J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.2 CH=CH.sub.2           J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              C.tbd.CH                        J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              N(CH.sub.3).sub.2               J-7        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              cyclopropyl                     (n=0)                                                                          J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              NH.sub.2                        J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              CF.sub.3                        J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.2 CH.sub.2                                                             OCH.sub.3                       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub. 3                                                                             CH.sub.2 SCH.sub.3              J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              CHO                             J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              COCH.sub.3                      J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              CH(SCH.sub.3)OC.sub.2                                                          H.sub.5                         J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              C(CH.sub.3)SCH.sub.3).sub.2                                                    1                               J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              C(SC.sub.2 H.sub.5).sub.2       J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              1,3-dioxolan-2-yl               J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              2-methyl-1,3-                                                                  oxathiolan-2-yl                 J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              1,3-oxathian-2-yl               J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              2-methyl-1,3-                                                                  dithian-2-yl                    J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              4-methyl-1,3-                                                                  dioxolan-2-yl                   J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              2-4-dimethyl-1,3-                                                              dithiolan-2-yl                  J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              N(OCH.sub.3)(CH.sub.3)          J-1        -- H  H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              C.tbd. CCH.sub.3                J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              C.sub.2 H.sub.5                 J-1        -- H  H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCF.sub.2 Br                    J-7        -- H  6-F  H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-1        -- H  5-F  Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  6-Cl Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-2        -- H  4-Cl Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-7        -- H  6-Br H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-1        -- H  5-Br Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-3        -- H  4-CH.sub.3                                                                          H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-12       -- H  3-CH.sub.3                                                                          H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-1        -- H  5-CH.sub.2 CN                                                                       Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  5-OCH.sub.3                                                                         Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  5-SCH.sub.3                                                                         Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-12       -- H  3-CH.sub.3                                                                          H        CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-12       -- H  3-CH.sub.3                                                                          H        CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (R.sub.3 =CH.sub.3)                                                            J-12       -- H  3-CH.sub.3                                                                          H        CH.sub.3                                                                               Cl      OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-1        -- H  5-OCF.sub.2 H                                                                       Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-7        CH.sub.2                                                                          H  H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-1        -- CH.sub.3                                                                          H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- CH.sub.3                                                                          H    Cl       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- CH.sub.3                                                                          H    CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- CH.sub.3                                                                          H    CN       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-2        -- CH.sub.3                                                                          H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-3        -- CH.sub.3                                                                          H    Cl       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-7        -- CH.sub.3                                                                          H    H        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-1        -- H  6-Cl CN       CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  6-Cl CN       CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  6-Cl CN       CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  6-Cl CN       CH.sub.3                                                                               Cl      OCH.sub.3                       J-7        -- H  H    CF.sub.3 CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CH.sub.3                                                                      OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CH.sub.3                                                                      CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CH.sub.3                                                                      CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CH.sub.3                                                                      Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CF.sub.3 n-C.sub.3 H.sub.7                                                                      Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH(CH.sub.3).sub.2                                                                     Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CN                                                                            OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CN                                                                            CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CN                                                                            CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 CN                                                                            Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 OCH.sub.3                                                                     OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 OCH.sub.3                                                                     CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 OCH.sub.3                                                                     CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CF.sub.3 CH.sub.2 OCH.sub.3                                                                     Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CF.sub.3 CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CF.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CF.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CF.sub.3 CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 CN                                                                             CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 OCH.sub.3                                                                      CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 OCH.sub.3                                                                      CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 OCH.sub.3                                                                      CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CH.sub.2 OCH.sub.3                                                                      CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-12       -- H  H    CH.sub.2 SCH.sub.3                                                                      CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-11       -- H  H    CH.sub.3 CH.sub.2 SCH.sub.3                                                                     OCH.sub.3                                                                              OCH.sub.3                       (R.sub.3 =CH.sub.3)                                                            J-7        -- H  H    F        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    F        CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    F        CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    F        CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH.sub. 3                                                                              Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 C.sub.2 H.sub.5                                                                        CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CH.sub.3 C.sub.2 H.sub.5                                                                        Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 C.sub.2 H.sub.5                                                                        Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 n-C.sub.3 H.sub.7                                                                      OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                               CH.sub.3                        (n= 0)                                                                         J-7        -- H  H    CH.sub.3 n-C.sub.3 H.sub.7                                                                      Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH(CH.sub.3).sub.2                                                                     OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH(CH.sub.3).sub.2                                                                     Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-1        -- H  H    F        CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    F        CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       J-1        -- H  H    F        CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        J-1        -- H  H    F        CH.sub.3                                                                               Cl      OCH.sub.3                       J-1        -- H  H    CN       CH.sub.2 CN                                                                            OCH.sub.3                                                                              OCH.sub.3                       J-1        -- H  H    CN       CH.sub.2 OCH.sub.3                                                                     OCH.sub.3                                                                              OCH.sub.3                       J-7        -- H  H    CH.sub.3 CH.sub.2 CH.sub.2 CN                                                                   OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH.sub.2 CH.sub.2 OCH.sub.3                                                            OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.3 CH.sub.2 (CH.sub.2).sub.2 CN                                                           OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 (CH.sub.2).sub.2 OCH.sub.3                                                     CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CH.sub.3 CH.sub.3                                                                               OCH.sub.3                                                                              OCH.sub.3                       (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CH.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CH.sub.3 CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- CH.sub.3                                                                          H    CH.sub.3 CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 CN                                                                             CH.sub.3                                                                               CH.sub.3                                                                               OCH.sub.3                       (n=0)                                                                          J-7        -- H  H    CH.sub.2 CN                                                                             CH.sub.3                                                                               CH.sub.3                                                                               CH.sub.3                        (n=0)                                                                          J-7        -- H  H    CH.sub.2 CN                                                                             CH.sub.3                                                                               Cl      OCH.sub.3                       (n=0)                                                                          __________________________________________________________________________

                                      TABLE 2                                      __________________________________________________________________________     General Formula 2                                                              J          E  R  R.sup.1 /R.sup.2                                                                    T.sup.1 /T.sup.2                                                                       Alk   X      Y                                   __________________________________________________________________________     J-1        -- H  H    Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    Cl      C.sub.2 H.sub.5                                                                      CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    Cl      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    Cl      C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    Cl      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    Cl      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    Cl      n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    Cl      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    Cl      n-C.sub.3 H.sub.7                                                                    OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    Cl      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    Cl      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    Cl      CH(CH.sub.3).sub.2                                                                   CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    Cl      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    Cl      CH(CH.sub.3).sub.2                                                                   OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    Cl      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    Cl      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        CH.sub.2                                                                          H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- CH.sub.3                                                                          H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- CH.sub.3                                                                          H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    CN      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    CN      CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    CN      C.sub.2 H.sub.5                                                                      CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    CN      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    CN      C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    CN      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    CN      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    CN      n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    CN      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    CN      n-C.sub.3 H.sub.7                                                                    OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    CN      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    CN      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    CN      CH(CH.sub.3).sub.2                                                                   CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    CN      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    CN      CH(CH.sub.3).sub.2                                                                   OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    CN      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    CN      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        CH.sub.2                                                                          H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- CH.sub.3                                                                          H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- CH.sub.3                                                                          H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    N(CH.sub.3).sub. 2                                                                     C.sub.2 H.sub.5                                                                      CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    N(CH.sub.3).sub.2                                                                      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    N(CH.sub.3).sub.2                                                                      C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    N(CH.sub.3).sub.2                                                                      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    N(CH.sub.3).sub.2                                                                      C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    N(CH.sub.3).sub.2                                                                      n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    N(CH.sub.3).sub.2                                                                      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    N(CH.sub.3).sub.2                                                                      n-C.sub.3 H.sub.7                                                                    OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    N(CH.sub.3).sub.2                                                                      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    N(CH.sub.3).sub.2                                                                      n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH(CH.sub.3).sub.2                                                                   CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    N(CH.sub.3 ).sub.2                                                                     CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH(CH.sub.3).sub.2                                                                   OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    N(CH.sub.3).sub.2                                                                      CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        CH.sub.2                                                                          H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- CH.sub.3                                                                          H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- CH.sub.3                                                                          H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    OCH.sub.3                                                                              C.sub.2 H.sub.5                                                                      CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    OCH.sub.3                                                                              C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    OCH.sub.3                                                                              C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             NCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              n-C.sub.3 H.sub.7                                                                    OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    OCH.sub.3                                                                              n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    OCH.sub.3                                                                              n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        -- H  H    OCH.sub.3                                                                              CH(CH.sub.3).sub.2                                                                   CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    OCH.sub.3                                                                              CH(CH.sub.3).sub.2                                                                   OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    OCH.sub.3                                                                              CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(OCH.sub.3)(CH.sub.3)              J-1        -- H  H    OCH.sub.3                                                                              CH(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                             N(CH.sub.3).sub.2                   J-1        CH.sub.2                                                                          H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- CH.sub.3                                                                          H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- CH.sub.3                                                                          H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    OC.sub.2 H.sub.5                                                                       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    OC.sub.2 H.sub.5                                                                       CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    OC.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    OC.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    Br      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    SCN     CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    SCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    SCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    SC.sub.2 H.sub.5                                                                       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub. 3                           J-1        -- H  H    NHCH.sub.3                                                                             CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    NHC.sub.2 H.sub.5                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    N(CH.sub.3)C.sub.2 H.sub.5                                                             CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    N(C.sub.2 H.sub.5).sub.2                                                               CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    N(OCH.sub.3)(CH.sub.3)                                                                 CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-1        -- H  H    N(OCH.sub.3)(CH.sub.3)                                                                 CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  H    N(CH.sub.2).sub.3                                                                      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    N(CH.sub.2).sub.4                                                                      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    N.sub.3 CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-7        -- H  H    H       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-7        -- H  H    H       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-7        -- H  H    H       CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          (n = 0)                                                                        J-7        -- H  H    CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub. 3                           (n = 0)                                                                        J-7        -- H  H    C.sub.2 H.sub.5                                                                        CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-7        -- H  H    CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-7        -- H  H    cyclopropyl                                                                            CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-2        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-2        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-2        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-2        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-2        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-2        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-2        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-2        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-3        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-3        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-3        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-3        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-3        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-3        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-3        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-3        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-4        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-4        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-4        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-4        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-4        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-4        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-4        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-4        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-5        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-5        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-5        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-5        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-5        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-5        -- H  H    OCH.sub.3                                                                              CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-5        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-5        -- H  H    N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-7        -- H  H    H       CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (n = 1)                                                                        J-7        CH.sub.2                                                                          H  H    H       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 1)                                                                        J-7        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-7        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-8        -- H  H    H       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-8        -- H  H    H       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 1)                                                                        J-9        -- H  H    H       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (n = 0)                                                                        J-10       -- H  H    Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-10       -- H  H    CN      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-11       -- H  H    Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-12       -- H  3-CH.sub.3                                                                          H       CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-12       -- H  3-CH.sub.3                                                                          H       CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-12       -- H  H    Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-12       -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-13       -- H  H    H       CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (R.sub.3 = CH.sub.3)                                                           J-12       -- H  H    H       CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = C.sub.6 H.sub.5)                                                    J-12       -- H  3-CH.sub.3                                                                          H       CH.sub.3                                                                             CH.sub. 3                                                                             OCH.sub.3                           (R.sub.3 = C.sub.2 H.sub.5)                                                    J-11       -- H  H    H       CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH(CH.sub.3).sub.2)                                                 J-10       -- H  H    cyclopropyl                                                                            CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (R.sub.3 = n-C.sub.3 H.sub.7)                                                  J-11       -- H  H    CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (R.sub.3 = CH.sub.2 CF.sub.3)                                                  J-12       -- H  H    H       CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.2 CH═CH.sub.2)                                           J-7        -- H  6-F  H       CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-1        -- H  5-F  Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  6-Cl Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            J-2        -- H  4-Cl Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-7        -- H  6-Br H       CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-1        -- H  5-Br Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-3        -- H  4-CH.sub.3                                                                          Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  5-CH.sub.2 CN                                                                       Cl      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  5-OCH.sub.3                                                                         Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  5-SCH.sub.3                                                                         Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  5-OCF.sub.2 H                                                                       Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  6-Cl CN      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           J-1        -- H  6-Cl CN      CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-1        -- H  6-Cl CN      CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F                                                                  CH.sub.3                            J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F                                                                  OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                    NHCH.sub.3                          J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                    OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.2 CH.sub.2 Cl                                                                 CH.sub.3                            J-1        -- H  H    Cl      CH.sub.3                                                                             CH.sub.2 CI                                                                           OCH.sub.3                           J-1        -- H  H    CN      CH.sub.3                                                                             CH.sub.2 Br                                                                           OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             H                                   J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             SCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.2 CHF.sub.2                                                                   CH.sub.3                            J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             C.tbd.CH                            J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             C.sub.2 H.sub.5                     J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.2 OCH.sub.3                  J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.2 (OCH.sub.3).sub.2          J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             cyclopropyl                         J-1        -- H  H    CN      CH.sub.3                                                                             C.sub.2 H.sub.5                                                                       OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             CH.sub.2 F                                                                            OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             CF.sub.3                                                                              OCH.sub.3                           J-1        -- H  H    Cl      CH.sub.3                                                                             OC.sub.2 F.sub.5                                                                      CH.sub.3                            J-1        -- H  H    CN      CH.sub.3                                                                             CH.sub.3                                                                              OC.sub.2 H.sub.5                    J-1        -- H  H    CN      CH.sub.3                                                                             OCH.sub.3                                                                             CF.sub.3                            J-1        -- H  H    CN      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.2 CH═CH.sub.2           J-1        -- H  H    Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.2 C.tbd.CH                  J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             C.tbd.CCH.sub.3                     J-1        -- H  H    Cl      CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.2 OCH.sub.2 CH.sub.3         J-1        -- H  H    Cl      CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.2 CH.sub.2 OCH.sub.3        J-7        -- H  H    CF.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                    N(CH.sub.3).sub.2                   (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               C.sub.2 H.sub.5                                                                      CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               n-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               n-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CH.sub.2 CN                                                                          OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CN.sub.2 CN                                                                          CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CH.sub.2 CN                                                                          OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          (n = 0)    3                                                                   J-7        -- H  H    CF.sub.3                                                                               CH.sub.2 CN                                                                          OCH.sub.3 CF.sub.3                                                                    N(CH.sub.3).sub.2                   (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CH.sub.2 OCH                                                                         OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CF.sub.3                                                                               CH.sub.2 OCH                                                                         CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CH.sub.2 OCH.sub.3                                                                     CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CH.sub.2 OCH.sub.3                                                                     CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    F       CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    F       CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CH.sub.3                                                                               CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-7        -- H  H    CH.sub.3                                                                               CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                      NHCH.sub.3                          (n = n)                                                                        J-7        -- H  H    CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3 CF.sub.3                                                                    N(CH.sub.3).sub.2                   (n = 0)                                                                        J-11       -- H  H    CH.sub.2 SCH.sub.3                                                                     CH.sub.3                                                                             OCH.sub.3                                                                             CH.sub.3                            (R.sub.3 = CH.sub.3)                                                           J-1        -- H  H    F       CH.sub.3                                                                             OCH.sub.3                                                                             OCH.sub.3                           J-7        -- H  H    CH.sub.2 CN                                                                            CH.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                           (n =0)                                                                         J-11       -- H  H    CH.sub.3                                                                               CH.sub.2 SCH.sub.3                                                                   CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           __________________________________________________________________________

                                      TABLE 3                                      __________________________________________________________________________     General Formula 3                                                              J     E    R   R.sup.1 /R.sup.2                                                                     T.sup.1 /T.sup.2                                                                   Alk   X.sub.1                                                                             Y.sub.1                                    __________________________________________________________________________     J-1   --   H   H     Cl  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-1   --   H   H     Cl  CH.sub.3                                                                             OCH.sub.3                                                                           O                                          J-1   --   H   H     Cl  CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                    O                                          J-1   --   H   H     Cl  CH.sub.3                                                                             OCF.sub.2 H                                                                         O                                          J-1   --   H   H     Cl  CH.sub.3                                                                             OCH.sub.3                                                                           CH.sub.2                                   J-1   --   H   H     CN  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-1   --   H   H     CN  CH.sub.3                                                                             OCH.sub.3                                                                           O                                          J-1   --   H   H     OCH.sub.3                                                                          CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-2   --   H   H     Cl  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-3   --   H   H     Cl  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-12  --   H   3-CH.sub.3                                                                           Cl  CH.sub.3                                                                             CH.sub.3                                                                            O                                          (R.sub.3 = CH.sub.3)                                                           J-7   --   H   H     H   CH.sub.3                                                                             CH.sub.3                                                                            O                                          (n = 0)                                                                        J-7   --   H   6-F   H   CH.sub.3                                                                             CH.sub. 3                                                                           O                                          (n = 0)                                                                        J-1   --   H   5-OCH.sub.3                                                                          Cl  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-1   --   H   6-Cl  CN  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-12  --   H   3-CH.sub.3                                                                           H   CH.sub.3                                                                             CH.sub.3                                                                            O                                          (R.sub.3 = CH.sub.3)                                                           J-1   CH.sub.2                                                                            H   H     CN  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-1   --   CH.sub.3                                                                           H     Cl  CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-1   --   H   H     F   CH.sub.3                                                                             CH.sub.3                                                                            O                                          J-7   --   H   H     F   CH.sub.3                                                                             CH.sub.3                                                                            O                                          (n = 0)                                                                        J-7   --   H   H     CF  CH.sub.3                                                                             CH.sub.3                                                                            O                                          (n = 0)                                                                        J-7   --   H   H     CH.sub.3                                                                           CH.sub.2 CN                                                                          OCH.sub.3                                                                           O                                          (n = 0)                                                                        J-7   --   H   H     CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                           O                                          (n = 0)                                                                        __________________________________________________________________________

                  TABLE 4                                                          ______________________________________                                         General Formula 4                                                              J       E      R      R.sup.1 /R.sup.2                                                                      T.sup.1 /T.sup.2                                                                     Alk    X.sub.1                              ______________________________________                                         J-1     --     H      H      Cl    CH.sub.3                                                                              CH.sub.3                             J-1     --     H      H      Cl    CH.sub.3                                                                              OCH.sub.3                            J-1     --     H      H      Cl    CH.sub.3                                                                              OC.sub.2 H.sub.5                     J-1     --     H      H      Cl    CH.sub.3                                                                              OCF.sub.2 H                          J-1     --     H      H      CN    CH.sub.3                                                                              CH.sub.3                             J-1     --     H      H      CN    CH.sub.3                                                                              OCH.sub.3                            J-1     --     H      H      OCH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                             J-2     --     H      H      Cl    CH.sub.3                                                                              CH.sub.3                             J-3     --     H      H      Cl    CH.sub.3                                                                              OCH.sub.3                            J-12    --     H      3-CH.sub.3                                                                            Cl    CH.sub.3                                                                              CH.sub.3                             (R.sub.3 = CH.sub.3)                                                           J-7     --     H      H      H     CH.sub.3                                                                              OCH.sub.3                            (n = 0)                                                                        J-7     --     H      6-F    H     CH.sub.3                                                                              CH.sub.3                             (n = 0)                                                                        J-1     --     H      5-OCH.sub.3                                                                           Cl    CH.sub.3                                                                              CH.sub.3                             J-1     --     H      6-Cl   CN    CH.sub.3                                                                              CH.sub.3                             J-12    --     H      3-CH.sub.3                                                                            H     CH.sub.3                                                                              CH.sub.3                             (R.sub.3 = CH.sub.3)                                                           J-1     CH.sub.2                                                                              H      H      CN    CH.sub.3                                                                              CH.sub.3                             J-1     --     CH.sub.3                                                                              H      Cl    CH.sub.3                                                                              CH.sub.3                             J-1     --     H      H      F     CH.sub.3                                                                              CH.sub.3                             J-7     --     H      H      F     CH.sub.3                                                                              OCH.sub.3                            (n = 0)                                                                        J-7     --     H      H      CF.sub.3                                                                             CH.sub.3                                                                              OCH.sub.3                            (n = 0)                                                                        J-7     --     H      H      CH.sub.3                                                                             CH.sub.2 CN                                                                           OCH.sub.3                            (n = 0)                                                                        ______________________________________                                    

                                      TABLE 5                                      __________________________________________________________________________     General Formula 5                                                              J     E    R  R.sup.1 /R.sup.2                                                                    T.sup.1 /T.sup.2                                                                     Alk  X.sub.1                                                                               Y.sub.3                                   __________________________________________________________________________     J-1   --   H  H    Cl    CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                  J-1   --   H  H    Cl    CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-1   --   H  H    Cl    CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                      CH.sub.3                                  J-1   --   H  H    Cl    CH.sub.3                                                                            OCF.sub.2 H                                                                           CH.sub.3                                  J-1   --   H  H    Cl    CH.sub.3                                                                            OCH.sub.3                                                                             H                                         J-1   --   H  H    Cl    CH.sub.3                                                                            CH.sub.3                                                                              H                                         J-1   --   H  H    CN    CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                  J-2   --   H  H    Cl    CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                  J-3   --   H  H    Cl    CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-12  --   H  3-CH.sub.3                                                                          Cl    CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                  (R.sub.3 = CH.sub.3)                                                           J-7   --   H  H    H     CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  (n = 0)                                                                        J-7   --   H  6-F  H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                  (n = 0)                                                                        J-1   --   H  5-OCH.sub.3                                                                         Cl    CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-1   --   H  6-Cl CN    CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-12  --   H  3-CH.sub.3                                                                          H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                  (R.sub.3 = CH.sub.3)                                                           J-1   CH.sub.2                                                                            H  H    CN    CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-1   --   CH.sub.3                                                                          H    Cl    CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-1   --   H  H    OCH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-1   --   H  H    F     CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  J-7   --   H  H    F     CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  (n = 0)                                                                        J-7   --   H  H    CF.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH.sub.3                                  (n = 0)                                                                        J-7   --   H  H    CH.sub.3                                                                             CH.sub.2 CN                                                                         OCH.sub.3                                                                             CH.sub.3                                  (n = 0)                                                                        __________________________________________________________________________

                                      TABLE 6                                      __________________________________________________________________________     General Formula 6                                                              J     E    R  R.sup.1 /R.sup.2                                                                      T.sup.1 /T.sup.2                                                                   Alk  X.sub.2                                                                             Y.sub.2                                     __________________________________________________________________________     J-1   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-1   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            OC.sub.2 H.sub.5                            J-1   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            SCH.sub.3                                   J-1   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            SC.sub.2 H.sub.5                            J-1   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            CH.sub.3                                    J-1   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            C.sub.2 H.sub.5                             J-1   --   H  H      Cl  CH.sub.3                                                                            C.sub.2 H.sub.5                                                                     OCH.sub.3                                   J-1   --   H  H      Cl  CH.sub.3                                                                            CH.sub.2 CF.sub.3                                                                   OCH.sub.3                                   J-1   --   H  H      CN  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-1   --   H  H      OCH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-1   --   H  H      H   CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   (n = 0)                                                                        J-1   --   CH.sub.3                                                                          H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub. 3                                  J-1   CH.sub.2                                                                            H  H      CN  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-2   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-3   --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-12  --   H  3-CH.sub.3                                                                            H   CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   (R.sub.3 = CH.sub.3)                                                           J-12  --   H  H      Cl  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   (R.sub.3 = CH.sub.3)                                                           J-1   --   H  5-OCH.sub.3                                                                           Cl  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-1   --   H  6-Cl   CN  CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   J-7   --   H  6-F    H   CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   (n = 0)                                                                        J-7   --   H  H      CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                   (n = 0)                                                                        J-7   --   H  H      CH.sub.3                                                                           CH.sub.2 CN                                                                         CH.sub.3                                                                            OCH.sub.3                                   (n = 0)                                                                        __________________________________________________________________________

                  TABLE 7                                                          ______________________________________                                         General Formula 7                                                              J       E      R       R.sup.1 /R.sup.2                                                                      T.sup.1 /T.sup.2                                                                     Alk    X.sub.3                             ______________________________________                                         J-1     --     H       H      Cl    CH.sub.3                                                                              CH.sub.3                            J-1     --     H       H      Cl    CH.sub.3                                                                              OCH.sub.3                           J-1     --     H       H      CN    CH.sub.3                                                                              CH.sub.3                            J-1     --     H       H      CN    CH.sub.3                                                                              OCH.sub.3                           J-1     --     H       H      OCH.sub.3                                                                            CH.sub.3                                                                              OCH.sub.3                           J-2     --     H       H      Cl    CH.sub.3                                                                              CH.sub.3                            J-3     --     H       H      Cl    CH.sub.3                                                                              CH.sub.3                            J-4     --     H       H      Cl    CH.sub.3                                                                              OCH.sub.3                           J-5     --     H       H      H     CH.sub.3                                                                              CH.sub.3                            J-7     --     H       H      H     CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-12    --     H       H      H     CH.sub.3                                                                              OCH.sub.3                           (R.sub.3 = CH.sub.3)                                                           J-7     --     H       6-F    H     CH.sub.3                                                                              OCH.sub.3                           (n = 0)                                                                        J-1     --     H       6-Cl   CN    CH.sub.3                                                                              OCH.sub.3                           J-12    --     H       3-CH.sub.3                                                                            H     CH.sub.3                                                                              CH.sub.3                            (R.sub.3 =  CH.sub.3)                                                          J-1     --     H       5-OCH.sub.3                                                                           Cl    CH.sub.3                                                                              CH.sub.3                            J-1     CH.sub.2                                                                              H       H      CN    CH.sub.3                                                                              CH.sub.3                            J-1     --     CH.sub.3                                                                               H      Cl    CH.sub.3                                                                              CH.sub.3                            J-7     --     H       H      CH.sub.3                                                                             CH.sub.3                                                                              CH.sub.3                            (n = 0)                                                                        J-7     --     H       H      CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3                            (n = 0)                                                                        J-7     --     H       H      CH.sub.3                                                                             CH.sub.2 CN                                                                           CH.sub.3                            ______________________________________                                    

                                      TABLE 8                                      __________________________________________________________________________     General Formula 8                                                              J     E  R  R.sup.1 /R.sup.2                                                                    T.sup.1 /T.sup.2                                                                   Alk  X.sub.4                                                                              Y.sub.4                                                                            Z.sub.1                                    __________________________________________________________________________     J-1   -- H  H    CN  CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                           CH                                         J-1   -- H  H    Cl  CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                           N                                          J-1   -- H  H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-1   -- H  H    CN  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           N                                          J-1   -- H  H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                          CH                                         J-1   -- H  H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                          N                                          J-1   -- H  H    Cl  CH.sub.3                                                                            Cl    CH.sub.3                                                                           CH                                         J-1   -- H  H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            Cl  CH                                         J-1   -- H  H    Cl  CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     CH.sub.3                                                                           CH                                         J-1   -- H  H    Cl  CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                   CH.sub.3                                                                           N                                          J-1   -- H  H    Cl  CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                          CH                                         J-1   -- H  H    Cl  CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                   N                                          J-1   CH.sub.2                                                                          H  H    CN  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-1   -- CH.sub.3                                                                          H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-2   -- H  H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-3   -- H  H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-4   -- H  H    Cl  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-5   -- H  H    H   CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-7   -- H  H    H   CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (n = 0)                                                                        J-12  -- H  H    H   CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (R.sub.3 = CH.sub.3)                                                           J-7   -- H  6-F  H   CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (n = 0)                                                                        J-12  -- H  3-CH.sub.3                                                                          H   CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (R.sub.3 = CH.sub.3)                                                           J-1   -- H  5-OCH.sub.3                                                                         Cl  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-1   -- H  6-Cl CN  CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-1   -- H  H    F   CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         J-7   -- H  H    F   CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (n = 0)                                                                        J-7   -- H  H    CH.sub.3                                                                           CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (n = 0)                                                                        J-7   -- H  H    CH.sub.3                                                                           CH.sub.2 CN                                                                         OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (n = 0)                                                                        J-7   -- H  H    CF.sub.3                                                                           CH.sub.3                                                                            OCH.sub.3                                                                            CH.sub.3                                                                           CH                                         (n = 0)                                                                        __________________________________________________________________________

                                      TABLE 9                                      __________________________________________________________________________     J   E    R   R.sup.1 /R.sup.2                                                                     T.sup.1 /T.sup.2                                                                    Alk W X.sub.4                                                                             Y.sub.4                                                                             Z.sub.1                                __________________________________________________________________________     J-1 --   H   H     Cl   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-1 --   H   H     Cl   CH.sub.3                                                                           S CH.sub.3                                                                            OCH.sub.3                                                                           N                                      J-1 --   H   H     Cl   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           N                                      J-1 --   H   H     CN   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-1 --   CH.sub.3                                                                           H     Cl   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-1 CH.sub.2                                                                            H   H     CN   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-2 --   H   H     Cl   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-3 --   H   H     Cl   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-4 --   H   H     Cl   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-1 --   H   5-OCH.sub.3                                                                          Cl   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-1 --   H   6-Cl  CN   CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     J-7 --   H   H     CH.sub.3                                                                            CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     (n = 0)                                                                        J-7 --   H   H     CF.sub.3                                                                            CH.sub.3                                                                           S OCH.sub.3                                                                           OCH.sub.3                                                                           CH                                     (n = 0)                                                                        __________________________________________________________________________

Formulations

Useful formulations of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used as spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulations, broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of these carriers: (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid inert diluent(s). More specifically, they will contain these ingredients in the following approximate proportions:

    ______________________________________                                                      Weight Percent*                                                                Active            Sur-                                                         Ingredient                                                                             Diluent(s)                                                                               factant(s)                                      ______________________________________                                         Wettable Powders                                                                              20-90      0-74     1-10                                        Oil Suspensions,                                                                               3-50     40-95     0-15                                        Emulsions, Solutions,                                                          (including Emulsifiable                                                        Concentrates)                                                                  Aqueous Suspension                                                                            10-50     40-84     1-20                                        Dusts           1-25     70-99     0-5                                         Granules and Pellets                                                                          0.1-95      5-99.9  0-15                                        High Strength  90-99      0-10     0-2                                         Compositions                                                                   ______________________________________                                          *Active ingredient plus at least one of a Surfactant or a Diluent equals       100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books, Caldwell, N.J., but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, "Solvents Guide", 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferably stable against phase separation at 0° C. "McCutcheon's Detergents and Emulsifiers Annual", MC Publishing Corp., Ridgewood, N.J., as well as Sisely and Wood, Encyclopedia of Surface Active Agents", Chemical Publishing Co., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor amounts of additives to reduce foaming, caking, corrosion, microbiological growth, etc.

The methods of making such compositions are well known. Solutios are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning, "Agglomeration", Chemical Engineering, Dec. 4, 1967, pages 147ff. and "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York, 1963, pages 8-57ff.

For further information regarding the art of formulation, see for example:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16 through Col. 7, line 19 and Examples 10 through 41;

R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138 to 140, 162 to 164, 166, 167 and 169 to 182;

H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, June 23, 1959, Col. 3, line 66 through Col. 5, line 17 and Examples 1 to 4;

G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pages 81 to 96; and

J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pages 101 to 103.

In the following examples, all parts are by weight unless otherwise indicated.

EXAMPLE 10

High Strength Concentrate

    ______________________________________                                         2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)-                                                                 99%                                                 amino]carbonyl]amino]sulfonyl]-N--                                             methoxybenzenecarboximidoyl chloride                                           trimethylnonyl polyethylene glycol                                                                         1%                                                 ether                                                                          ______________________________________                                    

The surfactant is sprayed upon the active ingredient in a blender and the mixture sifted through a U.S.S. No. 40 sieve (0.42 mm openings) prior to packaging. The concentrate may be formulated further for practical use.

EXAMPLE 11

Wettable Powder

    ______________________________________                                         2-[(cyano)(methoxyimino)methyl]-N---                                                                  65%                                                     [[(4-methoxy-6-methyl-2-pyrimidinyl)-                                          amino]carbonyl]benzenesulfonamide                                              dodecylphenol polyethylene                                                                            2%                                                      glycol ether                                                                   sodium ligninsulfonate 4%                                                      sodium silicoaluminate 6%                                                      montmorillonite (calcined)                                                                            23%                                                     ______________________________________                                    

The ingredients are thoroughly blended. The liquid surfactant is added by spraying upon the solid ingredients in the blender. After grinding in a hammer mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) and packaged.

EXAMPLE 12

Aqueous Suspension

    ______________________________________                                         N--methoxy-2-[[[[(4-methoxy-6-methyl-                                                                  50.0%                                                  1,3,5-triazin-2-yl)amino]carbonyl]-                                            amino]sulfonyl]benzenecarboximidoyl                                            chloride                                                                       polyacrylic acid thickener                                                                             0.3%                                                   dodecylphenol polyethylene glycol ether                                                                0.5%                                                   disodium phosphate      1.0%                                                   monosodium phosphate    0.5%                                                   polyvinyl alcohol       1.0%                                                   water                   56.7%                                                  ______________________________________                                    

The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.

EXAMPLE 13

Oil Suspension

    ______________________________________                                         2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)-                                                                  35%                                                amino]carbonyl]amino]sulfonyl]-N--                                             methoxybenzenecarboximidoyl chloride                                           blend of polyalcohol carboxylic esters                                                                      6%                                                and oil soluble petroleum sulfonates                                           xylene                      59%                                                ______________________________________                                    

The ingredients are combined and ground together in a sand mill to produce particles essentially all below 3 microns. The product can be used directly, extended with oils, or emulsified in water.

EXAMPLE 14

Oil Suspension

    ______________________________________                                         2-[(cyano)(methoxyimino)methyl]-N--                                                                       25%                                                 [[(4-methoxy-6-methyl-2-pyrimidinyl)-                                          amino]carbonyl]benzenesulfonamide                                              polyoxyethylene sorbitol hexaoleate                                                                        5%                                                 highly aliphatic hydrocarbon oil                                                                          70%                                                 ______________________________________                                    

The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water.

EXAMPLE 15

Aqueous Suspension

    ______________________________________                                         N--methoxy-2-[[[[(4-methoxy-6-methyl-                                                                 25.0%                                                   1,3,5-triazin-2-yl)amino]carbonyl]-                                            amino]sulfonyl]benzenecarboximidoyl                                            chloride                                                                       hydrated attapulgite    3.0%                                                   crude calcium ligninsulfonate                                                                         20.0%                                                   sodium dihydrogen phosphate                                                                            0.5%                                                   water                  61.5%                                                   ______________________________________                                    

The ingredients are ground together in a ball or roller mill until the solid particles have been reduced to diameters under 10 microns.

EXAMPLE 16

Wettable Powder

    ______________________________________                                         2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)-                                                                  40%                                                amino]carbonyl]amino]sulfonyl]-N--                                             methoxybenzenecarboximidoyl chloride                                           dioctyl sodium sulfosuccinate                                                                              1.5%                                               sodium ligninsulfonate      3%                                                 low viscosity methyl cellulose                                                                             1.5%                                               attapulgite                 54%                                                ______________________________________                                    

The ingredients are thoroughly blended, passed through an air mill, to produce an average particle size under 15 microns, reblended, and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) before packaging.

All compounds of the invention may be formulated in the same manner.

EXAMPLE 17

Granule

    ______________________________________                                         wettable powder of Example 16                                                                            15%                                                  gypsum                    69%                                                  potassium sulfate         16%                                                  ______________________________________                                    

The ingredients are blended in a rotating mixer and water sprayed on to accomplish granulation. When most of the material has reached the desired range of 1.0 to 0.42 cm (U.S.S. No. 18 to 40 sieves), the granules are removed, dried, and screened. Oversized material is crushed to produce additional material in the desired range. These granules contain % active ingredient.

EXAMPLE 18

Wettable Powder

    ______________________________________                                         2-[(cyano)(methoxyimino)methyl]-N--                                                                       50%                                                 [[(4-methoxy-6-methyl-2-pyrimidinyl)-                                          amino]carbonyl]benzenesulfonamide                                              sodium alkylnaphthalenesulfonate                                                                           2%                                                 low viscosity methyl cellulose                                                                             2%                                                 diatomaceous earth         46%                                                 ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and then air milled to produce particles of active essentially all below 10 microns in diameter. The product is reblended before packaging.

EXAMPLE 19

Extruded Pellet

    ______________________________________                                         N--methoxy-2-[[[[(4-methoxy-6-methyl-                                                                 25%                                                     1,3,5-triazin-2-yl)amino]carbonyl]-                                            amino-9 sulfonyl]benzenecarboximidoyl                                          chloride                                                                       anhydrous sodium sulfate                                                                              10%                                                     crude calcium ligninsulfonate                                                                          5%                                                     sodium alkylnaphthalenesulfonate                                                                       1%                                                     calcium magnesium bentonite                                                                           59%                                                     ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.

EXAMPLE 20

Wettable Powder

    ______________________________________                                         2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)-                                                                  80%                                                amino]carbonyl]amino]sulfonyl]-N--                                             methoxybenzenecarboximidoyl chloride                                           sodium alkylnaphthalenesulfonate                                                                           2%                                                 sodium ligninsulfonate      2%                                                 synthetic amorphous silica  3%                                                 kaolinite                   13%                                                ______________________________________                                    

The ingredients are blended and then ground in a hammer-mill to produce particles with an average particle size less than 25 microns in diameter. The material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) before being packaged.

EXAMPLE 21

High Strength Concentrate

    ______________________________________                                         2-[(cyano)(methoxyimino)methyl]-N--                                                                       98.5%                                               [[(4-methoxy-6-methyl-2-pyrimidinyl)-                                          amino]carbonyl]benzenesulfonamide                                              silica aerogel              0.5%                                               synthetic amorphous fine silica                                                                            1.0%                                               ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce a high strength concentrate essentially all passing a U.S.S. No. 50 sieve (0.3 mm opening). This material may then be formulated in a variety of ways.

Utility

Test results indicate that the compounds of the present invention are highly active preemergent or postemergent herbicides or plant growth regulants. Many of them have utility for broad-spectrum pre-and/or postemergence weed control in areas where complete control of all vegetation is desired, such as around storage tanks, industrial storage areas, parking lots, drive-in theaters, around billboards, highway and railroad structures. Some of the compounds have utility for selective weed control in crops such as rice, wheat, barley, corn, sorghum, soybeans and cotton. Alternatively, the subject compounds are useful to modify plant growth.

The rates of application for the compounds of the invention are determined by a number of factors, including their use as plant growth modifiers or as herbicides, the crop species involved, the types of weeds to be controlled, weather and climate, formulations selected, mode of application, amount of foliage present, etc. In general terms, the subject compounds should be applied at levels of around 0.001 to 20 kg/ha, the lower rates being suggested for use on lighter soils and/or those having a low organic matter content, for plant growth modication or for situations where only short-term persistence is required, such as a herbicide for fallow land.

The compounds of the invention may be used in combination with any other commercial herbicide, representative examples of which are those of the sulfonylurea, triazine, triazole, uracil, urea, amide, diphenyl ether, carbamate, imidazolinone, cineole and bipyridylium types. A partial listing follows:

    ______________________________________                                         Common Name                                                                               Chemical Name                                                       ______________________________________                                         acetochlor 2-chloro-N--(ethoxymethyl)-N--(2-ethyl-6-                                      methylphenyl)acetamide                                              acifluorfen                                                                               5-[2-chloro-4-(trifluoromethyl)phenoxy]-                                       2-nitrobenzoic acid                                                 acrolein   2-propenal                                                          alachlor   2-chloro-N--(2,6-diethylphenyl)-N--(methoxy-                                   methyl)acetamide                                                    ametryn    N--ethyl-N'--(1-methylethyl)-6-(methylthio)-                                   1,3,5-triazine-2,4-diamine                                          amitrole   1H--1,2,4-triazol-3-amine                                           AMS        ammonium sulfamate                                                  asulam     methyl [(4-aminophenyl)sulfonyl]carbamate                           atrazine   6-chloro-N--ethyl-N'--(1-methylethyl)-1,3,5-                                   triazine-2,4-diamine                                                barban     4-chloro-2-butynyl 3-chlorocarbamate                                benefin    N--butyl-N--ethyl-2,6-dinitro-4-(tri-                               methy      fluoromethyl)benzenamine                                            bensulfuron                                                                               2-[[[[[4,6-dimethoxy-2-pyrimidinyl)amino]-                                     carbonyl]amino]sulfonyl]methyl]benzoic                                         acid, methyl ester                                                  bensulide  O,O--bis(1-methylethyl) S--[2-[(phenylsul-                                     fonyl)amino]ethyl] phosphorodithioate                               bentazon   3-(1-methylethyl)-(1H)-2,1,3-benzothia-                                        diazin-4(3H)-one, 2,2-dioxide                                       benzofluor N--[4-(ethylthio)-2-(trifluoromethyl)-                                         phenyl]methanesulfonamide                                           benzoylprop                                                                               N--benzoyl-N--(3,4-dichlorophenyl)-DL-                                         alanine                                                             bifenox    methyl 5-(2,4-dichlorophenoxy)-2-                                              nitrobenzoate                                                       bromacil   5-bromo-6-methyl-3-(1-methylpropyl)-                                           2,4(1H,3H)pyrimidinedione                                           bromoxynil 3,5-dibromo-4-hydroxybenzonitrile                                   butachlor  N--(butoxymethyl)-2-chloro-N--(2,6-diethyl-                                    phenyl)acetamide                                                    buthidazole                                                                               3-[5-(1,1-dimethylethyl)-1,3,4-thia-                                           diazol-2-yl]-4-hydroxy-1-methyl-2-                                             imidazolidinone                                                     butralin   4-(1,1-dimethylethyl)-N--(1-methyl-                                            propyl)-2,6-dinitrobenzenamine                                      butylate   S--ethyl bis(2-methylpropyl)carbamothioate                          cacodylic  dimethyl arsinic oxide                                              acid                                                                           CDAA       2-chloro-N,N--di-2-propenylacetamide                                CDEC       2-chloroallyl diethyldithiocarbamate                                chloramben 3-amino-2,5-dichlorobenzoic acid                                    chlorbromuron                                                                             3-(4-bromo-3-chlorophenyl)-1-methoxy-1-                                        methylurea                                                          chlorimuron                                                                               2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)-                           ethyl      amino]carbonyl]amino]sulfonyl]benzoic                                          acid, ethyl ester                                                   chloroxuron                                                                               N'--[4-(4-chlorophenoxy)phenyl]-N,N--                                          dimethylurea                                                        chlorpropham                                                                              1-methylethyl 3-chlorophenylcarbamate                               chlorsulfuron                                                                             2-chloro-N--[[(4-methoxy-6-methyl-1,3,5-                                       triazin-2-yl)amino]carbonyl]benzene-                                           sulfonamide                                                         chlortoluron                                                                              N'--(3-chloro-4-methylphenyl)-N,N--                                            dimethylurea                                                        cinmethylin                                                                               exo-1-methyl-4-(1-methylethyl)-2-[(2-                                          methylphenyl)methoxy]-7-oxabicyclo-                                            [2.2.1]heptane                                                      clethodim  (E,E)-(±)-2-[1-[[(3-chloro-2-propenyl)-                                     oxy]imino]propyl]-5-[2-(ethylthio)-                                            propyl]-3-hydroxy-2-cyclohexen-1-one                                clomazone  2-[(2-chlorophenyl)methyl]-4,4-dimethyl-                                       3-isoxazolidinone                                                   cloproxydim                                                                               (E,E)-2-[1-[[(3-chloro-2-propenyl)oxy)-                                        imino]butyl]-5-[2-(ethylthio)propyl]-                                          3-hydroxy-2-cyclohexen-1-one                                        clopyralid 3,6-dichloro-2-pyridinecarboxylic acid                              CMA        calcium salt of MAA                                                 cyanazine  2-[[4-chloro-6-(ethylamino-1,3,5-tri-                                          azin-2-yl]amino]-2-methylpropanenitrile                             cycloate   S--ethyl cyclohexylethylcarbamothioate                              cycluron   3-cyclooctyl-1,1-dimethylurea                                       cyperquat  1-methyl-4-phenylpyridinium                                         cyprazine  2-chloro-4-(cyclopropylamino)-6-(iso-                                          propylamino)- .sub.-s-triazine                                      cyprazole  N--[5-(2-chloro-1,1-dimethylethyl)-1,3,4-                                      thiadiazol-2-yl]cyclopropanecarbox-                                            amide                                                               cypromid   3',4'-dichlorocyclopropanecarboxanilide                             dalapon    2,2-dichloropropanoic acid                                          dazomet    tetrahydro-3,5-dimethyl-2H-1,3,5-thia-                                         diazine-2-thione                                                    DCPA       dimethyl 2,3,5,6-tetrachloro-1,4-benzene-                                      dicarboxylate                                                       desmediphan                                                                               ethyl [3-[[(phenylamino)carbonyl]oxy]-                                         phenyl]carbamate                                                    desmetryn  2-(isopropylamino)-4-(methylamino)-6-                                          (methylthio)- .sub.-s-triazine                                      diallate   S--(2,3-dichloro-2-propenyl)bis(1-                                             methylethyl)carbamothioate                                          dicamba    3,6-dichloro-2-methoxybenzoic acid                                  dichlobenil                                                                               2,6-dichlorobenzonitrile                                            dichlorprop                                                                               (±)-2-(2,4-dichlorophenoxy)propanoic                                        acid                                                                dichlofop  (±)-2-[4-(2,4-dichlbrophenoxy)phenoxy]-                                     propanoic acid                                                      diethatyl  N--(chloroacetyl)-N--(2,6-diethylphenyl)-                                      glycine                                                             difenzoquat                                                                               1,2-dimethyl-3,5-diphenyl-1H--pyrazolium                            dinitramine                                                                               N.sup.3,N.sup.3 -diethyl-2,4-dinitro-6-(trifluoro-                             methyl)-1,3-benzenediamine                                          dinoseb    2-(1-methylpropyl)-4,6-dinitrophenol                                diphenamid N,N--dimethyl-α-phenylbenzeneacetamide                        dipropetryn                                                                               6-(ethylthio)-N,N'--bis(1-methylethyl)-                                        1,3,5-triazine-2,4-diamine                                          diquat     6,7-dihydrodipyrido[1,2-a:2',1'-c]-                                            pyrazinedium ion                                                    diuron     N'--(3,4-dichlorophenyl)-N,N--dimethylurea                          DNOC       2-methyl-4,6-dinitrophenol                                          DPX-M6316  3-[[[[(4-methoxy-6-methyl-1,3,5-triazin-                                       2-yl)amino]carbonyl]amino]sulfonyl]-                                           2-thiophenecarboxylic acid, methyl                                             ester                                                               DSMA       disodium salt of MAA                                                endothall  7-oxabicyclo[2.2.1]heptane-2,3-dicarbox-                                       ylic acid                                                           EPTC       S--ethyl dipropylcarbamothioate                                     ethalfluralin                                                                             N--ethyl-N--(2-methyl-2-propenyl)-2,6-                                         dinitro-4-(trifluoromethyl)-                                                   benzenamine                                                         ethofumesate                                                                              (±)-2-ethoxy-2,3-dihydro-3,3-dimethyl-                                      5-benzofuranyl methanesulfonate                                     Express ®                                                                             2-[[[[N--(4-methoxy-6-methyl-1,3,5-triazine-                                   2-yl)-N--methylamino]carbonyl]amino]-                                          sulfonyl]benzoic acid, methyl eter                                  fenac      2,3,6-trichlorobenzeneacetic acid                                   fenoxaprop (±)-2-[4-[(6-chloro-2-benzoxazolyl)oxy]-                                    phenoxy]propanoic acid                                              fenuron    N,N--dimethyl-N'--phenylurea                                        fenuron TCA                                                                               Salt of fenuron and TCA                                             flamprop   N--benzoyl-N--(3-chloro-4-fluorophenyl)-                                       DL-alanine                                                          fluazifop  (±)-2-[4-[[5-(trifluoromethyl)-2-pyri-                                      dinyl]oxy]phenoxy]propanoic acid                                    fluazifop-P                                                                               (R)-2-[ 4-[[5-(trifluoromethyl)-2-pyri-                             20         dinyl]oxy]phenoxy]propanoic acid                                    fluchloralin                                                                              N--(2-ch1oroethyl)-2,6-dinitro-N--propyl-                                      4-(trifluoromethyl)benzenamine                                      fluometuron                                                                               N,N--dimethyl-N'--[3-(trifluoromethyl)-                                        phenyl]urea                                                         fluorochlor-                                                                              3-chloro-4-(chloromethyl)-1-[3-(trifluoro-                          idone      methyl)phenyl]-2-pyrrolidinone                                      fluorodifen                                                                               p-nitrophenyl α,α,α-trifluoro-2-nitro-                        -p-tolyl ether                                                     fluoroglycofen                                                                            carboxymethyl 5-[2-chloro-4-(tri-                                              fluoromethyl)phenoxy]-2-nitrobenzoate                               fluridone  1-methyl-3-phsnyI-5-[3-(trifluoro-                                             methyl)phenyl]-4(1H)-pyridinone                                     fomesafen  5-[2-chloro-4-(trifluoromethyl)phenoxy]-                                       N--(methylsulfonyl)-2-nitrobenzamide                                fosamine   ethyl hydrogen (aminocarbonyl)-                                                phosphate                                                           glyphosate N--(phosphonomethyl)glycine                                         haloxyfop  2-[4-[[3-chloro-5-(trifluoromethyl)-2-                                         pyridinyl]oxy]phenoxy ]propanoic acid                               hexaflurate                                                                               potassium hexafluoroarsenate                                        hexazinone 3-cyclohexyl-6-(dimethylamino)-1-methyl-                                       1,3,5-triazine-2,4(1H,3H)-dione                                     imazamethabenz                                                                            6-(4-isopropyl-4-methyl-5-oxo-2-                                               imidazolin-2-yl)- .sub.--m-toluic acid,                                        methyl ester and 6-(4-isopropyl-                                               4-methyl-5-oxo-2-imidazolin-2-yl)-                                              -p-toluic acid, methyl ester                                       imazapyr   (±)-2 -[4,5-dihydro-4-methyl-4-(1-methyl-                                   ethyl)-5-oxo-1H--imidazol-2-yl]-3-                                             pyridinecarboxylic acid                                             imazaquin  2-[4,5-dihydro-4-methyl-4-(1-methyl-                                           ethyl)-5-oxo-1H--imidazol-2-yl]-3-                                             quinolinecarboxylic acid                                            imazethapyr                                                                               (±)-2-[4,5-dihydro-4-methyl-4-(1-methyl-                                    ethyl)-5-oxo-1H--imidazol-2-yl]-5-                                             ethyl-3-pyridinecarboxylic acid                                     ioxynil    4-hydroxy-3,5-diiodobenzonitrile                                    isopropalin                                                                               4-(1-methylethyl)-2,6-dinitro-N,N--                                            dipropylbenzenamine                                                 isoproturon                                                                               N--(4-isopropylphenyl)-N',N'--dimethylurea                          isouron    N'--[5-(1,1-dimethylethyl)-3-isoxazolyl]-                                      N,N-- dimethylurea                                                  isoxaben   N--[3-(1-ethyl-1-methylpropyl)-5-                                              isoxazolyl]-2,6-dimethoxybenzamide                                  karbutilate                                                                               3-[[(dimethylamino)carbonyl]amino]-                                            phenyl-(1,1-dimethylethyl)carbamate                                 lactofen   (±)-2-ethoxy-1-methyl-2-oxoethyl 5-[2-                                      chloro-4-(trifluoromethyl)phenoxy]-                                            2-nitrobenzoate                                                     lenacil    3-cyclohexyl-6,7-dihydro-1H--cyclopenta-                                       pyrimidine-2,4(3H,5H)-dione                                         linuron    N'--(3,4-dichlorophenyl)-N--methoxy-N--                                        methylurea                                                          MAA        methylarsonic acid                                                  MAMA       monoammonium salt of MAA                                            MCPA       (4-chloro-2-methylphenoxy)acetic acid                               MCPB       4-(4-chloro-2-methylphenoxy)butanoic                                           acid                                                                mecoprop   (±)-2-(4-chloro-2-methylphenoxy)-                                           propanoic acid                                                      mefluidide N--[2,4-dimethyl-5-[[(trifluoromethyl)-                                        sulfonyl]amino]phenyl]acetamide                                     methal-    N--(2-methyl-2-propenyl)-2,6-dinitro-N--                            propalin   propyl-4-(trifluoromethyl)benzenamide                               methabenz- 1,3-dimethyl-3-(2-benzothiazolyl)urea                               thiazuron                                                                      metham     methylcarbamodithioic acid                                          methazole  2-(3,4-dich1orophenyl)-4-methyl-1,2,4-                                         oxadiazolidine-3,5-dione                                            methoxuron N'--(3-chloro-4-methoxyphenyl)-N,N--                                           dimethylurea                                                        metolachlor                                                                               2-chloro-N--(2-ethyl-6-methylphenyl)-N--                                       (2-methoxy-1-methylethyl)acetamide                                  metribuzin 4-amino-6-(1,1-dimethylethyl)-3-(methyl-                                       thio)-1,2,4-triazin-5(4H)-one                                       metsulfuron                                                                               2-[[[[(4-methoxy-6-methyl-1,3,5-tri-                                methyl     azin-2-yl)amino]carbonyl]-                                                     amino]sulfonyl]benzoic acid,                                                   methyl ester                                                        MH         1,2-dihydro-3,6-pyridazinedione                                     molinate   S--ethyl hexahydro-1H--azepine-1-carbo-                                        thioate                                                             monolinuron                                                                               3-( -p-chlorophenyl)-1-methoxy-1-methyl-                                       urea                                                                monuron    N'--(4-chlorophenyl)-N,N--dimethylurea                              monuron TCA                                                                               Salt of monuron and TCA                                             MSMA       monosodium salt of MAA                                              napropamide                                                                               N,N--diethyl-2-(1-naphthalenyloxy)-                                            propanamide                                                         naptalam   2-[(1-naphthalenylamino)carbonyl]-                                             benzoic acid                                                        neburon    1-butyl-3-(3,4-dichlorophenyl)-1-methyl-                                       urea                                                                nitralin   4-(methylsulfonyl)-2,6-dinitro-N,N--                                           dipropylaniline                                                     nitrofen   2,4-dichloro-1-(4-nitrophenoxy)benzene                              nitrofluorfen                                                                             2-chloro-1-(4-nitrophenoxy)-4-(tri-                                            fluoromethyl)benzene                                                norea      N,N--dimethyl-N'--(octahydro-4,7-methano-                                      1H--inden-5-yl)urea 3aα,-                                                4α,5α,7α,7aα-isomer                         norflurazon                                                                               4-chloro-5-(methylamino)-2-[3-(trifluoro-                                      methyl)phenyl]-3(2H)-pyridazinone                                   oryzalin   4-(dipropylamino)-3,5-dinitro-                                                 benzenesulfonamide                                                  oxadiazon  3-[2,4-dichloro-5-(1-methylethoxy)-                                            phenyl]-5-(1,1-dimethylethyl)-                                                 1,3,4-oxadiazol-2(3H)-one                                           oxyfluorfen                                                                               2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-                                        (trifluoromethyl)benzene                                            paraquat   1,1'-dimethyl-4,4'-dipyridinium ion                                 pebulate   S--propyl butylethylcarbamothioate                                  pendimethalin                                                                             N--(1-ethylpropyl)-3,4-dimethyl-2,6-                                           dinitrobenzenamine                                                  perfluidone                                                                               1,1,1-trifluoro-N--[2-methyl-4-(phenyl-                                        sulfonyl)phenyl]methanesulfonamide                                  phenmedipham                                                                              3-[(methoxycarbonyl)amino]phenyl (3-                                           methylphenyl)carbamate                                              picloram   4-amino-3,5,6-trichloro-2-pyridine-                                            carboxylic acid                                                     PPG-1013   5-[2-chloro-4-(trifluoromethyl)-                                               phenoxy]-2-nitroacetophenone                                                   oxime-O--acetic acid, methyl ester                                  procyazine 2-[[4- chloro-6-(cyclopropylamino)-1,3,5-                                      triazine-2-yl]amino]-2-methylpropane-                                          nitrile                                                             profluralin                                                                               N--(cyclopropylmethyl)-2,6-dinitro-N--                                         propyl-4- (trifluoromethyl)benzenamine                              prometon   6-methoxy-N,N'--bis(1-methylethyl)-1,3,5-                                      triazine-2,4-diamine                                                prometryn  N,N'--bis(1-methylethyl)-6-(methylthio)-                                       1,3,5-triazine-2,4-diamine                                          pronamide  3,5-dichloro-N--(1,1-dimethyl-2-propyn-                                        yl)benzamide                                                        propachlor 2-chloro-N--(1-methylethyl)-N--                                                phenylacetamide                                                     propanil   N--(3,4-dichlorophenyl)propanamide                                  propazine  6-chloro-N,N'--bis(1-methylethyl)-                                             1,3,5-triazine-2,4-diamine                                          propham    1-methylethyl phenylcarbamate                                       prosulfalin                                                                               N--[[(dipropylamino)-3,5-dinitro-                                              phenyl]sulfonyl]-S,S--dimethylsulfil-                                          imine                                                               prynachlor 2-chloro-N--(1-methyl-2-propynyl)acet-                                         anilide                                                             pyrazon    5-amino-4-chloro-2-phenyl-3(2H)-                                               pyridazinone                                                        quizalofop (±)-2-[4-[(6-chloro-2-quinoxalinyl)-                             ethyl      oxy]phenoxy]propanoic acid, ethyl                                              ester                                                               secbumeton N--ethyl-6-methoxy-N'--(1-methylpropyl)-                                       1,3,5-triazine-2,4-diamine                                          sethoxydim 2-[1-(ethoxyimino)butyl]-5-[2-(ethyl-                                          thio)propyl]-3-hydroxy-2-cyclohexen-                                           1-one                                                               siduron    N--(2-methylcyclohexyl)-N'--phenylurea                              simazine   6-chloro-N,N'--diethyl-1,3,5-triazine-                                         2,4-diamine                                                         sulfometuron                                                                              2-[[[[(4,6-dimethyl-2-pyrimidinyl)-                                 methyl     amino]carbonyl]amino]sulfonyl]-                                                benzoic acid, methyl ester                                          TCA        trichloroacetic acid                                                tebuthiuron                                                                               N--[5-(1,1-dimethylethyl)-1,3,4-thiadi-                                        azol-2-yl]-N,N'--dimethylurea                                       terbacil   5-chloro-3-(1,1-dimethylethyl)-6-                                              methyl-2,4(1H,3H)-pyrimidinedione                                   terbuchlor N--(butoxymethyl)-2-chloro-N--[2-(1,1-                                         dimethylethyl)-6-methylphenyl]-                                                acetamide                                                           terbuthyl- 2-(tert-butylamino)-4-chloro-6-(ethyl-                              azine      amino- .sub.-s-triazine                                             terbutol   2,6-di-tert-butyl- -p-tolyl methylcar-                                         bamate                                                              terbutryn  N--(1,1-dimethylethyl)-N'--ethyl-6-                                            (methylthio)-1,3,5-triazine-                                                   2,4-diamine                                                         thiameturon                                                                               3-[[[[(4-methoxy-6-methyl-1,3,5-                                    methyl     triazin-2-yl)amino]carbonyl]-                                                  amino]sulfonyl]-2-thiophenecarboxylic                                          acid, methyl ester                                                  thiobencarb                                                                               S--[(4-chlorophenyl)methyl]diethylcar-                                         bamothioate                                                         triallate  S--(2,3,3-trichloro-2-propenyl) bis(1-                                         methylethyl)carbamothioate                                          triclopyr  [(3,5,6-trichloro-2-pyridinyl)-                                                oxy]acetic acid                                                     tridiphane 2-(3,5-dichlorophenyl)-2-(2,2,2-                                               trichloroethyl)oxirane                                              trifluralin                                                                               2,6-dinitro-N,N--dipropyl-4-(tri-                                              fluoromethyl)benzenamine                                            trimeturon 1-( -p-chlorophenyl)-2,3,3-trimethylpseu-                                      dourea                                                              2,4-D      (2,4-dichlorophenoxy)acetic acid                                    2,4-DB     4-(2,4-dichlorophenoxy)butanoic acid                                vernolate  S--propyl dipropylcarbamothioate                                    xylachlor  2-chloro-N--(2,3-dimethy1phenyl)-N--                                           (1-methylethyl)acetamide                                            ______________________________________                                    

The herbicidal properties of the subject compounds were discovered in a number of greenhouse tests. The test procedures and results follow.

    ______________________________________                                         COMPOUND TABLES                                                                ______________________________________                                          ##STR35##                                                                     CMPD  R         R.sup.1                                                                              X     Y      Z     m.p. (°C.)                     ______________________________________                                         1     CH.sub.3  H     OCH.sub.3                                                                            OCH.sub.3                                                                             CH    203 to 210                            2     CH.sub.3  H     CH.sub.3                                                                             OCH.sub.3                                                                             CH    190 to 192                            3     CH.sub.3  H     CH.sub.3                                                                             CH.sub.3                                                                              CH    201 to 203                                                                     dec.                                  4     CH.sub.3  H     Cl    OCH.sub.3                                                                             CH    195 to 200                            5     CH.sub.3  H     OCH.sub.3                                                                            CH.sub.3                                                                              N     189 to 191                            6     CH.sub.3  H     OCH.sub.3                                                                            OCH.sub.3                                                                             N     191 to 194                            7     CH.sub.3  H     OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                            N     180 to 186                            8     CH.sub.2 CH.sub.3                                                                        H     OCH.sub.3                                                                            OCH.sub.3                                                                             CH    203 to 207                            9     CH.sub.2 CH.sub.3                                                                        H     CH.sub.3                                                                             OCH.sub.3                                                                             CH    182 to 186                            10    CH.sub.2 CH.sub.3                                                                        H     CH.sub.3                                                                             CH.sub.3                                                                              CH    191 to 196                            11    CH.sub.2 CH.sub.3                                                                        H     Cl    OCH.sub.3                                                                             CH    165 to 170                            12    CH.sub.2 CH.sub.3                                                                        H     CH.sub.3                                                                             OCH.sub.3                                                                             N     188 to 192                            13    CH.sub.2 CH.sub.3                                                                        H     OCH.sub.3                                                                            OCH.sub.3                                                                             N     178 to 182                            14    CH(CH.sub.3).sub.2                                                                       H     OCH.sub.3                                                                            OCH.sub.3                                                                             CH    190 to 193                            15    CH(CH.sub.3).sub.2                                                                       H     CH.sub.3                                                                             OCH.sub.3                                                                             CH    190 to 192                            16    CH(CH.sub.3).sub.2                                                                       H     CH.sub.3                                                                             CH.sub.3                                                                              CH    172 to 176                            17    CH(CH.sub.3).sub.2                                                                       H     Cl    OCH.sub.3                                                                             CH    155 to 160                            18    CH(CH.sub.3).sub.2                                                                       H     CH.sub.3                                                                             OCH.sub.3                                                                             N     176 to 180                            19    CH(CH.sub.3).sub.2                                                                       H     OCH.sub.3                                                                            OCH.sub.3                                                                             N     178 to 183                            20    CH.sub.3  Cl    OCH.sub.3                                                                            OCH.sub.3                                                                             CH    197 to 200                            21    CH.sub.3  Cl    CH.sub.3                                                                             CH.sub.3                                                                              CH    153 to 160                            22    CH.sub.3  Cl    Cl    OCH.sub.3                                                                             CH    175 to 183                            23    CH.sub.3  Cl    OCH.sub.3                                                                            CH.sub.3                                                                              N     182 to 184                                                                     dec.                                  24    CH.sub. 3 Cl    OCH.sub.3                                                                            OCH.sub.3                                                                             N     183 to 187                            ______________________________________                                          ##STR36##                                                                     CMPD  R        X        Y      Z     m.p. (°C.)                         ______________________________________                                         25    CH.sub.3 OCH.sub.3                                                                               OCH.sub.3                                                                             CH    195 to 200                                26    CH.sub.3 CH.sub.3 OCH.sub.3                                                                             CH    178 to 179                                27    CH.sub.3 CH.sub.3 CH.sub.3                                                                              CH    179 to 180                                28    CH.sub.3 Cl       OCH.sub.3                                                                             CH    185 to 222                                29    CH.sub.3 CH.sub.3 OCH.sub.3                                                                             N     182 to 184                                30    CH.sub.3 OCH.sub.3                                                                               OCH.sub.3                                                                             N     186 to 188                                31    CH.sub.2 CH.sub.3                                                                       OCH.sub.3                                                                               OCH.sub.3                                                                             CH    163 to 167                                32    CH.sub.2 CH.sub.3                                                                       CH.sub.3 OCH.sub.3                                                                             CH    168 to 170                                33    CH.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                              CH    161 to 163                                34    CH.sub.2 CH.sub.3                                                                       Cl       OCH.sub.3                                                                             CH    160 to 163                                35    CH.sub.2 CH.sub.3                                                                       CH.sub.3 OCH.sub.3                                                                             N     180 to 182                                36    CH.sub.2 CH.sub.3                                                                       OCH.sub.3                                                                               OCH.sub.3                                                                             N     110 to 120 dec.                           ______________________________________                                          ##STR37##                                                                     CMPD  R        X        Y      Z     m.p. (°C.)                         ______________________________________                                         37    Cl       OCH.sub.3                                                                               OCH.sub.3                                                                             CH    175 to 178                                38    Cl       CH.sub.3 OCH.sub.3                                                                             CH    165 to 170                                39    Cl       CH.sub.3 CH.sub.3                                                                              CH    140 to 148                                40    Cl       Cl       OCH.sub.3                                                                             CH    160 to 164                                41    Cl       CH.sub.3 OCH.sub.3                                                                             N     138 to 147                                42    Cl       OCH.sub.3                                                                               OCH.sub.3                                                                             N     165 to 169                                43    OCH.sub.3                                                                               OCH.sub.3                                                                               OCH.sub.3                                                                             CH    182 to 185                                44    OCH.sub.3                                                                               CH.sub.3 OCH.sub.3                                                                             CH    158 to 161                                45    OCH.sub.3                                                                               CH.sub.3 CH.sub.3                                                                              CH    184 to 188                                46    OCH.sub.3                                                                               Cl       OCH.sub.3                                                                             CH    170 to 173                                47    OCH.sub.3                                                                               CH.sub.3 OCH.sub.3                                                                             N     143 to 147                                48    OCH.sub.3                                                                               OCH.sub.3                                                                               OCH.sub.3                                                                             N     160 to 164                                49    CN       OCH.sub.3                                                                               OCH.sub.3                                                                             CH    175 to 178                                50    CN       CH.sub.3 OCH.sub.3                                                                             CH    169 to 170                                51    CN       CH.sub.3 CH.sub.3                                                                              CH    175 to 178                                52    CN       Cl       OCH.sub.3                                                                             CH    158 to 160                                53    CN       CH.sub.3 OCH.sub.3                                                                             N     159 to 161                                54    CN       OCH.sub.3                                                                               OCH.sub.3                                                                             N     168 to 170                                55    H        OCH.sub.3                                                                               OCH.sub.3                                                                             CH    167 to 170 dec.                           56    H        OCH.sub.3                                                                               CH.sub.3                                                                              CH    177 to 178 dec.                           57    H        CH.sub.3 CH.sub.3                                                                              CH    170 to 171 dec.                           58    H        Cl       OCH.sub.3                                                                             CH    166 to 168 dec.                           59    H        CH.sub.3 OCH.sub.3                                                                             N     164 to 165 dec.                           60    H        OCH.sub.3                                                                               OCH.sub.3                                                                             N     167 to 169 dec.                           ______________________________________                                          ##STR38##                                                                     CMPD    R      X         Y      Z    m.p. (°C.)                         ______________________________________                                         61      H      OCH.sub.3 OCH.sub.3                                                                             CH   184 to 192                                62      H      CH.sub.3  OCH.sub.3                                                                             CH   196 to 200                                63      H      CH.sub.3  CH.sub.3                                                                              CH   187 to 190                                64      H      Cl        OCH.sub.3                                                                             CH   175 to 179                                65      H      CH.sub.3  OCH.sub.3                                                                             N    166 to 170                                66      H      OCH.sub.3 OCH.sub.3                                                                             N    180 to 185                                67      Cl     OCH.sub.3 OCH.sub.3                                                                             CH   169 to 175                                68      Cl     CH.sub.3  OCH.sub.3                                                                             CH   202 to 204                                69      Cl     CH.sub.3  CH.sub.3                                                                              CH   180 to 184                                70      Cl     Cl        OCH.sub.3                                                                             CH   180 to 193                                71      Cl     CH.sub.3  OCH.sub.3                                                                             N    168 to 172                                72      Cl     OCH.sub.3 OCH.sub.3                                                                             N    182 to 186                                ______________________________________                                          ##STR39##                                                                     CMPD     X         Y         Z    m.p. (°C.)                            ______________________________________                                         73       OCH.sub.3 OCH.sub.3 CH   206 to 208                                   74       CH.sub.3  OCH.sub.3 CH   204 to 206                                   75       CH.sub.3  CH.sub.3  CH   179 to 182                                   76       Cl        OCH.sub.3 CH   197 to 201                                   77       CH.sub.3  OCH.sub.3 N    190 to 194                                   78       OCH.sub.3 OCH.sub.3 N    198 to 201                                   ______________________________________                                          ##STR40##                                                                     CMPD     X        Y        Z     m.p. (°C.)                             ______________________________________                                         79       OCH.sub.3                                                                               OCH.sub.3                                                                               CH    179 to 181 dec.                               80       CH.sub.3 OCH.sub.3                                                                               CH    148 to 163 dec.                               81       CH.sub.3 CH.sub.3 CH    145 to 160 dec.                               82       Cl       OCH.sub.3                                                                               CH    140 to 151 dec.                               83       CH.sub.3 OCH.sub.3                                                                               N     140 to 150 dec.                               84       OCH.sub.3                                                                               OCH.sub.3                                                                               N     156 to 164 dec.                               ______________________________________                                          ##STR41##                                                                     CMPD     X         Y         Z    m.p. (°C.)                            ______________________________________                                         85       OCH.sub.3 OCH.sub.3 CH   179 to 182                                   86       CH.sub.3  OCH.sub.3 CH   176 to 179                                   87       CH.sub.3  CH.sub.3  CH   194 to 197                                   88       Cl        OCH.sub.3 CH   167 to 170                                   89       CH.sub.3  OCH.sub.3 N    157 to 160                                   90       OCH.sub.3 OCH.sub.3 N    173 to 177                                   ______________________________________                                    

Test A

Seeds of crabgrass (Digitaria spp.), barnyardgrass (Echinochloa crus-galli), giant foxtail (Setaria faberi), wild oats (Avena fatua), cheatgrass (Bromus secalinus) or downy brome (Bromus tectorum), velvetleaf (Abutilon theophrasti), morningglory (Ipomoea spp.), cocklebur (Xanthium pensylvanicum), sorghum, corn, soybean, sugarbeet, cotton, rice, wheat, barley and purple nutsedge (Cyperus rotundus) tubers were planted and treated preemergence with the test chemicals dissolved in a non-phytotoxic solvent. At the same time, these crop and weed species were treated with a soil/foliage application. At the same time of treatment, the plants ranged in height from 2 to 18 cm. Treated plants and controls were maintained in a greenhouse for sixteen days, after which all species were compared to controls and visually rated for response to treatment. The ratings, summarized in Table A, are based on a numerical scale extending from 0=no injury, to 10=complete kill. The accompanying descriptive symbols have the following meanings:

C=chlorosis/necrosis

B=burn

D=defoliation

E=emergence inhibition

G=growth retardation

H=formative effect

U=unusual pigmentation

X=auxillary stimulation

S=albinism

6Y=abscised buds or flowers.

    TABLE A       CMPD 1 CMPD 2 CMPD 3 CMPD 4 CMPD 5 CMPD 6 CMPD 7 CMPD 8 CMPD 9 CMPD 10  R      ATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01      0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         POSTEMERGENCE  COTTON 9C 9C 9C 5C,9G 9C 5C,9G 9C 4C,9H 9C 4C,96 5C,9G 5      C,9G 4C,9G 4C,9G 5C,9G 9C 5C,9G 6G 4C,9G 2G MORNINGGLORY 10C 10C 10C 10C      10C 2C,7G 10C 10C 10C 5C,9G 5C,9G 5C,9G 9C 5C,9G 10C 2C,6G 10C 10C 3C,6G      1C,1H COCKLEBUR 9C 9C 10C 10C 10C 10C 10C 10C 10C 10C 5C,9G 3H,6G 5C,9G      1H 10C 10C 10C 9C 9C 4C,9G NUTSEDGE 9C 9C 9C 3C,8G 9C 9C 9C 5C,9G 4C,9G      8G 2C,2G 0 3C,9G 3C,5G 5C,9G 4C,9G 5C,9G 4C,9G 4C,9G 2C,5G CRABGRASS 0 0      3G 0 6G 5G 3G 0 0 0 0 0 2G 0 0 0 0 0 3G 0 BARNYARDGRASS 9C 9C 9C 3C,9H      9C 5C,9H 3C,9H 6H 0 0 0 0 3C,8H 3G 9C 3C,9H 4C,9H 3C,7G 2C,2G 0 WILD      OATS 6G 2G 5C,9G 6G 4C,9G 4C,9G 6G 0 0 0 0 0 2G 0 4G 2G 2C,3G 0 3C,5G 0      WHEAT 7G 6G 5C,9G 7G 5C,9G 9G 5G 0 0 0 0 0 0 0 2G 0 2G 0 3C,5G 0 CORN 9G      2C,9G 5U,9G 3C,9G 8U,9C 4U,9G 8H 3H,4G 3C,9G 3H 3C,8H 0 4C,9G 3C,8G      3C,6H 2C,4G 3C,8H 3C,6G 3C,7G 3C,6G SOYBEANS 9C 9C 9C 9C 9C 9C 5C,9G      3C,5G 5C,9G 5C,9G 5C,9G 5C,9G 3C,8G 4C,9G 9C 4C,9G 10C 3C,8H 4C,9G 4C,9G      RICE 9C 5C,9G 5C,9G 3C,7G 6C,9G 6C,9G 3C,8G 5G 0 0 0 0 3C,7G 6G 4C,9G      3C,5G 3C,9G 7G 7G 2C,4G SORGHUM 6G 5G 4C,9G 4C,9G 9C 6C,9G 8H 2C,8G 2G 0      2G 0 7G 2C,2G 4C,8H 3C,7G 3C,9G 3C,8H 3C,7G 2C,4G CHEATGRASS 9G 7G 4C,9G      5C,9G 9C 5C,9G 9G 5G 0 0 0 0 10C 10C 10C 10C 9C 3C,7G 4C,9G 9C SUGARBEETS       -- 9C 10C 9C 9C 5C,9G 10C 9C 10C 10C 10C 9C 5C,9G 4C,8H 10C 9C 9C 5C,9G      3C,7G 3C,7G VELVETLEAF 10C 9C 10C 5C,9G -- 10C 10C 9G -- 5C,9H 9C 5C,9H      3G 0 3C,7G 2G 3C,7G 0 2G 0 GIANT FOXTAIL 2C,7G 3G 5C,9G 7G 4C,9G 5G 5G 0      0 0 0 0 2C,2G 0 3C,6G 3G 2C,5G 2C,2G 3C,5G 2C,4G BARLEY 8G 6G 4C,9H      2C,7G 5C,9G 9G 6G 2G 0 0 2C,5G 0 0 0 3C,8G 2C,3G 4C,8G 3C,4G 3C,7G 2C,4G      DOWNY BROME  PREEMERGENCE  COTTON 9G 2G 3C,8G 0 9G 5H 3C,7G 7G 8H 4G      3C,7G 2G 5G 3G 7G 0 1C 7G 2G 0 MORNINGGLORY 9H 2C,4G 3C,8G 0 9G 9G 9G 9G      9G 8G 9G 3C,7G 9G 1C 2C,5H 7G 9G 3C,3H 7G 2G COCKLEBUR 2C,7G 2C,7G 3C,4H      -- 9G 3C,5H 3C,6H 3C,8G 8H -- 5G 2G 3G 1C 3C,8H 3C,5H 9H 3C,7H 8H 3C,5H      NUTSEDGE 9G 3G 9G 5G 10E 5G 10E 8G -- 0 0 0 0 0 0 10E 10E 0 3G 0      CRABGRASS 2G 0 5G 0 5G -- 2G 0 3G 0 0 0 2C,4G 0 2C,3G 0 3C,3G 0 3G 0      BARNYARDGRASS 8H 6G 9H 3H 9H 2C 3C,7H 0 0 0 0 0 3C,7G 0 3C,4G 0 3C,7H 2G      6G 0 WILD OATS 2C,6G 3G 3C,5G 2C,3G 2C,8G 3C,7G 2C,3G 0 0 0 0 0 3G 2G      2C,5G 2G 2C,5G 3G 4G 0 WHEAT 8G 5G 3C,8G 5G 3C,9H 2C,8G 2G 2G 0 0 0 0 0      0 3G 0 4G 0 2G 0 CORN 2C,9H 2C,6G 3C,8H 3C,6H 9G 4C,8G 3C,7H 2C,2G 7G 2G      3C,8G 2G 9G 3C,6G 3C,9H 2C,2G 3C,9G 3C,5G 3C,9G 3C,5H SOYBEANS 3C,9H 4H      3C,7H 3C,6H 9H 3C,7H 3C,4G 0 4C,8H 3C,5G 3C,7H 3C,3H 3C,9H 7H 8H 3C,7H      3C,8H 3C,7G 9H 3C,6H RICE 9G 6G 9H 2G 10E 9H 9G 7G 2G 0 0 0 8G 5G 8G      2C,4G 8H 5G 7H 3G SORGHUM 3C,8H 0 3C,9H 7H 10E 9H 3C,9G 2C,7G 3C,5G 0 2G      0 3C,8H 3G 8H 2C,2G 3C,9H 3C,5G 9H 2C,3G CHEATGRASS 3C,8G 5G 8G 5G 9H 7G      7G 0 5G 0 0 0 5C,9G 8H 9G 7G 8G 8G 9G 9G SUGARBEETS 9G 9G 3C,9G 9G 9G 8G      3C,9G 3C,9G 5C,9G 7G 5C,9G 8G 2C,8G 3H 8H 3C,5H 8H 3C,6G 7G 3H VELVETLEAF       9G 7G 4C,9G 3H 9G 8H 9G 8H 8G 6G 2C,5G 2G 0 0 2C,4G 0 4G 2G 2G 0 GIANT      FOXTAIL 8G 0 9H 3G 9H 3G 7G 0 2G 0 0 0 2C,2G 1C 0 0 3C,7G 3G 3C,8G 3G      BARLEY 8G 6G 8G 2C,7G 9G 9G 3C,7G 2G 2G 0 0 0 3G 2G 9H 2C,5G 3C,8G 5G 6G      2C,5G DOWNY BROME        CMPD 11 CMPD 12 CMPD 13 CMPD 14 CMPD 15 CMPD 16 CMPD 17 CMPD 18 CMPD      19 CMPD 20  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0      .05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         POSTEMERGENCE  COTTON 9H 3C,86 10C 5C,9G 5C,9G 4C,9G 7G 7G 9H 7G 7G      5G 6G 4G 4C,8G 3C,7H 3C,8G 3G  9C 5C,9G MORNINGGLORY 10C 9C 10C 10C 10C      10C 3C,8G. 5C,9G 10C 5C,9H 3C,8H 2C,5G 3C,8H 2H 9C 3C,9H 4C,9G 4C,8H 10C      10C COCKLEBUR 9C 9C 10C 10C 10C 5C,9G 4C,9G 4C,9H 5C,9G 4C,9H 3C,9H      3C,6H 4C,9H 3C,8H 9C 3C,9H 5C,9G 3C,9H 10C 9C NUTSEDGE 10C 5C,9G 3C,7G      4G 9C 0 3C,9G 4C,9G 8G 3G 0 0 2G 0 0 0 0 0 9C 0 CRABGRASS 3G 0 0 0 0 0 0      0 0 2G 0 0 0 0 0 0 0 0 5G 0 BARNYARDGRASS 2C,5G 2H 0 0 0 0 3C,8H 3G 7G      3H 2C,5G 0 4G 5G 0 0 0 0 9C 3C,9G WILD OATS 0 0 0 0 0 0 4G 0 6G 2G 7G 0      0 0 0 0 0 0 5G 0 WHEAT 0 0 0 0 0 0 2G 0 3G 0 2G 0 0 0 0 0 0 0 8G 2G CORN      3C,4G 2G 3C,6G 0 2C,3G 0 4G 3G 3C,7G 2G 3C,3G 1C 0 0 2H 0 0 0 4U,9G      3C,8G SOYBEANS 4G 1H 9C 4C,9G 5C,9G 4C,9G 3C,9G 4C,9G 5C,9G 3C,6H 3C,5G      2C,3H 2G 1H 3C,8H 3C,6H 3C,8G 3C,5H 9C 9C RICE 2C,5G 1C 0 0 1C 0 4G 2G      5G 4G 3C,5G 0 2C,3G 0 0 0 0 0 3C,8G 5G SORGHUM 3C,7G 2C,4G 2G 2G 0 2G 3G      0 3C,4G 2G 3G 0 0 0 0 0 0 2G 9C 3C,9G SUGARBEETS 10C 3C,8G 10C 10C 10C      9C 3C,7H 4G 3C,5G 5G 2G 0 4G 0 5C,9G 4C,8G 4C,9G 3C,8H 10C 10C VELVETLEAF       10C 5C,9H 9C 5C,9G 9C 3C,8G 4C,9G 2C,8G 4C,9G 2H 5G 0 7G 0 4C,9H 8G      3C,8H 3C,7H 10C 8G GIANT FOXTAIL 2G 0 0 0 0 0 3C,7G 0 3G 2G 5G 0 0 0 0 0      0 0 3C,6G 2G BARLEY 0 0 0 0 2G 0 3G 0 5G 0 4G 0 0 0 0 0 0 0 3C,6G 3G      DOWNY BROME 3C,7G 0 0 0 0 0   CHEATGRASS     -- -- 8G 0 5G 5G 0 0 0 0 0      0 0 0 5C,9G 2C,7G  PREEMERGENCE  COTTON 3G 3G 4C,9G 6G 7H 2C,5G 0 0 0 0      2G 0 2G 0 3G 0 2G 0 3G 0 MORNINGGLORY 5G 4G 9G -- 9G 3C,3G 0 0 8H 0 1H 0      0 0 7G 0 3C,4H 2G 9G 2G COCKLEBUR 3C,4H 3C,5H 8H 3C,5H 7H 3C,3G 2H 0 7H      2C,3H 1H 0 2G 0 8H 0 2C,2H 0 3C,8H 5G NUTSEDGE 10E 0 0 0 7G 0 0 0 0 8G 0      0 0 0 0 0 0 0 9G 8G CRABGRASS 0 2C,5G 0 1C 0 0 0 0 0 0 0 0 0 0 0 0 0 0      3G 0 BARNYARDGRASS 0 0 0 0 0 0 0 0 2G 0 0 0 0 0 0 0 0 0 0 0 WILD OATS 2G      0 0 0 0 0 3G 0 5G 2G 6G 0 0 0 0 0 0 0 3G 0 WHEAT 0 0 0 0 0 0 0 0 4G 2G      5G 0 0 0 0 0 0 0 3C,5G 0 CORN 2C,5G 0 3C,7G 3C,3G 2C,4G 0 0 0 3C,7G      2C,3G 3C,7G 0 2C,5G 0 2C,5G 0 0 0 3C,9G 2C,5G SOYBEANS 0 0 9H 3C,8G      4C,8G 3C,8H 0 0 3C,7H 2G 0 0 0 0 3C,7G 0 3C,3H 2C,2H 3C,4H 0 RICE 7G 4G      0 0 0 0 4G 0 6G 2G 3G 0 2G 0 0 0 0 0 3C,8G 0 SORGHUM 7G 0 7G 0 0 0 0 0      2C,5G 2G 0 0 0 0 0 0 0 0 3C,9G 2G SUGARBEETS 9G 8G 5C,9G 5C,9G 5C,9G      5C,9G 3G 0 4H 4G 7G 2G 5G 0 8G 0 7G 5H 9G 7G VELVETLEAF 5H 3C,5H 7H      3C,5G 8G 2C,3G 0 0 0 0 0 0 0 0 3G 0 2C,2H 0 5C,9G 3H GIANT FOXTAIL 2G 2G      0 0 0 0 0 0 2G 0 0 0 0 0 0 0 0 0 2G 0 BARLEY 0 0 0 1C 0 0 0 0 6G 0 4G 0      0 0 0 0 0 0 3C,7G 2C DOWNY BROME 3G 2G 0 3G 0 0 -- -- CHEATGRASS     --      -- 0 0 7G 3G 5G 0 0 0 0 0 0 0 7G 0        CMPD 21 CMPD 22 CMPD 23 CMPD 24  CMPD 25 CMPD 26 CMPD 27 CMPD 28 CMPD      29 CMPD 30  RATE=KG/HA  0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05      0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         POSTEMERGENCE  COTTON 10C 3C,6G 9C 5G 4C,9G 4C,9G 5C,9G 0 10C 9C      3C,7G 4C,9G 6G 9C 2C,7G 9C 5C,9G 9C 5C,9G MORNINGGLORY 10C 3C,7H 10C      3C,8G 5C,9H 3C,7G 5C,9H 3C,4G 10C 10C 4C,8G 9C 3C,7G 10C 9C 5C,9G 5C,9G      9C 5C,9G COCKLEBUR 10C 3C,8H 10C 2C,9G 3C,9H 2C,4G 2C,7G 1C,3G 9C 10C      5C,9G 10C 4C,9G 10C 9C 10C 9C 10C 5C,9G NUTSEDGE 5C,9G 9G 8G 0 3G 3G 0 0      9C 9C 2C,9G 5C,9G 4C,9G 9C 9C 2C,6G 3G 9C 4C,7G CRABGRASS 4G 0 0 2G 0 2G      0 0 2G 6G 2G 7G 4G 2G 0 6G 0 0 0 BARNYARDGRASS 5C,9G 2C,8H 1C,5H 2G 9C      4C,8H 3C,9H 3C,7H 5C,9H 9C 4C,9H 9C 4C,9H 3C,8H 5H 0 0 2H 0 WILD OATS      2C,7G 5G 3G 0 8G 2C,3G 2C,6G 2G 9G 4C,9G 8G 6C,9G 2C,9G 6G 0 0 0 0 0      WHEAT 9G 3G 0 0 5G 3G 2G 0 9G 4C,9G 9G 5C,9G 3C,9G 5G 0 0 0 0 0 CORN      3C,9G 2C,7H 2C,7H 2G 3C,8G 3C,7H 2C,8G 3C,4G 9G 6U,9G 2C,8G 7U,9C 3C,9G      3C,8H 5H 5U,9H 6H 3C,8H 0 SOYBEANS 9C 9C 6C,9G 2C,6G 6C,9G 4C,9G 4C,9G      3C,8G 9C 5C,9G 5C,9G 9C 9C 4C,8H 2H 5C,9G 4C,9G 5C,9G 5C,9G RICE 8G 5G      2G 2G 4G 2G 2G 0 9C 9C 3C,8G 9C 5C,9G 3C,8G 2G 2C,2G 0 0 0 SORGHUM 5C,9G      9G 9G 2C,8H 6C,9G 3C,8G 3C,9G 8G 2C,7H 4C,9G 2C,9G 4C,9G 4C,9G 4C,9G      3C,7G 4C,9G 4G 2G 0 CHEATGRASS 4C,9G 9G 6G 6G 5C,9G 8G 3C,9G 8G 6C,9G 9C      4C,9G 9C 5C,9G 5C,9G 8G 6G 0 0 0 SUGARBEETS 5C,9G 10C 9C 3C,7G 5C,9G      3C,6G 9C 5C,9G 10C 10C 9C 9C 10C 9C 10C 9C 9C 10C 9C VELVETLEAF 10C 9G      9C 2C,7G 3C,8G --   10C 10C 5C,9G 9C 8G 9C 7G -- -- 10C 4C,9G GIANT      FOXTAIL 8G 4G 2G 0 6G 3G 6G 0 4C,8G 5C,9G 3C,8G 5C,9G 3C,8G 4G 0 5G 0 0      0 BARLEY 9G 6G 4G 0 0 0 2G 0 3G 3C,9G 3C,9G 5C,9G 2C,9G 3C,7G 2G 0 0 0 0       PREEMERGENCE  COTTON 1C 0 6G 0 8G 0 2G 0 9G 9H 2C,7G 9G 7G 5G 7G 9G 5G      3C,8G 5G MORNINGGLORY 5G 5G 9G 4G 9G 2C,6G 2C,4G 1C,5G 9G 9H 8G 9G 5G 9H      8G 9G 9G 9G 5G COCKLEBUR 3C,7H 3C,7H 8G 6G 9G 6G 2C,6G 5G 7G 9H 3C,7H 9H      7G 9H 8H 9H 7H 3C,7H 1C NUTSEDGE 10E 3G 10E 0 8G 0 5G 2G 5G 9G -- 10E 9G      9G 4G 10E 0 0 0 CRABGRASS 2G 0 0 -- 4G 2G 3G -- 5G 4G 0 5G 0 0 0 0 0 0 0      BARNYARDGRASS 4G 0 0 0 4G 0 0 0 8H 9H 9H 9H 8H 7H 0 2G 0 0 0 WILD OATS      2C,5G 0 0 0 0 0 0 0 3G 3C,8G 3C,8G 2C,8G 3C,5G 4G 0 0 0 0 0 WHEAT 3C,9G      0 0 0 2G 0 0 0 6G 8G 2C,5G 3C,9H 7G 5G 0 0 0 0 0 CORN 9G 2C,8G 2G 0      4C,7H 0 1C 0 8H 2C,9G 3C,7H 2C,9G 2C,9G 3C,7G 2G 8G 3C,6G 3C,8H 7G      SOYBEANS 9H 1C,4G 0 0 4C,8H 0 2C,2G 0 9H 4C,8H 3C,4H 9H 8H 0 0 9H 2C,7G      9H 3C,5G RICE 5C,8H 2G 3G 0 5C,8H 0 2C,4G 0 8G 3C,9G 8G 9H 9H 8H 3G 2G 0      2G 0 SORGHUM 9H 2C,7H 2C,8G 0 4C,8H 3C,7H 4C,9G 3C,5G 9G 2C,9G 3C,9G 9H      10H 3C,8H 0 2C,8G 0 3G 0 CHEATGRASS 9G 2G 6G 0 4G 0 0 0 9G 3C,9G 8G 9H      8H 7H 2G 3G 0 0 0 SUGARBEETS 9G 9G 3C,9G 0 5C,9G 3C,8G 4C,9G 4G 8G 9G 9G      9G 7G 9C 7G 4C,9G 8H 4C,9G 3C,8G VELVETLEAF 3G 0 8G 0 2C,4G 0 2C,3G 2G      9G 9G 3C,8H 9G 8H 4C,9G 8G 5C,9G 7H 5C,9G 3C,7G GIANT FOXTAIL 7G 6G 5G      4G 3C,8H 2G 7G 3G 8G 9H 8H 9H 3H 2G 0 0 0 0 0 BARLEY 9G 4G 1C,5G 0 2C,4G      2G 4G 0 9G 8G 2C,8G 9G 8G 2C,6G 0 3C 0 2C 0        CMPD 31 CMPD 32 CMPD 33 CMPD 34 CMPD 35  CMPD 36 CMPD 37 CMPD 38 CMPD      39 CMPD 40  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0      .05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         POSTEMERGENCE  COTTON 9C 9G 3C,9G 3C,9G 3C,9G 2C,9G 4C,9G 2C,9G 5C,9G 4      C,9G 5C,9G 4C,9G 5C,9G 9C 9C 5C,9G 9C 5C,9G 9C 5C,9G MORNINGGLORY 10C      3C,8G 10C 10C 10C 4C,9G 9C 3C,8G 10C 9C 5C,9G 5C,9G 10C 10C 9C 10C 10C      4C,9G 10C 9C COCKLEBUR 10C 4C,9G 9C 4C,9G 9C 3C,9H 10C 4C,9G 10C 9C 9C      9C 10C 10C 9C 3C,8G 9C 4C,9G 10C 9C NUTSEDGE 9C 9C  9C 9C 9C  3C,8G -- 0       0 2C,9G 4C,9G 2C,9G 2C,9G 2C,9G 9G 4C,9G 9G CRABGRASS 5G 0 2G 5G 3C,7G      0 3C,7G 0 0 0 0 0 4G 2G 3G 0 3C,7G 5G 4G 0 BARNYARDGRASS 4C,9H 3C,5G      4C,9H 8H 9H 7H 3C,8H 2C,3G 0 0 0 0 9C 5C,9G 5C,9G 4C,8H 9C 5C,9G 9C      5C,9G WILD OATS 0 0 3C,7G 2C,3G 3C,7G 2C 0 0 0 0 0 0 5C,9G 2C,8G 3C,7G      3G 4C,9G 9G 2C,9G 3C,7G WHEAT 2G 0 7G 3G 9G 4G 2G 0 0 0 0 0 6C,9G 5C,9G      8G 5G 5C,9G 8G 9G 8G CORN 3C,8G 3G 3C,9H 3C,8G 3C,9H 3C,7G 3G 0 4G 0 2G      0 4U,9G 4U,9G 3C,9H 3C,6H 3C,7G 2G 3C,8H 3C,7H SOYBEANS 4C,9G 3C,8G      3C,9G 3C,6H 3C,9G 8H 2H 0 4C,9G 5C.,9G 5C,9G 4C,9G 9C 9C 5C,9G 4C,9G      5C,9G 5C,9G 5C,9G 2C,7G RICE 3C,9G 7G 3C,9G 8G 5C,9G 8G 7G 2C,4G 0 0 0 0      5C,9G 9C 7G 5G 9C 4C,9G 5C,9G 2C,7G SORGHUM 3C,9G 3C,7G 9G 3C,9G 2C,9G      3C,8G 2C,8G 2G 2G 0 2G 0 5C,9G 6C,9G 4C,8G 3C,7G 5C,9G 4C,9G 5C,9G 4C,9G      CHEATGRASS 4C,9G 7G 3C,9G 5G 5C,9G 8G 8G 0 0 0 0 0 6C,9G 3C,9G 4C,9G      3C,9G 6C,9G 9G 5C,9G 3C,9G SUGARBEETS 10C 2C,8G 9C 3C,8G 10C 3C,8G 3C,9G      3C,8G 9C 4C,9G 10C 9C 9C 5C,9G 5C,9G 4C,9H 9C 4C,9H 9C 9C VELVETLEAF 10C      5C,9G 10C 5C,9G 5C,9G 8G 9C 3C,8G 10C 9C 9C 9C 10C 10C 10C 9C 10C 9C 10C      4C,8H GIANT FOXTAIL 3C,6G 0 3C,7G 2G 3C,6G 2G 3C,7G 1C 2G 0 0 0 9C 4C,9G      3C,9G 4C,8G 9C 4C,9G 4C,9G 7G BARLEY 2C,2G 0 9G 7G 2C,9G 8G 0 0 0 0 0 0      3C,9G 2C,9G 2C,5G 3G 3C,9G 7G 3C,8G 4G

      CMPD 31 CMPD 32 CMPD 33 CMPD 34 CMPD 35 CMPD 36 CMPD 37 CMPD 38 CMPD 39 C      MPD 40  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01      0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         PREEMERGENCE  COTTON 2G 1C 8G 7G 7G 0 2G 0 2C,9G 3G 9G 3G 9G 8G 4G 0      9G 7G 4C,9G 9G MORNINGGLORY 2C,3H 0 8H 3C,5G 2C,2G 0 7H 1H 9G 3H 9G 3G      9G 4G 4G 0 9G 8H 9G 9G COCKLEBUR 8H 2C,3H 9H 3C,7H -- 2C,2H 8H 2C,5G 9H      3C,5G 9H 3C,6H 8H 10E 0 0 9H 3C,5H 8H 3C,6H NUTSEDGE 10E 0 10E 0 8G 0      10E 0 10E 0 4G 0 10E 0 4G 0 9G 10E 10E 9G CRABGRASS 0 0 2C,5G 0 2C,4G 4G      0 0 0 0 2G 0 4G 2G 2G 0 6G 2G 6G 3G BARNYARDGRASS 3H 0 9H 6G 9H 3C,5G 2G      0 0 0 2G 0 9H 3G 3G 0 9H 3C,5G 9H 3G WILD OATS 0 0 3C,8G 3G 7G 1C 0 0 0      0 0 0 3C,8G 3C,6G 0 0 4C,8H 3C,4G 3C,6G 2C,2G WHEAT 0 0 8H 3G 8G 2G 0 0      0 0 0 0 4C,9H 6G 0 0 3C,9H 7G 8H 8G CORN 4G 0 9H 2C,8G 2C,9G 3C,4G 2G 0      2C,5G 3C,5G 2C,3G 2C,2G 3C,9H 2C,5G 2G 0 2C,6G 5G 3C,8G 5G SOYBEANS      3C,7H 2C,3G 3C,7H 3C,6G 2C,8H 3C,6G 0 0 8H 3C,5G 3C,8H 3C,7G 3C,7H 3C.7G      2C,2G 0 9H 9H 8H 3C,7G RICE 3C,8H 6G 9H 8G 9H 7G 8H 5G 0 0 2G 0 10H 9H      2G 0 9H 10H 9H 9H SORGHUM 9H 2C,5G 3C,9G 3C,9G 9H 2C,8H 2C,5G 4G 5G 4G      2C,2G 2G 4C,9G 2C,8G 3G 0 3C,9H 4C,9H 3C,9H 3C,9H CHEATGRASS 7G 3G 9H 7G      3C,9H 3C,7G 5G 0 0 0 0 0 4C,9H 3G 3G 0 8H 5G 3C,8H 4G SUGARBEETS 3H 8G      8G 3H 8G 7G 8G 3H 3C,9G 4C,9G 5C,9G 3C,8G 5C,9G 4C,8G 7G 0 4C,9G 7G      5C,9G 8G VELVETLEAF 3G 0 7H 0 0 0 5G 1H 5C,9G 0 3C,7H 2G 5C,9G 4C,9G 2H      0 4C,8H 3C,7H 4C,8H 3G GIANT FOXTAIL 0 0 2C,4G 0 4G 2G 0 0 0 0 0 0 4C,8H      3C,7G 0 0 3C,8H 3C,7G 3C,6G 3G BARLEY 5G 0 9G 8G 9G 8G 3G 0 1C 4G 0 0 9G      8G 3G 0 9H 3C,8H 8G 3C,7G        CMPD 41 CMPD 42 CMPD 43 CMPD 44 CMPD 45 CMPD 46 CMPD 47 CMPD 48 CMPD      49 CMPD 50  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0      .05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         POSTEMERGENCE  COTTON 4C,9G 3C,5G 4C,9G 3C,8H 5C,9G 5C,9G 4C,9G 4C,9G 3      C,9G 9G 9C 9G 6G 0 6G 0 9C 10C 10C 3C,9G MORNINGGLORY 5C,9G 3C,9G 10C      4C,9G 9C 10C 10C 9C 9C 5C,9G 6C,9G 5C,9G 4C,8H 2C,2G 4C,8H 0 10C 10C 9C      9C COCKLEBUR 4C,9G 2C,7G 4C,9G 3C,7G 10C 4C,8H 10C 4C,9G 9C 4C,9G 10C      3C,9G 3C,5H 0 2C,3H 1C 10C 10C 3C,7H 2C,4H NUTSEDGE 5G 4G 3C,8G 0 --      4C,9G 4C,9G 9G 9G 9G 9G 3C,9G 4G --  0 -- 4C,9G  7G CRABGRASS 4G 2G      3C,7G 3C,5G 9C 5G 2C,6G 2G 3G 2G 4G 3G 2G 0 2C,4G 2G 5G -- 0 2G BARNYARDG      RASS 5C,9G 5C,9G 4C,9G 4C,9G 9C 9C 5C,9G 3C,9G 4C,9G 4C,8H 9C 9H 3C,4H 0      3C,6H 0 9C 5C,9G 3C,7H 3C,5H WILD OATS 4C,9G 2C,8G 4C,9G 3C,8G 4C,9G      2C,9G 3C,9G 3C,7G 3C,7G 7G 3C,9G 6G 2C,6G 0 2C,6G 2G 9G 5G 4G 2G WHEAT      3C,7G 8G 5C,9G 5C,9G 9C 9C 9G 9G 9G 8G 9G 6G 4C,9G 3G 9G 8G 9G 5G 7 7G      CORN 4C,9G 3C,9G 5C,9G 4C,9G 9C 4C.,9G 4C,9H 3C,6H 2G 0 2C,3G 0 3C,9G 0      3C,9G 2C,4G 5C,9G 4C,9G 4C,8H 1C,3G SOYBEANS 5C,9G 3C,8H 9C 3C,8G 6C,9G      6C,9G 6C,9G 3C,8G 2C,6G 2C,3H 2C,6G 4H 0 0 1C 0 9C 9C 3C,8H 5H RICE      5C,9G 4C,9G 5C,9G 4C,9G 6C,9G 6C,9G 9C 9C 9C 9C 9C 4C,9G 3C,9G 3C,9G      4C,9G 3C,9G 5C,9G 5C,9G 3C,6G 2C,3G SORGHUM 5C,9G 4C,8H 4C,9G 4C,9G 9C      4C,9G 4C,9G 4C,9H 4C,9G 4C,8H 4C,9G 3C,9G 3C,7H 0 3C,7G 2G 4C,9G 4C,9G      3C,7G 4G CHEATGRASS 5C,9G 3C,9G 4C,9G 3C,9G 6C,9G 4C,9G 5C,9G 4C,8G      5C,9G 3C,8G 5C,9G 3C,9G 4C,9G 6G 9G 7G 9C 5C,9G 3C,7G 5G SUGARBEETS 9C      3C,7G 9C 5C,9G 9C 9C 9C 9C 9C 4C,8H 6C,9G 9C 3C,6H 3H 3C,6H 3H 9C 9C 9C      3C,8H VELVETLEAF 3C,7H 2G 4C,8H 4G 10C 10C 10C 5C,9H 5C,9H 4C,8H 2C,7G      4C,8H 0 0 C 0 10C 10C 9C 3C,7G GIANT FOXTAIL 5C,9G 4C,9G 9C 4C,9G 9C      5C,9G 9C 5C,9G 9C 3C,7G 5C,9G 3C,8G 2C,6G 2G 3C,8G 0 9C 4C,9G 3C,7G      2C,5G BARLEY 8G 7G 4C,9G 8G 5C,9G 3C,9G 3C,9G 3C,7G 9G 3C,6G 9G 4G 9G 0      9G 0 2C,7G 0 0 0  PREEMERGENCE  COTTON 6G 2G 3C,7G 2G 9G 9G 5G 2G 2C 0      5G 2G 0 0 0 0 5C,9G 7G 0 0 MORNINGGLORY 9G 0 9G 2C 9H 9H 9G 5G 3C,8H 3G      9G 8H 4G 0 2G 0 9G 8G 4G 0 COCKLEBUR 2G 0 2C,7G 2G 9H 8H 2C,7H 3C,6H 8H      2C,2H 9H 8H 2G 0 4G 0 9H 1C,1H 0 0 NUTSEDGE 0 0 5G 0 10E 10E 10E 0 10E      9G 9G 10E 0 0 0 0 10E 10E 0 0 CRABGRASS 2G 0 5G 0 7G 3G 2G 0 2G 0 0 0 4G      0 2G 0 5G 0 0 0 BARNYARDGRASS 2C,7G 0 4C,8H 4G 9H 9H 4C,7H 4H 3C,7H 2H      4C,8H 2H 0 0 0 0 9H 0 0 0 WILD OATS 3C,7G 2C,2G 3C,7H 2C,2G 4C,8G 3C,7G      3C,6G 2C,3G 2C,3G 0 2C,5G 2G 0 0 0 0 3C,6G 2G 0 0 WHEAT 2C,9G 6G 9H 5G      9H 8H 9H 7H 5G 0 8H 3G 0 0 0 0 7G 0 0 0 CORN 9G 3C,7G 9H 4C,6G 10H 9H      4C,9G 3C,7G 3C,7G 0 4C,7G 4G 3C,6G 0 2C,6G 1C,2G 4C,9G 3C,7G 3G 0      SOYBEANS 9H 2C,2H 3C,7H 2C 9H 9H 9H 4C,7H 2C,5G 0 4C,8H 2C,5G 00 0 0 0      9H 3C,7G 0 0 RICE 10E 6G 10H 9H 10E 10H 10H 3C,6H 4C,8H 0 9H 9H 2C,5G 0      4G 2G 9H 6G 2G 0 SORGHUM 4C,9H 3C,8H 3C,9H 3C,3G 9H 4C,9H 5C,9H 3C,8H      3C,9H 3C,3G 5C,9H 3C,8H 2C,3G 0 0 0 3C,9G 2C,5G 3G 0 CHEATGRASS 4G 0      3C,6G 6G 10E 9H 9H 8H 8H 0 3C,6G 6G 0 0 0 0 4C,8G 0 0 0 SUGARBEETS 7G 2H      3C,9G 4G 9G 9G 3C,9G 9G 9G 8G 9G 8G 2G 2G 0 0 5C,9G 7G 3G 0 VELVETLEAF      2G 0 3G 1H 4C,9G 4C,9G 4C,8H 3C,6H 4C,7H 2C,4H 4C,7H 2C,5H 5G 2H 2G 0      4C,9G 2H 1C 0 GIANT FOXTAIL 3C,7G 5G 4C,8H 3G 3C,8G 3C,8G 3C,8H 5H 5H 6H      7H 7H 4G 0 3C,7H 3G 4C,9H 3G 2G 0 BARLEY 9H 3C,8G 9H 2C,4G 3C,9G 9G 9G      8H 3C,8H 0 9G 8H 0 0 0 0 2C,8G 3C,7G 0 0

      CMPD 51 CMPD 52 CMPD 53 CMPD 54 CMPD 55 CMPD 56 CMPD 57 CMPD 58 CMPD 59 C      MPD 60  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01      0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         POSTEMERGENCE  COTTON 5C,9G 3C,9G 4C,9G 4C,9G 3C,4G 2C,3G 3C,7H 3C      5C,9G 5C,9G 10C 9C 3C,9H 3C,7H 4C,8G 6G 2C,3G 0 5G 0 MORNINGGLORY 9C      4C,9G 10C 5C,9G 4C,9G 1C,2G 2C,2H 1C,1H 10C 2C,7G 9C 2C,4G 2C,2G 0 10C      3C,7H 3C,8G 1H 3C,8H 1C,1H COCKLEBUR 5C,9G 4C,9G 9C 4C,9G 2C,3G 1H 2C,3G      0 10C 9C 10C 5C,9G 9C 1C,3H 3C,7H 4H 3C,8H 2G 3C,8H 2H NUTSEDGE 9G 2C,9G      4C,9G 3C,5G 5G 0 4G 0 10C 9C 6C,9G 3C,8G 4C,9G 3G 5C,9G 3C,7G 0 0 3G 4G      CRABGRASS 2C,2G 0 2C,2G 0 2G 0 3G 0 4C,9G 3G 4G 2G 3G 3G 2G 0 0 0 2G 0      BARNYARDGRASS 4C,9G 3C,8H 5C,9G 4C,9G 3C,6H 2C,3H 3C,7H 0 9C 9C 9H 3C,9H      3C,7H 3C,4H 3C,8H 2H 3C,8H 2H 4C,8H 2C,4H WILD OATS 9G 8G 2C,7G 2G 3G 0      3G 0 3C,8G 3G 9G 3C,6G 9G 5G 0 0 9G 5G 8G 0 WHEAT 9G 2C,9G 8G 3G 9C 6C      9C 6G 8G 0 8G 3G 8G 4G 0 0 4G 0 5G 0 CORN 2C,9H 6G 4C,9H 3C,8G 3C,7G 2G      3C,7H 2G 5C,9G 3C,9H 5C,9G 3C,9H 3C,8H 3G 3C,7H 2C,5G 3C,9H 3C,6H 5C,9G      4G SOYBEANS 5C,9G 4C,9G. 5C,9G 3C,7H 2C,4G 0 3C,5H 2H 9C 5C,9G 9C 5C,9G      5C,9G 4C,9G 3C,7H 4H 4C,9H 4H 3C,8G 4H RICE 5C,9G 3C,6G 5C,9G 2C,3G 5G 0      2C,5G 0 9C 3C,8G 9C 2C,5G 9C 3C,8G 2C,7G 2G 9C 5C,9G 5C,9G 5C,9G SORGHUM      4C,9G 4C,8G 5C,9G 4C,9G 3C,5G 0 3C,7G 2G 9G 3C,8G 3C,8H 3C,7G 4C,9G      3C,9H 4C,9G 3C,8H 4C,9H 3C,6G 3C,9G 3C,7H CHEATGRASS 5C,9G 8G 5C,9G 7G      9G 5G 4C,9G 3G 9C 2C,8G 5C,9G 7G 6C,9G 4C,9G 4G 0 2C,7G 6G 4G 4G      SUGARBEETS 9C 4C,9G 9C 9C 4C,9G 1C 3C,7H 1H 10C 10C 9C 9C 9C 5C,9G 9C      5C,9G 9C 3C,5G 5C,9H 2C,6G VELVETLEAF 9C 3C,8H 10C 9C 0 0 0 0 10C 9C 9C      9C 9C 3C,8H 3C,9G 1C,2H 2C,5G 0 2C,7G 2G GIANT FOXTAIL 4C,9G 3C,9G 3C,7G      6G 2C,6G 0 3C,7G 2G 4C,9G 3C,7G 3C,8G 3C,7G 2C,3G 2G 2C,6G 0 0 0 3G 0      BARLEY 8G 6G 6G 3G 6G 3G 3C,8G 2C,5G 5G 0 5G 0 0 0 0 0 0 0 0 0       PREEMERGENCE  COTTON 9G 3C,5G 3C,7G 3C,4G 2C,2H 0 0 0 8G 3G 2G 0 5G 2G      8G 3G 0 0 0 0 MORNINGGLORY 9G 2H 9C 3C,3G 2C,2H 0 0 0 9G 0 lC,lH 0 0 3G      2C,6G 0 0 0 0 0 COCKLEBUR 7H 2C 9H 0 1H 0 0 0 3C,7H 0 2C 0 1C 0 0 0 0 0      0 0 NUTSEDGE 10E 3C,5G 10E 3G 0 0 0 0 10E 0 9G 9G 9G -- 8G 0 10E 0 0 0      CRABGRASS 2C 0 0 0 0 0 0 0 5G 0 3G 0 0 0 0 0 0 0 0 0 BARNYARDGRASS 3C,8G      0 3C,8H 3G 0 0 0 0 2C,8H 4G 3C,8H 2G 3G 0 7G 0 0 0 0 0 WILD OATS 3C,7G      3C,4G 2C,3G 0 0 0 0 0 3C,6G 2G 3C,5G 1C 2C,7G 0 0 0 0 0 0 0 WHEAT 3C,8H      7G 5G 0 0 0 0 0 5G 0 6G 0 5G 0 0 0 0 0 0 0 CORN 3C,9H 3C,8G 4C,9H 2G 3G      0 2G 0 5C,9G 3C,7G 4C,9H 1C 3G 0 2C,3G 0 1C 0 2C,2G 0 SOYBEANS 9H 4C,8G      4C,8H 3C,6G 0 0 0 0 3C,8H 2C,3H 2C,4H 1C 0 0 1C 0 0 0 1C 0 RICE 9H 3C,4G      4C,9G 2C,7G 3G 0 0 0 9H 8H 9H 2G 6G 0 5G 0 3C,6G 0 5G 0 SORGHUM 3C,9H      3C,7G 5C,9G 4C,8G 2C,2G 0 2G 0 9G 6G 2C,7G 0 4G 0 3C,7G 0 3G 0 2C,5G 0      CHEATGRASS 9G 8G 3C,8H 6G 0 0 0 0 8G 3G 7G 3G 2C,6G 0 0 0 0 0 0 0      SUGARBEETS 3C,9G 3C,6H 4C,9G 3C,7G 3H 2G 2G 0 9G 9G 4C,9G 8G 9G 2G 9G 7G      7G 2G 2H 0 VELVETLEAF 3C,5H 2C,3G -- 2C,2H 0 0 0 0 4C,9G 5H 3C,5H 0      3C,5H 0 2C,3G 0 0 0 0 0 GIANT FOXTAIL 3C,7G 2C,5G 3C,8H 2G 0 0 0 0 9H 3G      7G 0 3G 0 2G 0 0 0 0 0 BARLEY 9G 2G 4C,8G 2C,3G 0 0 0 0 6G 0 2C,6G 0 2G      0 2G 0 0 0 0 0        CMPD 61 CMPD 62 CMPD 63 CMPD 64 CMPD 65 CMPD 66 CMPD 67 CMPD 68 CMPD      69 CMPD 70  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0      .05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01         POSTEMERGENCE  COTTON 10C 10C 10C 9C 10C 10C 10C 5C,9G 10C 5C,9G 10C      5C,9G 5C,9G 2C,8G 5C,9G 3C,8G 5C,9G 3C,8G 7G 5G MORNINGGLORY 9C 10C 10C      10C 10C 9C 10C 10C 10C 9C 9C 10C 5C,9H 3G 3C,7G 3C,3H 1C 0 10C 3C,7G      COCKLEBUR 10C 10C 10C 10C 10C 10C 10C 10C 10C 9C 10C 10C 10C 9C 10C      5C,9G 10C 5C,9G 9C 3C,7G NUTSEDGE 10C 10C 10C 10C 9C 9C 10C 10C 5C,9G 0      5C,8G 3G 6C,9G 9C 9C 9C 3C,8G 5C,9G 5C,9G 4C,8G CRABGRASS 4C,8G 2C,5G      5C,9G 3G 4C,8G 5C,9G 2G 0 4C,8G 0 0 0 0 0 0 0 4G 0 0 0 BARNYARDGRASS 9H      4C,8H 9C 5C,9H 9C 9C 3C,8G 4G 3C,6G 0 5C,9G 3C,5H 3H 2G 0 0 0 0 0 0 WILD      OATS 0 0 6G 2G 3C,8G 5G 0 0 0 0 3G 0 0 0 0 0 0 0 0 0 WHEAT 0 0 6G 2G 8G      5G 0 0 2G 0 0 0 0 0 0 0 0 0 0 0 CORN 3C,6G 3G 5C,9G 3C,9H 10C 9G 0 0      3C,7H 3G 2C,7G 0 0 0 4G 3G 3G 0 0 0 SOYBEANS 4C,9G 5C,9G 9C 5C,9G 9C      5C,9G 4C,9G 2C,7G 9C 5C,9G 9C 9C 5C,9G 5C,9G 4C,9G 3C,8G 4C,9G 2C,8G      2C,3H 0 RICE 3C,7G 3G 4C,9G 3C,7G 5C,9G 4C,9G 3G 0 0 0 0 0 0 0 0 0 2G 2G      0 0 SORGHUM 3C,8G 6G 4C,9G 4C,9G 9C 9C 3C,7G 5G 4,,9G 2G 5G 0 0 0 3C,6G      2G 4G 2G 0 0 CHEATGRASS 3C,7G 5G 9C 8G 9C 5C,9G 5G 0 0 0 0 0 3G 0 0 0 0      0 0 0 SUGARBEETS 10C 10C 10C 10C 10C 10C 9C 10C 10C 10C 10C 9C 9C 10C 9C      3C,7G 4C,9G 3C,6G 3C,8G 7G VELVETLEAF 10C 10C 10C 10C 10C 10C 9C 3C,8G      10C 9C 9C 9C 5C,9G 3C,7G 9C 3C,8G 3C,9G 2C,5G 4C,8G 5G GIANT FOXTAIL      3C,6G 2G 5C,9G 5G 5C,9G 4C,8G 5G 0 3G 0 0 0 0 0 3G 0 0 0 0 0 BARLEY      2C,4G 0 8G 7G 9G 8G 2G 0 5G 0 2G 0 2G 0 3G 0 0 0 0 0  PREEMERGENCE      COTTON 9G 6G 9G 8G 9G 9G 9G 9G 9G 9G 9G 8G 2G 0 2G 0 3G 0 0 0 MORNINGGLOR      Y 9G 5G 9G 6G 9G 9G 9G 9G 9G 9G 9G 9G 0 0 2G 0 0 0 0 0 COCKLEBUR 7H      2C,2G 9H 3C,6H 9H 9H 3C,5H 7G 9H 8H 9H 7H 3C,5H 2C 3C,5H 2C,3G 3C,5G 0      1C 0 NUTSEDGE 10E 8G 10E 3G 10E 10E 10E 9G 10E 3G 3G 0 10E 0 0 0 0 0 5G      0 CRABGRASS 3C,7G 0 3C,8G 3C,6G 8G 3C,7G 2C,5G 0 3C,8G 3G 2G 0 0 0 0 0 0      0 0 0 BARNYARDGRASS 8H 1C 9H 7H 9H 9H 2C,5G 2G 5G 0 5G 0 0 0 3G 0 0 0 0      0 WILD OATS 2G 0 3C,7G 2C,3G 3C,7G 3G 0 0 0 0 0 0 0 0 0 0 0 0 0 0 WHEAT      2G 0 8G 5G 8H 5G 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CORN 3C,6G 0 3C,9H 3C,7G 9G      3C,9G 3C,7G 0 3C,7G 3C,6G 3C,7G 3C,7G 0 0 3C,6G 0 2G 0 2G 0 SOYBEANS      4C,9H 5G 3C,9H 3C,8H 9H 3C,8H 3C,5G 3G 9G 4C,8G 9H 3C,7H 3C,5H 2C,2H      3C,3H 1H 3C,4H 0 2H 0 RICE 8H 0 8G 3C,7G 8G 2C,6G 2C,5G 0 0 0 0 0 0 0 5G      0 4G 0 0 0 SORGHUM 8G 0 3C,9H 3C,8G 10H 3C,9H 3C,7G 4G 8G 55G 5G 3C,4G 0      0 3C,6G 0 7G 0 0 0 CHEATGRASS 4C,9G 2G 5C,8G 8G 9H 9G 0 0 0 0 0 0 0 0 3G      0 0 0 0 0 SUGARBEETS 9G 8G 5C,9G 4C,9G 9G 9G 5C,9G 9G 9G 5C,9G 5C,9G      5C,9G 8G 5G 5G 4G 3H 0 3G 0 VELVETLEAF 4C,8G 3G 4C,9G 7G 9G 9G 8G 5G      5C,9G 5G 4C,8G 4G 4H 0 4H 0 0 0 0 0 GIANT FOXTAIL 3G 0 3C,8G 6G 5G 5G 0      0 3C,5G 0 3G 0 0 0 0 0 0 0 2G 0 BARLEY 3C,7G 0 3C,9G 3C,7G 9G 3C,8G 6G 0      2G 0 0 0 0 0 2G 0 2G 0 0 0        CMPD 71 CMPD 72 CMPD 73 CMPD 74 CMPD 75 CMPD 76 CMPD 77 CMPD 78 CMPD      79 CMPD 80  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0.05 0.01 0      .05 0.01 0.05 0.01 0.05 0.01 0.05 0.01  0.05 0.01         POSTEMERGENCE  COTTON 4C,9G 6G 4C,9G 5G 9C 3C,7H 3C,7G 5G 0 0 0 0 2G      0 7G 0 10C 9C 9C 9C MORNINGGLORY 5C,9G 3C,7G 4C,9G 4C,8G 5C,9G 7G 4C,9H      2C,3H 0 0 0 0 3H 0 2C,3H 0 10C 10C 10C 5C,9G COCKLEBUR 10C 9C 9C 2C,6G      9C 10C 10C 3C,9G 0 0 2C,5G 0 3C,8H 0 4C,8H 0 10C 10C 9C 5C,9G NUTSEDGE      4C,8G 0 9C 0 4C,9G 3C,8G 3C,6G 0 0 0 0 0 0 0 0 0 -- 5C,9G 9C 8G CRABGRASS       0 0 0 0 3G 0 0 0 0 0 0 0 0 0 0 0 5C,9G 3C,7G 3C,8G 1C BARNYARDGRASS 0 0      0 0 3H 0 0 0 0 0 0 0 0 0 0 0 9C 9C 9C 3C,9H WILD OATS 0 0 0 0 0 0 0 0 0      0 0 0 0 0 0 0 3C,9G 9G 3C,8G 3C,8G WHEAT 0 0 0 0 0 0 2G 0 0 0 0 0 0 0 0      0 5C,9G 5C,9G 3C,9G 9G CORN 2G 0 0 0 4C,9G 7H 3C,8H 3G 0 0 0 0 0 0 0 0      9C 4U,9G 3C,7G 5G SOYBEANS 4C,9G 4C,9G 5C,9G 9G 4C,9G 3C,8H 4C,9H 5H 1H      0 0 0 1H 0 3H 0 9C 9C 5C,9G 5C,9H RICE 0 0 0 0 4G 0 0 0 0 0 0 0 3G 0 4G      0 9C 9C 9C 3C,8G SORGHUM 0 0 0 0 4G 0 3C,3G 0 0 0 0 0 0 0 2C 0 10C 4C,9G      3C,9G 4C,9G CHEATGRASS 0 0 0 0 3C,6G 3C,6G 3C,6G 0 0 0 0 0 0 0 0 0 6C,9G      5C,9G 10C 2C,9G SUGARBEETS 5C,9G 5C,9G 9C 4C,8G 10C 3C,7H 3C,9G 3C,7G 0      0 2G 0 5H 0 3C,7H 2G 9C 9C 10C 5C,9G VELVETLEAF 5C,9G 3C,5G 3C,8G 7G 9C      3C,7G 3C,7G 0 0 0 0 0 0 0 0 0 9C 10C 9C 4C,8H GIANT FOXTAIL 0 0 0 0      2C,4G 0 0 0 0 0 0 0 0 0 0 0 10C 9C 9C 4C,8G BARLEY 0 0 0 0 0 0 0 0 0 0 0      0 0 0 0 0 9C 5C,9G 2C,9G 7G  PREEMERGENCE  COTTON 6G 0 0 0 0 0 0 0 -- 0      0 0 0 0 0 0 9C 3C,9G 3C,8H 8G MORNINGGLORY 3G 0 6G 2G 3H 0 0 0 0 0 0 0 0      0 0 0 10C 9H 5C,9G 2C,5H COCKLEBUR 3C,5G 3H 2C 0 5H 0 1H 0 -- 0 -- 0 --      0 0 0 9H 8H 9H 2C,2H NUTSEDGE 0 0 0 0 5G 0 0 0 0 0 0 0 0 0 0 0 10E 10E      9G 0 CRABGRASS 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3C,7G 3C,8G 8H 0 BARNYARDG      RASS 0 0 0 0 2H 0 0 0 0 0 0 0 0 0 0 0 9H 3C,7G 3C,7G 3C,7G WILD OATS 0 0      0 0 2G 0 0 0 0 0 0 0 0 0 0 0 4C,8G 3C,7G 3C,7G 2C,2G WHEAT 0 0 0 0 2G 0      0 0 0 0 0 0 0 0 0 0 10H 2C,8G 2C,9G 6G CORN 2G 0 0 0 2C,7G 0 0 0 0 0 0 0      0 0 0 0 10H 2C,9G 3C,7H 3G SOYBEANS 3C,6G 3C,3H 3C,7H 3C,3H 3C,6H 0 1C 0      0 0 0 0 0 0 0 0 9H 9H 9H 3C,6H RICE 0 0 0 0 6G 0 0 0 0 0 0 0 0 0 0 0 10E      9G 10H 4G SORGHUM 0 0 0 0 3G 0 2C 0 0 0 0 0 0 0 0 0 5C,9G 3C,9G 5C,9G      3C,7H CHEATGRASS 0 0 0 0 7G 0 0 0 0 0 0 0 0 0 0 0 9H 8G 3C,8G 7G      SUGARBEETS 5C,9G 4C,9G 3C,8G 3C,5H 9G 3H 7G 0 0 0 0 0 2H 0 5G 0 9G 4C,9G      5C,9G 7G VELVETLEAF 2G 0 0 0 7H 0 1H 0 0 0 0 0 0 0 0 0 4C,9G 4C,9G 3C,9H      1C GIANT FOXTAIL 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9H 3C,8G 3C,7G 3G      BARLEY 0 0 0 0 2G 0 0 0 0 0 0 0 0 0 0 0 9H 9G 3C,9G 2C,5G        CMPD 81 CMPD 82 CMPD 83 CMPD 84  RATE=KG/HA 0.05 0.01 0.05 0.01 0.05      0.01 0.05 0.01         POSTEMERGENCE  COTTON 5C,9G 5C,9G 5C,9G 5C,9G 3C,9H 8H 4C,9G 2C,3H      MORNINGGLORY 10C 10C 10C 10C 10C 3C,8H 4C,9G 5C,9G COCKLEBUR 5C,9H 4C,9G      10C 9C 5C,9G 3C,8H 4C,9G 3C,7H NUTSEDGE 6C,9G 2C,9G 10C 5C,9G 2G 0 2C,5G      4G CRABGRASS 3C,7G 3C,6G 5C,8G 3C,7G 4C,8H 3G 5C,9G 2C,3G BARNYARDGRASS      9C 4C,9H 9C 4C,9G 5C,9G 4C,9G 9C 4C,9G WILD OATS 6C,9G 2C,8G 4C,9G 6G      3C,9G 3C,7G 5C,9G 3C,7G WHEAT 9G 9G 9G 9G 2C,9G 2C,9G 2C,9G 9G CORN 0 0      0 0 4U,9G 3U,9G 9C 4U,9G SOYBEANS 9C 5C,9G 4C,8H 2C,7H 5C,9G 3C,8H 5C,9H      4C,8G RICE 9C 5C,9G 9C 5C,9G 9C 5C,9G 9C 9C SORGHUM 5C,9G 9G 9C 5C,9G 9C      4C,9G 9C 4C,9G CHEATGRASS 4C,9G 3C,7G 5C,9G 8G 6C,9G 7G 9C 9C SUGARBEETS      9C 4C,9G 10C 4C,9H 9C 3C,7H 10C 5C,9G VELVETLEAF 9C 4C,9H 4C,9G 2C,8G      3C,7H 3C,4H 3C,7H 2H GIANT FOXTAIL 5C,9G 3C,8G 9C 5C,9G 5C,9G 3C,8G      6C,9G 3C,8G BARLEY 8G 6G 3C,9G 8G 4C,9G 8G 5C,9G 8G  PREEMERGENCE      COTTON 9G 3C,7H 9G 9G  3G 0 2C,3G 0 MORNINGGLORY 9H 3C,4H 9G 2C,8H 9G 0      2C,6H 4G COCKLEBUR 9H 3C,7H 9H 8H 3C,3H 1C 2C,2H 0 NUTSEDGE 10E 9G 10E      9G 0 0 0 0 CRABGRASS 9H 5G 8H 0 3G 0 3G 0 BARNYARDGRASS 3C,8H 1C 9H      2C,3G 3C,7H 0 3C,5G 0 WILD OATS 4C,7G 3C,5G 3C,5G 1C 7G 0 3C,4G 0 WHEAT      2C,9H 6G 8G 0 7G 0 7G 0 CORN 2C,3G 0 3G 0 3C,9G 2C,5G 2C,9G 2G SOYBEANS      9H 4C,7H 4C,8H 3C,6H 4C,8H 2C,5G 3C,7H 3G RICE 10E 3C,7G 10E 9H 10E 6G      10H 0 SORGHUM 5C,9G 3C,8G 4C,9G 4C,9G 3C,9G 3C,8G 4C,9G 3C,9G CHEATGRASS      9H 3C,8H 9H 8G 8G 0 8G 0 SUGARBEETS 4C,9G 3C,7H 9G 8G 2C,4H 0 2C,4G 4G      VELVETLEAF 5C,9G 3C,7H 4C,9H 3C,5H 1C 0 0 0 GIANT FOXTAIL 9H 2C,3G 3C,8G      3G 2C,7G 2G 6G 0 BARLEY 4C,8G 2G 2C,9G 2C,5G 4C,8H 3G 2C,9G 3G

Test B

Postemergence

Three round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with nutsedge (Cyperus rotundus) tubers, crabgrass (Digitaria sanguinalis), sicklepod (Cassia obtusifolia), jimsonweed (Datura stramonium), velvetleaf (Abutilon theophrasti), lambsquarters (Chenopodium album), rice (Oryza sativa), and teaweed (Sida spinosa). The second pot was planted with green foxtail (Setaria viridis), cocklebur (Xanthium pensylvanicum), morningglory (Ipomoea hederacea), cotton (Gossypium hirsutum), johnsongrass (Sorghum halepense), barnyardgrass (Echinochloa crus-galli), corn (Zea mays), soybean (Glycine max), and giant foxtail (Setaria faberi). The third pot was planted with wheat (Triticum aestivum), barley (Hordeum vulgare), wild buckwheat (Polygonum convolvulus), cheatgrass (Bromus secalinus) or downy brome (Bromus tectorum), sugarbeet (Beta vulgaris), wild oat (Avena fatua), common chickweed (Stellaria media) or field violet (Viola arvensis), blackgrass (Alopecurus myosuroides), and rape (Brassica napus). The plants were grown for approximately fourteen days, then sprayed postemergence with the chemicals dissolved in a nonphytotoxic solvent.

Preemergence

Three round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with nutsedge tubers, crabgrass, sicklepod, jimsonweed, velvetleaf, lambsquarters, rice, and teaweed. The second pot was planted with green foxtail, cocklebur, morningglory, cotton, johnsongrass, barnyardgrass, corn, soybean, and giant foxtail. The third pot was planted with wheat, barley, wild buckwheat, cheatgrass or downy brome, sugarbeet, wild oat, chickweed or field violet, blackgrass, and rape. The three pans were sprayed preemergence with the chemicals dissolved in a non-phytotoxic solvent.

Treated plants and controls were maintained in the greenhouse for approximately 24 days, then all rated plants were compared to controls and visually rated for plant response.

Response ratings are based on a scale of 0 to 100 where 0=no effect, and 100=complete control. A dash (-) response means no test.

Response ratings are contained in Table B.

    TABLE B       CMPD 1 CMPD 2 CMPD 3 CMPD 4 CMPD 5 CMPD 6 CMPD 7 RATE = G/HA 62 16 4 1      62 16 4 1 62 16 4 1 62 16 4 1 62 16 4 1 250 62 16 4 250 62        POSTEMERGENCE GIANT FOXTAIL 30 0 0 0                     50 30      VELVETLEAF 100 100 100 50 100 100 100 50 100 100 80 60 100 100 60 30 100      100 60 0 100 100 90 40 100 100 SUGARBEETS 100 100 100 100 100 -- 90 60      100 100 80 50 100 100 -- -- 100 100 80 40 100 100 -- 100 100 100      CRABGRASS 30 0 0 0 30 20 0 0 50 40 20 0 20 0 0 0 20 0 0 0 10 0 0 0 30 20      TEAWEED 90 70 50 30 90 70 30 30 90 70 50 40 80 40 20 0 90 60 20 -- 90 60      40 30 90 90 JIMSONWEED 100 100 70 50 100 100 90 70 100 90 80 50 100 100      80 50 100 100 80 30 90 90 60 40 100 100 RICE 60 50 30 0 90 50 40 40 90      80 80 50 50 40 20 10 10 0 0 0 10 0 0 0 100 100 COCKLEBUR 100 100 80 40      100 100 70 50 100 100 100 -- 100 100 100 50 100 100 100 40 100 100 80 40      90 40 COTTON 100 100 80 30 100 90 60 50 100 90 80 30 90 80 50 0 90 80 80      30 90 80 80 20 90 80 SOYBEANS 100 100 100 100 100 100 100 90 100 100 100      100 100 50 20 0 100 100 100 90 100 100 100 100 100 100 BARNYARDGRASS 70      60 50 30 100 100 -- 50 100 100 90 50 70 30 0 0 0 0 0 0 40 20 0 0 90 70      WILD OATS 0 0 0 0 80 70 40 20 100 100 70 40 30 0 0 0 0 0 0 0 10 0 0 0 50      40 MORNINGGLORY 100 100 100 50 100 100 70 50 100 90 70 40 100 100 80 20      100 100 60 40 100 100 90 80 100 100 WHEAT 30 0 0 0 90 70 40 40 100 100      80 50 50 20 10 0 30 30 20 10 10 0 0 0 0 0 SICKLEPOD 100 100 100 40 100      100 -- -- 100 100 -- -- 90 90 40 0 100 90 20 -- 100 90 80 -- 100 100      JOHNSONGRASS 70 60 50 30 100 80 40 40 100 100 80 40 70 60 20 20 20 0 0 0      0 0 0 0 60 40 NUTSEDGE 100 100 100 50 100 100 60 50 100 100 70 50 100      100 70 50 100 100 40 30 100 100 40 30 0 0 CORN 70 50 30 0 90 --  80 50      100 100 90 50 50 40 20 0 30 20 0 0 50 -- -- 10 90 80 WILD BUCKWHEAT 100      100 80 30 100 100 40 40 100 100 70 30 100 -- 100 90 90 90 60 30 100 100      60 40 100 100 BLACKGRASS 90 80 70 50 90 90 70 60 100 90 80 70 70 40 --      20 40 20 20 0 50 30 20 0 70 50 RAPE 100 100 100 100 100 -- 100 60 100      100 100 70 100 100 100 100 100 100 90 60 100 -- 100 90 90 90 BARLEY 50      30 0 0 80 70 50 30 90 80 70 40 50 40 20 0 10 0 0 0 0 0 0 0 10 0 GREEN      FOXTAIL 50 30 0 0 80 70 40 20 70 70 40 20 40 20 10 0 10 0 0 0 0 0 0 0 80      50 CHEATGRASS 60 50 30 0 90 70 50 20 90 90 70 40 80 50 20 0 0 0 0 0 30 0      0 0 LAMBSQUARTER 30 0 70 50 100 90 50 50 100 90 70 40 100 100 -- -- 100      100 100 70 100 100 100 100 100 100 CHICKWEED 100 90 80 50 100 90 40 0      100 80 50 30 90 50 -- -- 90 80 70 30 -- 100 90 60 100 90 DOWNY BROME                          60 40        CMPD 1 CMPD 2 CMPD 3 CMPD 4 CMPD 5 CMPD 6 CMPD 7 RATE = G/HA 250 62 16 4       62 16 4 1 62 16 4 1 250 62 16 4 250 62 16 4 250 62 16 4 250 62        PREEMERGENCE GIANT FOXTAIL 70 50 30 0 100 90 40 20 100 90 70 20 90 80      60  30 90 40 10 0 60 20 10 0 70 40 VELVETLEAF 100 90 80 70 100 90 70 --      100 100 90 30 100 100 80 70 100 100 80 40 100 100 60 40 100 90 SUGARBEETS       100 100 100 100 100 100 90 40 100 100 100 90 100 100 90 80 100 100 100      100 100 100 100 80 100 100 CRABGRASS 60 30 0 0 70 40 0 0 80 70 40 40 70      60 40 0 80 40 20 0 50 30 0 0 80 70 TEAWEED 90 80 70 60 90 70 30 -- 90 80      40 20 90 90 70 30 90 80 50 40 80 70 60 30 100 90 JIMSONWEED 90 80 70 60      100 -- 80 40 100 100 80 60 100 100 80 70 100 -- 70 50 90 80 40 40 100 50      RICE 100 80 50 30 100 90 80 40 100 100 90 90 100 100 100 70 90 40 40 0      60 40 20 0 100 90 COCKLEBUR 90 80 70 60 80 70 50 30 90 80 80 70 90 90 80      70 90 80 70 40 90 70 50 50 80 30 COTTON 90 60 30 0 100 70 50 30 100 90      80 50 100 90 60 40 100 90 60 30 100 100 70 20 100 90 SOYBEANS 90 70 0 0      90 80 60 50 90 80 70 60 80 70 50 40 90 90 80 60 90 80 70 50 100 100      BARNYARDGRASS 100 90 60 30 100 100 90 40 100 100 90 40 100 100 70 50 100      70 40 30 100 90 40 20 100 80 WILD OATS 90 60 30 0 80 50 30 0 90 80 70 60      70 70 20 0 40 10 0 0 10 0 0 0 70 40 MORNINGGLORY 90 80 70 60 100 80 60      -- 100 70 50 40 100 100 90 70 100 100 90 40 100 90 90 50 100 100 WHEAT      80 50 30 0 90 60 30 0 90 80 70 30 50 30 20 10 10 0 0 0 10 0 0 0 10 0      SICKLEPOD 100 70 50 30 80 40 -- -- 90 80 50 0 100 100 80 -- 100 90 90 60      100 80 50 -- 100 70 JOHNSONGRASS 80 50 30 0 100 100 80 80 100 100 90 40      100 90 70 50 90 80 50 30 50 50 30 20 50 50 NUTSEDGE 100 100 70 30 100 40      30 -- 100 100 80 30 100 100 90 80 100 -- 90 70 90 90 40 30 CORN 60 30 0      0 100 50 40 20 100 100 70 50 100 60 40 40 90 50 50 10 100 40 30 10 100      100 WILD BUCKWHEAT 100 90 80 60 100 100 80 30 100 100 80 80 100 100 90      60 100 100 100 80 100 100 100 70 100 100 BLACKGRASS 100 90 70 50 100 90      40 10 100 90 90 70 100 90 80 40 90 80 50 20 80 70 30 0 70 50 RAPE 100 90      80 50 100 100 70 30 100 100 100 100 100 100 100 90 100 100 100 20 100      100 90 30 90 90 BARLEY 70 50 30 0 70 70 40 30 90 80 70 60 80 70 40 10 40      30 10 0 20 0 0 0 30 20 GREEN FOXTAIL 90 60 30 0 100 80 40 10 100 80 60 0      90 80 50 30 90 40 20 0 60 20 0 0 90 80 CHEATGRASS 90 80 70 50 100 90 70      40 100 90 80 70 -- 90 70 40 60 40 20 20 50 30 10 0 LAMBSQUARTER 100 90      80 70 100 100 100 60 100 100 100 90 100 100 100 90 100 100 100 90 100      100 100 80 100 100 CHICKWEED 100 95 90 80 100 90 80 20 90 90 80 70 90 --      80 50 100 90 80 60 100 100 90 60 90 80 DOWNY BROME        90 60        CMPD 7 CMPD 8 CMPD 9 CMPD 11 CMPD 12 CMPD 13 CMPD 20 RATE = G/HA 16 4      250 62 16 4 250 62 16 4 250 62 16 4 62 16 4 1 250 62 16 4 62 16 4      1        POSTEMERGENCE GIANT FOXTAIL 20 0 90 40 -- 20 70 50 40 30 70 40      40 10 0 0 0 0 0 0 0 0     VELVETLEAF 90 80 100 100 100 100 100 100 100      80 100 100 100 90 100 100 90 60 100 100 100 90 100 100 80 70 SUGARBEETS      100 100 100 100 100 100 100 100 90 60 100 100 80 50 100 100 100 90 100      100 100 90 100 100 100 60 CRABGRASS 0 0 70 40 40 30 50 50 40 0 30 20 0 0      40 20 0 0 0 0 0 0 10 0 0 0 TEAWEED 80 50 100 100 90 40 100 100 90 40 100      80 80 50 90 60 40 20 100 80 60 40 80 60 40 10 JIMSONWEED 90 90 100 100      90 70 100 100 90 80 100 100 90 70 100 100 90 80 100 100 90 90 100 80 40      0 RICE 50 10 50 40 30 10 90 80 40 0 50 30 0 0 10 0 0 0 10 0 0 0 40 40 30      10 COCKLEBUR 20 0 100 100 100 100 100 100 100 90 100 100 100 100 100 100      100 100 100 100 100 80 100 100 100 80 COTTON 80 70 100 100 100 90 100      100 90 60 70 60 50 20 100 90 70 50 90 90 80 70 -- 50 40 -- SOYBEANS 100      90 100 100 100 90 100 100 90 60 70 40 20 0 100 100 100 90 100 100 100      100 100 100 100 100 BARNYARDGRASS 50 10 100 100 100 30 100 100 70 50 100      70 20 -- 0 0 0 0 30 10 0 0 90 50 50 20 WILD OATS 30 20 70 50 30 0 70 50      30 0 50 30 0 0 30 20 0 0 20 0 0 0 10 0 0 0 MORNINGGLORY 90 85 100 100 90      40 100 100 100 90 100 100 100 80 100 90 70 50 100 100 100 90 100 100 80      40 WHEAT 0 0 50 30 0 0 60 30 0 0 0 0 0 0 20 0 0 0 10 0 0 0 40 40 20 10      SICKLEPOD 100 80 100 100 90 80 90 90 50 20 70 60 30 0 100 80 40 20 100      100 90 70 100 90 50 20 JOHNSONGRASS 30 0 90 80 40 0 90 80 60 30 50 40 30      0 0 0 0 0 0 0 0 0 100 60 40 20 NUTSEDGE 0 0 100 100 100 100 100 100 100      40 100 100 100 30 100 50 30 0 100 40 20 0 100 50 50 30 CORN 80 40 50 40      30 10 100 100 70 20 50 30 10 0 40 20 0 0 40 20 0 0 100 90 70 20 WILD      BUCKWHEAT 100 100 100 100 100 90 100 100 100 100 100 100 100 100 100 100      100 90 100 100 90 80 100 80 40 0 BLACKGRASS 30 20 90 70 50 30 90 80 70      60 60 30 0 0 50 40 20 0 20 0 0 0 80 70 60 0 RAPE 50 30 100 100 100 100      100 100 100 100 100 100 100 100 100 100 100 90 100 100 100 100 100 100      100 70 BARLEY 0 0 30 0 0 0 60 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 60 60 30 10      GREEN FOXTAIL 20 0 100 80 50 30 100 100 70 20 90 40 40 10 20 0 0 0 20 0      0 0 30 10 0 -- CHEATGRASS                       80 70 30 -- LAMBSQUARTER      100 90 100 100 90 80 100 100 90 50 100 90 40 -- 100 60 40 20 100 100 80      60 90 70 60 0 CHICKWEED 80 60 100 100 80 50 100 100 90 60 90 60 30 0 100      100 90 85 100 100 90 80 100 100 80 40 DOWNY BROME 20 0 90 70 60 50 100      70 50 30 70 50 30 0 0 0 0 0 40 20 0 0        CMPD 7 CMPD 8  CMPD 9 CMPD 11 CMPD 12 CMPD 13 CMPD 20 RATE = G/HA 16      250 62 16 4 250 62 16 4 250 62 16 250 62 16 250 62 16 250 62 16 4        PREEMERGENCE GIANT FOXTAIL 20 90 80 70 60 90 80 70 50 80 70 50 50 20 0 5      0 20 0 80 40 20 10 VELVETLEAF 80 90 70 50 30 90 70 50 30 90 70 50 100 90      90 100 90 90 100 100 70 20 SUGARBEETS 100 100 100 90 80 100 100 90 80      100 100 100 100 100 100 100 100 100 100 100 80 80 CRABGRASS 30 70 50 30      0 60 30 0 0 30 0 0 50 30 30 50 20 0 50 30 0 0 TEAWEED 90 90 70 50 30 90      80 50 30 90 70 50 100 80 80 100 90 90 90 80 40 0 JIMSONWEED 30 70 60 50      30 90 80 70 30 90 70 60 100 90 90 100 90 80 90 90 80 50 RICE 80 100 90      70 30 100 90 60 30 100 90 70 80 50 20 70 40 10 90 70 60 40 COCKLEBUR 0      90 70 50 30 90 80 70 60 90 80 70 100 100 90 100 90 80 90 80 70 60 COTTON      80 70 50 30 0 80 40 0 0 70 30 0 100 90 90 100 80 80 70 60 50 40 SOYBEANS      70 90 80 60 30 90 80 50 30 30 0 0 100 100 90 100 100 80 80 70 20 20      BARNYARDGRASS 70 90 80 50 30 100 70 50 30 80 50 30 40 30 0 40 20 0 100      100 50 30 WILD OATS 30 50 40 30 0 70 50 30 0 40 0 0 30 0 0 40 20 0 20 0      0 0 MORNINGGLORY 100 90 80 60 30 90 80 70 60 90 80 60 100 100 100 100      100 90 100 90 90 50 WHEAT 0 50 30 20 0 70 50 30 0 0 0 0 0 0 0 0 0 0 70      40 10 0 SICKLEPOD -- 100 100 70 50 90 70 50 30 50 30 0 100 90 70 100 70      50 100 90 -- 30 JOHNSONGRASS 30 70 50 30 0 90 70 50 30 50 30 0 40 20 0      40 20 0 100 90 80 50 NUTSEDGE  100 100 100 30 100 90 70 50 100 90 60 50      30 0 100 50 -- 90 70 60 50 CORN 60 90 60 0 0 100 90 50 0 30 0 0 100 40      30 100 70 30 80 70 10 10 WILD BUCKWHEAT 100 100 100 90 70 100 100 95 90      100 100 100 100 100 100 100 100 100 100 100 80 40 BLACKGRASS 40 80 70 60      50 100 90 60 30 90 60 30 60 40 0 30 20 0 90 90 40 20 RAPE 60 100 100 100      90 100 100 95 90 100 100 100 100 100 100 100 100 100 100 100 90 40      BARLEY 10 50 30 20 0 60 40 20 0 0 0 0 20 0 0 0 0 0 50 30 30 20 GREEN      FOXTAIL 40 90 70 50 30 100 90 60 30 80 50 30 70 50 20 50 30 0 80 40 30      10 CHEATGRASS                   90 80 70 40 LAMBSQUARTER 90 100 90 80 60      100 90 80 60 100 90 70 100 100 90 100 100 90 100 100 100 90 CHICKWEED 60      100 100 90 60 100 90 70 50 90 80 70 90 85 70 90 90 90 100 100 90 60      DOWNY BROME 30 90 70 50 30 100 90 60 30 70 50 30 50 30 0 60 30 0        CMPD 23 CMPD 25 CMPD 26 CMPD 27 CMPD 28 CMPD 29 CMPD 30 RATE = G/HA 62 1      6 4 1 62 16 4 1 62 16 4 1 62 16 4 1 62 16 4 1 62 16 4 1 62 16        POSTEMERGENCE GIANT FOXTAIL     30 0 0 0                   VELVETLEAF      90 40 30 20 100 90 60 30 100 100 50 20 100 90 70 70 100 90 40 0 100 100      -- 40 100 100 SUGARBEETS 100 90 70 -- 100 100 100 90 100 90 80 60 100      100 -- 50 100 90 80 70 100 -- 90 60 100 100 CRABGRASS 20 0 0 0 30 0 0 0      70 30 20 20 60 60 20 0 20 0 0 0 40 20 0 0 0 0 TEAWEED 10 0 -- 0 70 50 30      0 70 50 40 -- 90 70 70 30 60 30 20 0 90 80 20 20 80 60 JIMSONWEED 90 70      30 0 100 90 70 50 100 90 80 30 100 100 40 0 100 80 80 --  100 100 90 30      100 80 RICE 40 10 10 0 80 60 30 0 90 80 70 40 100 100 70 60 80 50 20 10      10 0 0 0 0 0 COCKLEBUR 90 80 50 20 80 70 50 30 100 100 70 40 100 100 70      40 100 100 70 30 100 100 90 40 100 100 COTTON 30 20 0 0 100 80 60 30 100      90 40 40 100 90 50 40 80 80 50 30 90 90 70 20 90 80 SOYBEANS 100 90 50      20 100 100 90 50 100 100 100 60 100 100 100 60 80 70 20 20 100 100 100      80 100 100 BARNYARDGRASS 90 80 40 0 70 50 30 0 100 90 80 40 100 100 90      40 70 40 10 0 50 10 0 0 30 10 WILD OATS 70 60 30 0 50 30 0 0 80 70 40 20      80 70 60 20 40 -- 10 -- 40 0 0 0 30 10 MORNINGGLORY 100 70 40 0 100 100      90 40 100 100 80 30 90 80 70 40 100 100 70 20 100 100 80 40 100 90 WHEAT      50 30 30 0 40 20 0 0 90 70 30 20 80 70 70 30 40 30 30 0 10 10 10 0 20 20      SICKLEPOD 30 -- -- -- 100 100 100 90 100 100 80 20 100 100 -- 40 100 70      -- 20 100 100 100 20 100 100 JOHNSONGRASS 100 40 30 20 70 50 30 0 90 80      50 40 100 100 80 60 60 50 30 30 10 0 0 0 0 0 NUTSEDGE 30 30 20 0 100 100      50 30 100 100 70 40 100 100 90 40 100 100 30 20 100 -- 20 -- 100 40 CORN      100 70 30 0 70 60 50 30 100 100 90 70 100 100 80 50 50 30 20 0 90 50 10      0 40 30 WILD BUCKWHEAT 80 60 0 0 90 70 50 30 100 -- 50 30 90 70 -- 40      100 80 60 40 100 -- 50 -- 100 90 BLACKGRASS 70 30 30 0 90 80 70 50 90 80      70 50 100 90 80 70 70 60 40 0 90 80 70 20 30 --  RAPE 100 90 70 40 100      100 100 100 100 100 90 80 100 100 90 70 100 100 90 70 100 100 100 70 100      100 BARLEY 40 30 20 10 50 30 0 0 80 70 50 30 90 60 60 30 10 10 0 0 20 10      0 0 20 10 GREEN FOXTAIL 20 0 0 0 50 30 0 0 90 80 30 0 90 80 40 0 40 30 0      0 40 0 0 0 0 0 CHEATGRASS 80 40 0 0 90 70 50 30 90 80 70 70 90 90 90 70      90 70 40 0 30 0 0 0 20 0 LAMBSQUARTER 100 100 40 0 90 80 70 60 90 80 60      60 80 70 40 0 70 40 30 -- 100 100 90 80 100 90 CHICKWEED 70 60 -- 0 100      90 70 50 90 50 -- 0 100 90 20 -- 40 0 0 -- 100 100 80 30 100 100

      CMPD 23 CMPD 25 CMPD 26 CMPD 27 CMPD 28 CMPD 29 CMPD 30 RATE = G/HA 250 6      2 16 4 62 16 4 1 62 16 4 1 62 16 4 1 250 62 16 4 250 62 16 4 250      62        PREEMERGENCE GIANT FOXTAIL 100 80 30 0 100 60 30 0 100 90 60      20 100 80 70 30 40 20 0 0 80 70 20 0 40 20 VELVETLEAF 100 80 60 40 100      60 30 0 100 80 -- 0 90 90 80 30 100 90 70 30 100 100 90 50 100 100      SUGARBEETS 100 90 70 50 100 100 90 70 100 90 90 70 100 90 90 70 100 100      70 70 100 100 100 70 100 100 CRABGRASS 90 80 30 0 60 30 0 0 90 50 50 0      80 40 20 0 60 20 0 0 70 60 30 20 70 20 TEAWEED 50 -- -- -- 60 30 0 0 100      70 30 0 90 80 50 -- 80 80 70 30 100 80 70 30 90 80 JIMSONWEED 90 -- 40      30 80 60 50 30 100 90 80 40 90 80 70 40 100 90 80 50 100 90 80 60 100 90      RICE 100 100 90 40 90 60 0 0 100 90 80 40 100 100 90 60 100 90 70 20 90      40 10 0 50 10 COCKLEBUR 80 60 60 40 60 50 40 30 90 80 50 30 90 80 70 60      90 80 70 50 90 90 80 60 90 80 COTTON 90 70 40 0 0 0 0 0 90 50 30 0 90 70      50 40 90 70 50 20 100 100 90 70 100 100 SOYBEANS 90 80 60 20 60 0 0 0 80      60 20 0 80 60 50 20 70 50 40 20 100 100 80 60 90 80 BARNYARDGRASS 100 50      30 0 60 30 0 0 100 100 90 30 100 90 70 40 100 90 70 40 -- 90 70 30 100      80 WILD OATS 60 20 20 0 60 30 0 0 80 70 50 20 80 70 60 10 30 20 0 0 20 0      0 0 30 0 MORNINGGLORY 100 70 60 30 90 70 50 30 100 90 50 50 80 70 -- 40      100 90 70 40 100 100 100 90 100 100 WHEAT 70 30 20 10 40 0 0 0 80 50 20      10 100 80 60 10 40 20 10 0 0 0 0 0 10 0 SICKLEPOD 80 -- -- -- 100 90 30      0     100 80 40 10 90 30 30 -- 100 100 90 -- 100 90 JOHNSONGRASS 100 100      90 30 70 50 30 0 100 100 80 30 100 90 80 60 90 90 40 20 80 70 -- 0 70 40      NUTSEDGE 80 70 70 30 90 50 30 0 90 40 30 -- 100 80 70 20 100 90 40 0 100      90 40 20 -- 90 CORN 50 30 -- 0 0 0 0 0 100 50 30 10 100 100 70 40 90 40      10 0 100 50 20 10 90 20 WILD BUCKWHEAT 100 100 60 30 90 70 50 30 100 90      70 50 100 80 70 60 100 90 80 40 100 100 90 70 100 100 BLACKGRASS 100 100      20 0 90 70 50 30 100 90 80 30 100 100 70 40 -- 80 40 10 90 80 70 40 70      40 RAPE 100 100 50 0 100 90 70 30 100 100 100 40 100 100 80 40 100 100      90 50 100 100 100 40 100 100 BARLEY 70 50 30 20 60 30 0 0 70 50 30 20 80      70 40 20 40 20 10 10 50 20 0 0 20 0 GREEN FOXTAIL 100 80 30 0 70 50 30 0      100 90 50 10 100 80 60 20 50 40 10 0 80 60 0 0 40 10 CHEATGRASS 100 50      10 0 70 30 0 0 100 90 80 60 100 90 90 60 90 70 50 10 80 50 30 20 40 10      LAMBSQUARTER 100 100 90 40 100 100 100 100 100 100 90 90 100 100 90 70      100 90 90 70 100 100 100 90 100 100 CHICKWEED 90 70 40 0 100 90 70 50      100 90 80 40 90 90 80 30 90 80 70 30 100 90 80 70 100 90        CMPD 30 CMPD 31 CMPD 32 CMPD 34 CMPD 35 CMPD 36 CMPD 37 RATE = G/HA 4      1 250 62 16 4 250 62 16 4 250 62 16 4 250 62 16 4 250 62 16 4 62 16 4      1    POSTEMERGENCE GIANT FOXTAIL   50 40 30 0 70 50 30 0 50 30 0 0 30 0      0 0 30 20 0 0 90 70 60 20 VELVETLEAF 70 40 100 100 70 60 100 100 100 90      100 100 90 60 100 100 100 90 100 100 95 80 100 100 90 50 SUGARBEETS 90      60 100 100 100 70 100 100 90 30 100 90 70 60 100 100 100 100 100 100 100      80 100 100 100 90 CRABGRASS 0 0 0 0 0 0 60 50 40 30 50 30 0 0 0 0 0 0 50      20 0 0 70 70 20 0 TEAWEED 40 10 70 50 30 0 100 90 80 60 80 70 50 30 100      90 80 70 100 80 80 70 100 60 50 0 JIMSONWEED 50 20 100 90 80 50 100 100      90 70 100 100 80 60 100 100 100 90 100 100 90 70 100 90 80 60 RICE 0 0      50 40 30 0 90 80 70 50 70 50 30 0 30 0 0 0 30 10 0 0 100 100 80 40      COCKLEBUR 50 30 100 90 80 70 100 100 90 80 100 100 90 70 100 100 100 100      100 100 100 100 100 100 70 20 COTTON 50 30 70 50 40 30 100 100 80 50 90      70 50 30 100 90 80 70 90 90 80 70 100 90 80 30 SOYBEANS 100 80 100 90 80      60 100 90 80 30 30 0 0 0 100 100 100 80 100 100 90 90 100 100 90 20      BARNYARDGRASS 0 0 80 70 50 30 90 80 70 60 80 50 30 0 60 0 0 0 70 40 20 0      100 100 100 90 WILD OATS 0 0 60 30 0 0 90 60 30 0 30 0 0 0 30 0 0 0 30      20 0 0 100 100 70 40 MORNINGGLORY 80 30 100 80 60 30 100 100 90 70 100      100 90 60 100 100 95 90 100 100 100 85 100 100 100 50 WHEAT 10 10 50 30      0 0 90 70 50 30 0 0 0 0 0 0 0 0 10 0 0 0 100 100 90 80 SICKLEPOD -- --      90 70 60 30 100 100 90 70 100 100 100 50 100 100 -- -- 100 100 100 70      100 90 50 30 JOHNSONGRASS 0 -- 70 50 30 0 100 100 90 80 70 50 30 0 70 50      0 0 20 0 0 0 100 100 90 60 NUTSEDGE 20 20 90 70 50 30 100 90 80 70 100      90 60 30 60 30 0 0 100 90 60 30 100 90 0 0 CORN 10 0 0 0 0 0 90 80 70 40      30 0 0 0 60 30 0 0 60 20 0 0 100 100 90 0 WILD BUCKWHEAT -- 50 100 100      100 70 100 100 90 80 100 100 100 80 100 100 100 100 100 100 100 80 100      100 90 80 BLACKGRASS 0 0 100 90 70 50 100 100 100 80 70 50 30 0 100 90      70 50 40 30 20 0 100 100 70 40 RAPE 80 70 100 100 100 100 100 100 100      100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 90      BARLEY 0 0 40 30 20 0 60 50 40 0 50 30 0 0 0 0 0 0 20 0 0 0 100 70 40 0      GREEN FOXTAIL 0 0 50 40 30 0 90 70 50 30 50 30 0 0 50 30 0 0 40 10 0 0      100 90 80 20 CHEATGRASS 0 0 LAMBSQUARTER 70 50 100 100 70 50 100 90 70      50 100 70 50 30 100 100 90 70 90 70 70 40 100 100 90 50 CHICKWEED 90 --      100 100 70 50 100 100 100 100 80 50 30 0 100 100 100 100 100 100 100 100      100 100 80 70 DOWNY BROME   70 30 0 0 100 100 95 90 100 80 70 60 70 30 0      0 40 20 0 0 100 90 80 30        CMPD 30 CMPD 31 CMPD 32 CMPD 34 CMPD 35 CMPD 36 CMPD 37 RATE = G/HA 16 4       250 62 16 4 250 62 16 4 250 62 16 4 250 62 16 250 62 16 4 62 16 4      1       PREEMERGENCE GIANT FOXTAIL 0 0 70 50 30 0 90 60 30 0 30 0 0 0 50 3      0 0 40 40 30 20 100 90 40 0 VELVETLEAF 90 70 90 80 70 50 90 80 70 50 90      80 70 60 100 100 90 100 90 40 20 100 90 30 0 SUGARBEETS 100 70 90 80 70      50 100 100 100 90 100 100 90 70 100 100 100 100 100 90 90 100 100 90 60      CRABGRASS 0 0 50 30 0 0 80 50 30 0 40 20 0 0 50 30 0 40 20 20 0 90 70 0      0 TEAWEED 70 50 50 30 0 0 90 80 70 40 95 90 70 0 90 80 60 100 100 50 50      100 90 50 50 JIMSONWEED 80 20 90 80 70 50 100 100 90 70 100 90 80 70 100      100 90 90 80 30 20 100 100 50 50 RICE 0 0 100 80 60 0 100 100 90 70 100      90 60 30 50 30 0 60 40 0 0 100 100 70 30 COCKLEBUR 70 50 90 80 70 60 90      80 70 60 90 80 60 30 95 90 85 100 100 70 30 100 90 80 60 COTTON 80 40 50      30 0 0 90 80 60 30 70 50 30 0 100 70 60 100 100 30 10 100 100 80 30      SOYBEANS 70 50 70 30 0 0 90 70 50 0 0 0 0 0 100 90 80 100 100 20 0 90 90      0 0 BARNYARDGRASS 50 0 100 50 30 0 100 95 90 85 50 30 0 0 50 30 0 30 20      20 0 100 100 40 20 WILDOATS 0 0 70 50 30 0 90 80 70 50 60 30 0 0 0 0 0      20 0 0 0 80 80 0 0 MORNINGGLORY 100 100 90 80 70 60 100 90 80 70 90 80      50 30 100 100 90 100 100 80 20 100 100 30 0 WHEAT 0 0 30 0 0 0 90 70 50      30 30 0 0 0 0 0 0 0 0 0 0 90 80 20 0 SICKLEPOD -- -- 80 50 0 0 100 100      80 30 70 50 30 0 90 80 60 100 100 60 30 90 90 80 50 JOHNSONGRASS 0 0 70      50 30 0 100 90 85 80 70 60 50 30 50 30 0 40 30 20 0 90 80 50 20 NUTSEDGE      50 30 100 90 70 30 100 100 80 30 100 90 70 0 70 60 50 90 20 0 0 100 90      90 30 CORN 10 -- 70 50 20 0 100 100 90 50 80 30 0 0 100 90 80 50 50 30      30 100 100 20 0 WILD BUCKWHEAT 90 70 90 80 70 60 100 90 80 70 80 70 60      50 100 100 90 100 100 100 90 100 100 100 100 BLACKGRASS 30 0 90 80 70 50      100 95 90 85 90 70 50 30 80 70 60 70 40 40 20 80 70 50 30 RAPE 100 40      100 100 90 60 100 100 100 100 100 100 100 90 100 100 100 100 100 100 90      100 100 100 20 BARLEY 0 0 60 30 0 0 90 70 60 50 60 30 0 0 30 0 0 20 0 0      0 90 90 20 0 GREEN FOXTAIL 0 0 80 60 30 0 90 60 30 0 30 0 0 0 50 30 0 40      30 0 0 100 100 50 50 CHEATGRASS 10 0 LAMBSQUARTER 80 80 100 90 80 70 100      100 90 70 100 90 80 70 100 100 90 95 90 80 40 100 100 80 50 CHICKWEED 80      -- 90 80 70 60 100 95 90 85 90 70 50 30 100 100 100 100 90 70 70 100 100      50 50 DOWNY BROME   50 30 0 0 100 100 100 90 90 80 70 60 70 50 30 50 30      20 20 100 90 40 0        CMPD 38 CMPD 39 CMPD 40 CMPD 41 CMPD 42 CMPD 43 CMPD 49 RATE = G/HA 62 1      6 4 1 62 16 4 1 62 16 4 1 250 62 16 4 250 62 16 4 62 16 4 1 62 16        POSTEMERGENCE GIANT FOXTAIL 60 50 30 0 95 50 20 0 100 40 20 0 100 80      50 20 100 50 40 0 100 100 60 40 100 100 VELVETLEAF 100 90 60 40 100 80      60 50 100 90 40 0 90 60 40 0 70 40 20 0 100 100 90 90 100 100 SUGARBEETS      90 80 70 60 100 100 90 50 100 90 80 30 100 100 80 30 100 100 100 70 100      100 100 100 100 100 CRABGRASS 0 0 0 0 50 20 0 0 40 20 0 0 70 60 40 20 90      20 20 0 90 40 20 0 100 50 TEAWEED 80 70 50 20 90 90 50 0 80 50 20 0 50      20 0 0 30 20 0 0 100 80 70 20 100 90 JIMSONWEED 100 90 80 60 100 90 70      40 100 100 80 50 90 90 80 70 100 90 80 30 100 90 80 70 100 100 RICE 60      40 20 0 100 70 40 20 90 80 30 0 100 100 90 40 100 100 90 40 100 100 90      70 90 70 COCKLEBUR 80 30 0 0 90 70 30 20 100 50 20 0 80 50 20 0 80 20 0      0 100 80 30 0 100 80 COTTON 90 70 30 20 90 70 30 0 90 50 20 0 60 50 -- 0      80 30 30 0 100 90 80 60 100 90 SOYBEANS 90 80 70 50 100 90 80 30 80 80      20 20 100 90 80 30 100 70 60 0 100 100 80 30 100 90 BARNYARDGRASS 70 50      50 40 100 100 60 50 100 90 70 40 100 100 90 60 100 100 80 60 100 100 100      80 100 100 WILD OATS 80 70 40 0 90 90 50 40 90 70 30 0 100 100 90 80 100      100 100 90 100 100 100 90 80 70 MORNINGGLORY 90 70 70 60 100 90 70 20      100 100 50 0 100 100 50 0 90 90 80 20 100 100 80 50 100 100 WHEAT 90 90      70 40 90 90 80 50 90 90 50 40 100 100 90 90 100 100 90 80 100 100 90 90      50 50 SICKLEPOD 0 0 0 0 80 50 30 0 80 40 0 0 80 30 0 0 80 30 0 0 100 80      50 0 100 60 JOHNSONGRASS 60 50 40 30 100 70 60 40 100 80 70 40 100 100      80 40 100 100 70 40 100 100 80 60 100 90 NUTSEDGE 50 50 40 0 100 100 100      40 100 80 20 0 40 0 0 0 90 50 50 30 90 90 40 0 0 0 CORN 90 40 20 0 40 20      0 0 80 30 0 0 100 100 80 70 100 100 60 30 100 100 80 80 100 80 WILD      BUCKWHEAT 70 50 30 30 100 80 50 20 100 100 50 20 100 40 30 0 100 90 50 0      100 100 100 50 100 100 BLACKGRASS 90 80 70 50 100 100 70 50 100 90 50 30      100 100 90 80 100 100 80 80 100 100 90 50 70 70 RAPE 90 80 80 70 100 100      100 70 100 100 100 80 100 90 90 80 100 100 90 70 100 100 100 90 100 100      BARLEY 50 40 30 0 90 70 30 20 80 50 40 20 90 60 60 30 100 100 80 30 100      100 90 80 80 70 GREEN FOXTAIL 40 20 0 0 100 70 40 0 90 70 20 0 100 90 50      50 100 50 40 0 100 100 70 40 100 100 LAMBSQUARTER 100 70 70 40 100 50 50      0 100 100 70 70 90 80 40 0 100 80 50 30 100 100 70 70 100 90 CHICKWEED      80 60 50 50 100 100 60 40 100 70 20 0 100 80 70 50 100 90 70 50 100 100      90 80 100 90 DOWNY BROME 80 60 50 0 90 80 40 20 90 70 30 0 100 100 90 80      100 100 90 80 100 100 80 40 80 70        CMPD 38 CMPD 39 CMPD 40 CMPD 41 CMPD 42 CMPD 43 CMPD 49 RATE = G/HA      250 62 16 4 62 16 4 1 62 16 4 1 250 62 16 4 250 62 16 4 62 16 4 1 62      16    PREEMERGENCE GIANT FOXTAIL 0 0  0 0 100 30 30 0 60 60 0 0 100 100      90 40 100 90 70 0 100 100 70 60 90 80 VELVETLEAF 40 30 0 0 90 80 50 30      100 50 40 0 100 40 40 40 70 50 30 0 100 100 90 70 90 80 SUGARBEETS 50 30      20 0 100 80 50 0 100 100 50 50 100 90 0 0 100 100 50 30 100 100 100 80      90 80 CRABGRASS 0 0 0 0 70 30 30 0 100 70 60 40 100 70 0 0 100 90 50 50      90 90 80 50 100 100 TEAWEED 40 40 0 0 60 40 0 0 80 70 30 30 80 50 30 0      50 50 50 0 100 100 80 50 100 90 JIMSONWEED 50 0 0 0 60 50 30 30 90 30 0      0 100 80 30 0 100 90 50 0 100 90 80 0 90 60 RICE 30 20 0 0 80 40 40 0      100 100 30 20 100 100 60 40 100 100 70 50 100 100 100 40 100 90 COCKLEBUR       50 50 0 0 80 30 30 0 90 80 40 0 90 70 40 0 90 90 30 0 100 100 70 0 90      80 COTTON 0 0 0 0 100 100 30 0 100 80 50 0 100 90 30 0 80 80 30 0 100      100 100 90 70 40 SOYBEANS 0 0 0 0 100 90 30 0 90 60 0 0 100 100 20 --      100 70 0 -- 100 100 60 50 90 40 BARNYARDGRASS 30 20 0 0 100 100 0 -- 100      100 30 20 100 100 50 0 100 100 100 30 100 100 80 40 100 90 WILD OATS 50      30 30 0 70 20 0 0 90 60 30 0 80 80 0 0 90 80 40 20 90 80 60 60 60 40      MORNINGGLORY 50 0 0 0 100 0 0 0 100 70 70 0 100 90 20 0 100 100 50 0 100      100 50 0 100 90 WHEAT 30 0 0 0 70 20 0 0 50 30 0 0 100 20 0 0 100 100 20      0 100 90 80 40 70 20 SICKLEPOD 50 50 0 0 80 0 0 0 80 80 70 30 90 80 30      30 100 80 40 0 100 100 90 70 100 90 JOHNSONGRASS 30 0 0 0 90 70 20 0 90      90 50 20 100 90 70 40 100 90 50 30 90 90 70 70 100 90 NUTSEDGE -- 0 0 0      100 100 50 50 -- 90 70 20 20 0 0 0 100 50 30 0 100 100 80 40 90 80 CORN      0 0 0 0 40 20 0 0 40 30 0 0 100 90 40 0 100 40 30 0 100 100 0 0 70 60      WILD BUCKWHEAT 90 -- 50 50 100 100 100 90 100 100 100 100 100 100 100      100 100 100 100 100 100 100 100 100 100 90 BLACKGRASS 30 20 20 0 70 30 0      0 90 50 0 0 100 70 50 40 90 90 70 40 90 80 70 50 90 70 RAPE 40 30 30 0      100 80 50 0 100 100 70 40 100 60 30 20 80 80 70 20 100 100 100 40 100 90      BARLEY 0 0 0 0 90 30 30 0 70 50 0 0 100 80 0 0 90 90 50 30 100 90 70 0      80 30 GREEN FOXTAIL 40 20 0 0 100 80 40 40 90 90 40 30 100 100 90 50 100      100 90 30 100 100 100 30 100 90 LAMBSQUARTER 50 0 0 0 90 50 30 0 100 90      80 30 80 70 70 30 100 70 70 70 100 100 90 0 100 100 CHICKWEED 100 30 0 0      70 0 0 0 70 70 0 0 90 90 0 0 100 70 0 0 100 90 -- 50 100 100 DOWNY BROME      40 20 0 0 100 40 0 0 90 80 40 40 100 100 90 30 100 100 80 40 100 100 90      70 90 40

      CMPD 49 CMPD 52 CMPD 55 CMPD 56 CMPD 61 CMPD 62 CMPD 63 RATE = G/HA 4 1 6      2 16 4 1 250 62 16 4 250 62 16 4 62 16 4 1 62 16 4 1 62 16 4 1        POSTEMERGENCE GIANT FOXTAIL 50 20 50 30 0 0 70 30 0 0 0 0 0 0 100 50      30 10 90 90 50 40 100 90 40 20 VELVETLEAF 60 0 100 70 40 30 100 100 100      80 100 100 80 40 100 100 100 90 100 100 100 90 100 100 100 90 SUGARBEETS      100 90 100 100 100 70 100 100 100 100 100 100 100 100 100 100 100 100      100 100 100 100 100 100 100 100 CRABGRASS 40 0 0 0 0 0 40 30 0 0 0 0 0 0      50 30 0 0 70 40 30 20 100 70 40 20 TEAWEED 40 10 80 40 30 20 90 70 60 50      70 50 30 0 100 90 50 40 100 100 90 50 100 100 100 70 JIMSONWEED 90 40      100 100 90 80 100 100 70 50 100 100 90 70 100 100 90 80 100 100 100 90      100 100 90 80 RICE 20 0 0 0 0 0 70 60 50 30 50 30 0 0 80 50 40 30 90 60      50 40 100 90 70 40 COCKLEBUR 70 50 80 60 50 30 100 100 80 60 100 100 100      80 100 100 80 40 100 100 100 80 100 100 100 70 COTTON 90 50 100 70 30 0      80 70 50 40 70 60 50 0 100 100 90 70 100 100 100 60 100 100 90 60      SOYBEANS 70 60 100 90 50 0 100 100 100 100 100 100 90 70 100 100 100 100      100 100 100 100 100 100 100 100 BARNYARDGRASS 60 40 90 80 70 60 90 70 60      50 0 0 0 0 100 40 20 0 100 100 100 70 100 100 100 90 WILD OATS 50 40 70      50 30 0 70 60 50 30 0 0 0 0 50 20 0 0 80 60 40 10 100 70 60 30 MORNINGGLO      RY 90 50 90 70 60 0 100 90 60 30 100 100 100 60 100 100 90 90 100 100      100 90 100 100 90 40 WHEAT 40 30 70 50 30 0 50 30 0 0 0 0 0 0 40 20 10 0      50 40 20 0 100 70 30 0 SICKLEPOD 50 0 30 0 0 0 100 100 100 70 100 90 80      60 100 100 100 90 100 100 70 50 100 100 80 40 JOHNSONGRASS 80 60 90 80      70 50 90 60 30 0 0 0 0 0 100 -- 40 30 100 100 90 70 100 100 90 70      NUTSEDGE 0 0 50 30 0 0 100 100 100 80 100 100 100 70 100 100 100 100 100      100 100 90 100 100 100 40 CORN 30 30 20 10 0 0 100 80 70 60 0 0 0 0 90      80 70 40 100 100 100 70 100 100 90 80 WILD BUCKWHEAT 9 70 100 90 80 70      100 100 100 100 100 100 100 90 100 100 100 100 100 100 100 80 100 100      100 100 BLACKGRASS 60 50 100 100 80 50 100 100 80 70 50 30 0 0 90 90 50      10 100 90 60 30 100 100 70 20 RAPE 100 90 100 100 90 80 100 100 100 100      100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 BARLEY      60 20 50 30 0 0 60 30 0 0 30 0 0 0 50 30 10 0 80 70 30 30 80 70 60 40      GREEN FOXTAIL 60 50 0 0 0 0 80 50 30 0 0 0 0 0 50 40 30 20 100 100 80 50      100 100 90 40 CHEATGRASS       100 100 70 50 30 0 0 0 LAMBSQUARTER 90 60      100 100 70 50 90 70 50 30 90 80 70 50 100 90 90 70 100 90 80 70 100 90      70 60 CHICKWEED 80 70 100 90 70 30 100 100 70 50 100 80 70 60 100 100      100 -- 100 100 100 100 100 100 100 90 DOWNY BROME 60 40 70 50 30 0        100 80 50 30 100 100 80 70 100 100 80 80        CMPD 49 CMPD 52 CMPD 55 CMPD 56 CMPD 61 CMPD 62 CMPD 63 RATE = G/HA 4      1 250 62 16 4 250 62 16 4 250 62 16 4 250 62 16 4 250 62 16 4 62 16 4      1    PREEMERGENCE GIANT FOXTAIL 80 70 90 70 50 30 100 100 70 30 0 0 0 0      40 30 0 0 100 60 50 20 50 40 0 0 VELVETLEAF 50 40 70 50 30 0 100 90 60      30 90 70 50 30 90 90 80 40 100 90 60 40 80 80 60 40 SUGARBEETS 60 30 95      90 80 70 100 100 100 100 100 100 100 100 100 100 90 70 100 100 90 80 90      80 80 70 CRABGRASS 90 50 95 90 85 80 70 50 30 0 0 0 0 0 90 80 70 30 100      90 70 40 100 80 70 30 TEAWEED 70 40 90 70 50 0 90 80 70 50 80 60 50 30      100 90 90 60 100 90 90 70 90 90 80 30 JIMSONWEED 40 20 90 70 50 30 95 90      60 40 60 50 40 30 100 90 50 -- 100 100 90 70 90 80 50 20 RICE 60 20 100      90 60 30 100 100 70 30 60 30 0 0 80 80 50 20 100 80 70 20 90 50 40 20      COCKLEBUR 70 -- 70 50 30 0 90 80 30 0 90 60 30 0 80 80 60 -- 90 80 70 40      90 80 70 20 COTTON -- 40 70 50 20 0 90 80 70 60 70 50 30 0 90 90 40 20      90 90 50 30 90 60 40 30 SOYBEANS 10 0 60 30 0 0 100 90 60 0 100 90 30 0      90 70 40 10 90 70 50 20 80 60 20 10 BARNYARDGRASS 40 30 100 100 80 50      100 100 80 40 30 0 0 0 100 90 60 30 100 90 60 20 100 100 40 10 WILD OATS      40 30 40 30 0 0 90 70 50 30 30 0 0 0 70 70 60 30 80 70 60 20 60 50 50 10      MORNINGGLORY 40 40 80 50 30 20 100 90 60 50 90 80 70 50 100 100 90 30      100 100 90 70 100 90 70 30 WHEAT 0 0 80 30 0 0 70 50 30 0 0 0 0 0 40 20      10 0 90 70 60 30 80 70 40 20 SICKLEPOD 40 -- 90 70 50 30 90 80 50 30 100      70 50 30 100 90 90 60 100 100 90 40 100 90 80 40 JOHNSONGRASS 40 0 90 80      70 50 90 80 70 30 60 0 0 0 80 40 30 10 100 90 40 -- 90 60 30 0 NUTSEDGE      30 -- 100 100 50 30 100 100 70 50 100 100 0 0 90 -- 80 30 90 80 70 70 90      30 -- 0 CORN 20 0 100 80 30 0 100 90 30 0 0 0 0 0 60 50 30 20 100 90 50      0 90 50 20 10 WILD BUCKWHEAT 80 50 100 95 90 80 90 80 70 50 100 90 80 50      100 90 90 80 100 90 80 80 90 90 -- 80 BLACKGRASS 40 0 100 90 80 70 90 80      70 60 70 50 30 0 80 70 40 30 100 90 70 30 100 50 40 20 RAPE 20 0 100 100      90 60 100 100 60 30 100 100 80 40 100 100 100 90 100 100 100 90 100 90      90 80 BARLEY 20 0 80 70 50 30 50 30 0 0 0 0 0 0 80 50 30 0 90 90 70 60      90 80 40 30 GREEN FOXTAIL 70 40 100 90 80 50 100 90 60 30 0 0 0 0 80 80      60 0 100 100 90 30 100 90 30 0 CHEATGRASS       100 70 60 50 30 0 0 0      LAMBSQUARTER 100 80 100 100 90 80 100 100 100 90 100 100 90 70 100 100      90 80 100 100 100 90 100 100 100 70 CHICKWEED 90 70 100 90 60 30 100 90      80 60 90 80 70 60 100 100 100 100 100 100 100 100 100 90 -- 40 DOWNY      BROME 20 0 90 80 50 30         90 80 40 40 100 90 80 70 100 100 90      60      CMPD 64 CMPD 65 CMPD 66 CMPD 67 CMPD 68 CMPD 73 RATE = G/HA 62      16 4 1 250 62 16 4 250 62 16 4 250 62 16 4 250 62 16 4 62 16 4 1        POSTEMERGENCE GIANT FOXTAIL 50 10 0 0 100 90 20 0 100 40 0  0 10 0 0 0 5      0 30 0 0 0 0 0 0 VELVETLEAF 100 100 90 50 100 100 100 90 100 100 100 90      100 100 100 80 100 100 100 90 90 70 50 30 SUGARBEETS 100 100 100 90 100      100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 90 70 50 30      CRABGRASS 10 0 0 0 60 40 0 0 10 0 0 0 20 0 0 0 30 30 0 0 30 0 0 0      TEAWEED 100 90 -- 70 100 100 100 50 100 100 80 50 100 70 70 60 100 90 50      40 50 30 0 0 JIMSONWEED 100 100 100 90 100 100 100 100 100 100 100 80      100 100 80 70 100 100 100 70 70 50 30 0 RICE 30 20 10 0 40 30 10 0 40 20      10 0 60 40 10 0 60 50 40 0 0 0 0 0 COCKLEBUR 100 100 100 40 100 100 100      100 100 100 100 80 100 100 100 90 100 100 80 40 90 70 50 30 COTTON 90 90      70 40 100 100 90 70 100 100 90 40 90 90 80 60 100 90 70 40 70 50 30 0      SOYBEANS 100 100 70 50 100 100 100 100 100 100 100 100 100 100 100 100      100 100 100 30 80 60 30 0 BARNYARDGRASS 90 50 30 10 90 70 40 10 100 80      30 0 40 10 0 0 100 80 40 0 0 0 0 0 WILD OATS 40 0 0 0 30 10 10 0 10 10 0      0 20 0 0 0 50 30 0 0 0 0 0 0 MORNINGGLORY 100 100 100 60 100 100 100 100      100 100 100 100 100 90 70 30 100 90 70 30 80 70 50 30 WHEAT 20 0 0 0 10      10 0 0 0 0 0 0 0 0 0 0 20 10 0 0 0 0 0 0 SICKLEPOD 100 70 50 0 100 100      100 70 100 100 90 40 100 90 80 40 60 60 50 40 50 30 0 0 JOHNSONGRASS 90      60 40 20 60 50 30 0 40 10 0 0 40 30 30 0 90 50 20 0 0 0 0 0 NUTSEDGE 100      100 100 60 -- 100 30 0 100 60 40 30 100 100 100 80 90 80 -- 70 60 30 0 0      CORN 30 10 0 0 100 100 90 50 100 80 70 10 40 10 0 0 80 50 -- 30 50 40 30      20 WILD BUCKWHEAT 100 100 100 100 100 100 100 100 100 100 100 100 100      100 100 100 100 100 90 70 80 70 50 30 BLACKGRASS 40 30 20 0 90 80 30 0      60 20 0 -- 50 30 20 0 80 70 50 20 0 0 0 0 RAPE 100 100 100 100 100 100      100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 80 50 30      BARLEY 30 10 0 0 40 20 10 0 30 10 0 0 20 0 0 0 -- 30 10 0 0 0 0 0 GREEN      FOXTAIL 70 50 -- 20 100 90 70 20 70 50 30 0 30 0 0 0 60 40 20 0 0 0 0 0      CHEATGRASS                     0 0 0 0 FIELD VIOLET      0 0 0 0 LAMBSQUARTER 90 70 60 50 100 100 80 50 100 100 100 70 100 70 50      20 100 100 70 60 50 30 0 0 CHICKWEED 100 100 90 90 100 100 100 100 100      100 100 100 100 100 100 40 100 100 100 90 DOWNY BROME 40 30 30 0 100 100      40 0 70 10 0 0 50 40 20 0 80 70 70 30        CMPD 64 CMPD 65 CMPD 66 CMPD 67 CMPD 68 CMPD 73 RATE = G/HA 250 62 16      4 250 62 16 4 250 62 16 4 250 62 16 250 62 16 250 62 16 4        PREEMERGENCE GIANT FOXTAIL 40 0 0 0 90 -- 80 20 40 20 0 0 0 0 0 20 0 0 5      0 30 0 0 VELVETLEAF 90 90 80 40 100 90 70 40 100 90 90 30 90 70 50 50 40      -- 90 70 50 30 SUGARBEETS 100 90 90 90 100 100 100 90 100 100 100 90 100      90 80 90 90 80 90 70 50 30 CRABGRASS 100 80 -- 40 90 90 60 30 90 80 30 0      40 10 0 40 20 0 60 30 0 0 TEAWEED 90 90 80 40 100 100 90 20 100 90 70 --      80 70 20 90 70 30 70 50 30 0 JIMSONWEED 100 90 80 50 100 100 90 40 90 80      40 0 70 60 40 80 70 40 80 50 30 0 RICE 90 70 30 10 70 40 10 0 70 60 0 0      60 50 30 60 40 30 60 30 0 0 COCKLEBUR 90 70 70 30 90 90 80 70 90 80 80      30 80 70 30 90 50 0 70 50 30 0 COTTON 90 80 -- 0 90 80 70 20 90 90 50 10      30 20 0 50 0 0 40 20 0 0 SOYBEANS 50 30 20 10 100 90 50 20 90 90 30 20      20 10 10 20 10 10 50 30 0 0 BARNYARDGRASS 80 40 20 0 90 80 30 0 90 40 0      0 30 10 0 50 20 0 50 30 0 0 WILD OATS 20 10 -- -- 50 40 30 30 40 30 20      10 40 30 20 60 50 40 50 0 0 0 MORNINGGLORY 100 90 90 80 100 100 90 90      100 100 90 70 40 40 0 80 70 40 70 50 30 0 WHEAT 30 20 10 0 10 0 0 0 10 0      0 0 10 0 0 40 10 0 0 0 0 0 SICKLEPOD 100 80 60 -- 100 100 90 80 100 90      50 40 80 70 30 40 -- 0 70 30 0 0 JOHNSONGRASS 60 50 40 20 30 20 10 0 20      20 0 0 60 20 0 40 0 0 30 0 0 0 NUTSEDGE 100 100 90 40 80 70 40 0 80 --      50 0 90 90 40 80 70 30 80 50 30 0 CORN 70 20 10 0 100 80 30 10 100 80 20      10 10 0 0 90 20 10 30 0 0 0 WILD BUCKWHEAT 100 90 80 80 100 100 100 90      100 100 100 90 100 90 80 100 90 80 90 70 50 30 BLACKGRASS 70 60 30 0 80      80 40 -- 60 30 20 0 100 40 0 70 50 30 60 30 0 0 RAPE 100 100 90 90 100      100 90 80 100 90 90 80 100 100 90 100 90 90 70 50 30 0 BARLEY 30 -- 20      10 60 40 20 0 30 10 0 0 20 0 0 60 30 20 0 0 0 0 GREEN FOXTAIL 90 40 20 0      100 90 50 40 100 90 30 0 0 0 0 40 0 0 60 30 0 0 CHEATGRASS          60 30 0 0 LAMBSQUARTER 100 100 100 70 100 90 50 40 100 90 90 30 90      90 80 90 80 70 90 70 50 30 CHICKWEED 100 100 100 90 100 100 100 80 100      100 90 90 100 100 80 100 90 90 DOWNY BROME 90 80 30 10 70 40 30 30 40 20      0 0 20 0 0 70 30 0

Test C

The Corn and Sorghum Herbicide Test included the following species in both the preemergence and postemergence evaluations:

    ______________________________________                                                  SPECIES                                                               Category   Common Name  Scientific Name                                        ______________________________________                                         Crops      Corn         Zea mays                                                          Soybean      Glycine max                                                       Sorghum      Sorghum bicolor                                        Grasses    Green foxtail                                                                               Setaria viridis                                                   Giant foxtail                                                                               Setaria faberii                                                   Johnsongrass Sorghum halepense                                                 Barnyardgrass                                                                               Echinochloa crus-galli                                            Fall panicum Panicum dichotomiflorum                                           Crabgrass    Digitaria sanguinalis                                             Nutsedge     Cyperus rotundus                                       Broadleaves                                                                               Cocklebur    Xanthium pensylvanicum                                            Morningglory Ipomoea hederacea                                                 Velvetleaf   Abutilon theophrasti                                              Jimsonweed   Datura stramonium                                                 Lambsquarters                                                                               Chenopodium album                                                 Pigweed      Amaranthus retroflexus                                            Smartweed    Polygonum persicaris                                   ______________________________________                                    

Postemergence

Postemergence plantings were grown in Sassafras sandy loam soil. Corn and soybeans were grown in separate 25 cm diameter containers. Sorghum and the seven grass weed species were grown in two 18 cm diameter containers, 4 species per container. The seven broadleaf weed species were also grown in two 18 cm diameter containers, 4 species in one container, 3 species in the second container. One additional planting of corn in an 18 cm diameter container was made. The soil surface of this additional container of corn was covered with the absorbent, perlite, before spray treatment so that test chemicals would enter the plant only via the foliage. The plants were grown 10-21 days, dependent upon the species and then sprayed postemergence with the test chemicals dissolved in a nonphytotoxic solvent.

Preemergence

Preemergence plantings were grown in fertilized Tama silt loam soil. These plantings are identical to those described in the postemergence section, with the exception of the corn planting having perlite covering the soil surface. These plantings were made the day of or the day before spraying the test chemicals dissolved in a nonphytotoxic solvent.

Evaluation

Treated plants and controls were maintained in the greenhouse for 2 to 4 weeks. Visual planting response ratings were made on a percentage scale of 0 to 100 in comparison with a control where 0=no injury, and 100=death. Response ratings are contained in Table C.

                  TABLE C                                                          ______________________________________                                         CMPD 36                                                                        RATE GM/HA     125    64     32   16   8   4   2                               ______________________________________                                         POSTEMERGENCE                                                                  CORN           40     20     0    0    0   0   0                               SOYBEANS       100    100    100  100  95  75  55                              GREEN FOXTAIL  0      0      0    0    0   0   0                               GIANT FOXTAIL  0      0      0    0    0   0   0                               FALL PANICUM   0      0      0    0    0   0   0                               LARGE CRABGRASS                                                                               0      0      0    0    0   0   0                               JOHNSONGRASS   35     0      0    0    0   0   0                               SORGHUM        25     0      0    0    0   0   0                               PURPLE NUTSEDGE                                                                               70     40     0    0    0   0   0                               VELVETLEAF     100    100    95   70   65  35  0                               COCKLEBUR      100    100    100  100  95  70  50                              LADY SMARTWEED 100    100    100  85   65  40  25                              LAMBSQUARTER   100    95     85   70   60  30  0                               REDROOT PIGWEED                                                                               100    100    100  100  85  60  35                              IVY MORNINGLORY                                                                               100    100    100  100  90  65  45                              JIMSONWEED     100    100    100  95   75  45  30                              PERLITE CORN   25     0      0    0    0   0   0                               ______________________________________                                         RATE GM/HA    250      125     64   32   16                                    ______________________________________                                         PREEMERGENCE                                                                   CORN          40       20      0    0    0                                     SOYBEANS      80       55      20   0    0                                     GREEN FOXTAIL 30       0       0    0    0                                     GIANT FOXTAIL 20       0       0    0    0                                     FALL PANICUM  20       0       0    0    0                                     LARGE CRABGRASS                                                                              20       0       0    0    0                                     BARNYARDGRASS 40       20      0    0    0                                     JOHNSONGRASS  90       75      60   30   0                                     SORGHUM       45       35      30   0    0                                     PURPLE NUTSEDGE                                                                              90       75      40   30   0                                     VELVETLEAF    100      70      55   30   0                                     COCKLEBUR     95       80      50   20   0                                     LADY SMARTWEED                                                                               100      100     80   50   25                                    LAMBSQUARTER  100      100     75   55   35                                    REDROOT PIGWEED                                                                              100      100     95   60   40                                    IVY MORNINGLORY                                                                              95       90      60   35   0                                     JIMSONWEED    100      80      50   25   0                                     ______________________________________                                         CMPD 56                                                                        RATE GM/HA      125     64      32    16                                       ______________________________________                                         POSTEMERGENCE                                                                  CORN            85      75      65    50                                       SOYBEANS        100     100     100   100                                      GREEN FOXTAIL   40      25      0     0                                        GIANT FOXTAIL   40      25      0     0                                        FALL PANICUM    45      25      0     0                                        LARGE CRABGRASS 0       0       0     0                                        BARNYARDGRASS   100     90      65    35                                       JOHNSONGRASS    70      65      60    40                                       SORGHUM         90      85      70    50                                       PURPLE NUTSEDGE 100     100     70    35                                       VELVETLEAF      100     90      55    35                                       COCKLEBUR       100     80      65    35                                       LADY SMARTWEED  95      85      60    45                                       LAMSQUARTER     55      25      0     0                                        REDROOT PIGWEED 100     100     95    65                                       IVY MORNINGLORY 50      20      0     0                                        JIMSONWEED      100     100     90    60                                       PERLITE CORN    70      60      55    40                                       ______________________________________                                         RATE GM/HA       250        125    64                                          ______________________________________                                         PREEMERGENCE                                                                   CORN             0          0      0                                           SOYBEANS         40         30     0                                           GREEN FOXTAIL    20         0      0                                           GIANT FOXTAIL    20         0      0                                           FALL PANICUM     0          0      0                                           LARGE CRABGRASS  0          0      0                                           BARNYARDGRASS    0          0      0                                           JOHNSONGRASS     55         25     0                                           SORGHUM          0          0      0                                           PURPLE NUTSEDGE  0          0      0                                           VELVETLEAF       0          0      0                                           COCKLEBUR        0          0      0                                           LADY SMARTWEED   35         20     0                                           LAMBSQUARTER     40         30     0                                           REDROOT PIGWEED  60         35     0                                           IVY MORNINGLORY  0          0      0                                           JIMSONWEED       30         0      0                                           ______________________________________                                    

Test D

Weed species were planted 3 or 4 per 15-cm diameter pot in Sassafras sandy loam (pH 6.8; 1% OM). Cotton was planted separately in the same sized pot. Postemergence plantings were made 12-16 days prior to treating so plants were in the 2- to 3-leaf stage (5-12 cm tall). Preemergence plantings were made the day before treating. Compounds were sprayed in a suitable nonphytotoxic solvent at 374 l/ha, then after 3 weeks of growth in a greenhouse, plant responses were visually rated on a percent scale where 0=no injury and 100=plant death. The following species were included:

    ______________________________________                                                                       Planting                                                                       Depth                                            Common Name   Latin Name      (cm)                                             ______________________________________                                         Cotton (Coker 315)                                                                           Gossypium hirsutum                                                                             2                                                Barnyardgrass Echinochloa crus-galli                                                                         1                                                Bermudagrass  Cynodon dactylon                                                                               1                                                Broadleaf signalgrass                                                                        Brachiaria platyphylla                                                                         1                                                Crabgrass     Digitaria sanguinalis                                                                          1                                                Fall panicum  Panicum dichotomiflorum                                                                        1                                                Goosegrass    Eleusin indica  1                                                Johnsongrass  Sorghum halepense                                                                              1                                                Nutsedge      Cyperus rotundus                                                                               3                                                Cocklebur     Xanthium pensylvanicum                                                                         3                                                Ivy leaf morningglory                                                                        Ipomea hederacea                                                                               3                                                Lambsquarters Chenopodium album                                                                              1                                                Pigweed       Amaranthus retroflexus                                                                         1                                                Prickly sida  Sida spinosa    1                                                Purslane      Portulaca oleracea                                                                             1                                                Sicklepod     Cassia obtusifolia                                                                             3                                                Smartweed     Polygonum persicaria                                                                           1                                                Velvetleaf    Abutilon theophrasti                                                                           3                                                Ground cherry Physalis heterophylla                                                                          1                                                ______________________________________                                    

The results are shown in Table D.

                  TABLE D                                                          ______________________________________                                         CMPD 28                                                                        RATE GM/HA     125     64      32    16   8                                    ______________________________________                                         PREEMERGENCE                                                                   COTTON         90      90      80    50   20                                   REDROOT PIGWEED                                                                               100     100     100   90   80                                   LAMBSQUARTER   50      50      0     0    0                                    VELVETLEAF     98      90      80    70   70                                   PRICKLY SIDA   60      60      50    40   20                                   SICKLEPOD      30      30      30    0    0                                    COCKLEBUR      90      90      90    90   60                                   CMN PURSLANE   80      70      60    60   30                                   IVY MORNINGLORY                                                                               90      90      70    0    0                                    GOOSEGRASS     30      20      0     0    0                                    BERMUDAGRASS   30      20      0     0    0                                    BARNYARDGRASS  80      70      60    30   20                                   JOHNSONGRASS   50      40      0     0    0                                    FALL PANICUM   50      50      50    0    0                                    LARGE CRABGRASS                                                                               20      20      0     0    0                                    BRDLF SGNLGRASS                                                                               0       0       0     0    0                                    PURPLE NUTSEDGE                                                                               100     100     70    70   50                                   LADY SMARTWEED 90      90      80    80   80                                   GROUND CHERRY  70      60      60    50   30                                   ______________________________________                                    

Test E

Sixteen-cm-diameter Airlite plastic pots were partially filled with Tama silt loam soil and the soil saturated with water. Japonica and Indica rice seedlings at the 2.0 to 2.5 leaf stage were transplanted into 1/3 of the pots. Into another third of the pots were transplanted seedling or sprouted tubers of water plantain (Alisma trivale), Scripus (Scirpus paludosus), Cyperus (Cyperus esculentus), and arrowhead (Sagittaria spp.). The remaining pots were planted and barnyardgrass (Echinochloa crus-galli) seeds and sprouted tubers of water chestnut (Eleocharis spp.). These weeds all represent major rice weeds or genera of weeds important in rice. Three to four days after planting, the water level was raised to 3 cm (about 1200 ml/pot) and maintained at this level throughout the test. Chemical treatments were applied directly to the paddy water, within 24 hours of raising the water, after being formulated in a nonphytotoxic solvent. The pots were maintained in the greenhouse. Rates of application and plant response ratings made 21 days after treatment are summarized in Table E.

                  TABLE E                                                          ______________________________________                                         CMPD 1                                                                         RATE = G/HA       16    8        4    2                                        ______________________________________                                         BARNYARDGRASS     40    20       0    0                                        WATERCHESTNUT     55    30       0    0                                        ARROWHEAD         90    85       0    0                                        SCIRPUS           50    30       0    0                                        WATER PLAINTAIN   95    90       0    0                                        RICE JAPONICA     65    30       10   0                                        RICE INDICA       20     0       0    0                                        ______________________________________                                         CMPD 5                                                                         RATE = G/HA     125    64       32   16    8                                   ______________________________________                                         BARNYARDGRASS   20     0        0    0     0                                   WATERCHESTNUT   20     20       0    0     0                                   ARROWHEAD       90     80       65   0     0                                   SCIRPUS          0     0        0    0     0                                   YELLOW NUTSEDGE 30     0        0    0     0                                   WATER PLAINTAIN 85     70       65   0     0                                   RICE JAPONICA   20     0        0    0     0                                   RICE INDICA     20     0        0    0     0                                   ______________________________________                                         CMPD 8                                                                         RATE = G/HA    125    64       32   16     8                                   ______________________________________                                         BARNYARDGRASS  80     75       50    0      0                                  WATERCHESTNUT  95     90       90   80     70                                  SCIRPUS        100    100      100  100    95                                  YELLOW NUTSEDGE                                                                               90     85       80   70      0                                  WATER PLAINTAIN                                                                               100    100      98   95     90                                  RICE JAPONICA  75     60       50   40     30                                  RICE INDICA    30     25       20    0      0                                  ______________________________________                                         CMPD 11                                                                        RATE = G/HA    125      64    32    16  8                                      ______________________________________                                         BARNYARDGRASS  40       30     0     0  0                                      WATERCHESTNUT  90       90    85    75  70                                     SCIRPUS        100      95    90    85  75                                     YELLOW NUTSEDGE                                                                               75       40     0     0  0                                      WATER PLAINTAIN                                                                               98       95    95    80  0                                      RICE JAPONICA  60       50    40    20  0                                      RICE INDICA    20       20    20    20  0                                      ______________________________________                                         CMPD 12                                                                        RATE = G/HA     64     32       16   8     4                                   ______________________________________                                         BARNYARDGRASS   0      0        0    0     0                                   WATERCHESTNUT   60     60       30   0     0                                   SCIRPUS         0      0        0    0     0                                   YELLOW NUTSEDGE 0      0        0    0     0                                   WATER PLAINTAIN 0      0        0    0     0                                   RICE JAPONICA   0      0        0    0     0                                   RICE INDICA     0      0        0    0     0                                   ______________________________________                                         CMPD 13                                                                        RATE = G/HA    64        32    16    8   4                                     ______________________________________                                         BARNYARDGRASS  0         0     0     0   0                                     WATERCHESTNUT  70        0     0     0   0                                     SCIRPUS        0         0     0     0   0                                     YELLOW NUTSEDGE                                                                               0         0     0     0   0                                     WATER PLAINTAIN                                                                               0         0     0     0   0                                     RICE JAPONICA  0         0     0     0   0                                     RICE INDICA    0         0     0     0   0                                     ______________________________________                                         CMPD 29                                                                        RATE = G/HA    250    125    64   32  16  8    4                               ______________________________________                                         BARNYARDGRASS  80     60     50   50  0   0    0                               WATERCHESTNUT  75     65     60   30  0   0    0                               ARROWHEAD      --     --     100  90  90  50   0                               SCIRPUS        30      0     0     0  0   90   0                               YELLOW NUTSEDGE                                                                               80     30     20   20  0   100  0                               WATER PLAINTAIN                                                                               100    95     90   70  0   95   0                               CMN ARROWHEAD  95     90     85   80  0   --   --                              RICE JAPONICA  25     20     15   10  0   0    0                               RICE INDICA    30     25     20   10  0   0    0                               ______________________________________                                         CMPD 30                                                                        RATE = G/HA    125      64     32    16  8                                     ______________________________________                                         BARNYARDGRASS  20       20     0     0   0                                     WATERCHESTNUT   0       0      0     0   0                                     ARROWHEAD      60       0      0     0   0                                     SCIRPUS        40       0      0     0   0                                     YELLOW NUTSEDGE                                                                               60       0      0     0   0                                     WATER PLAINTAIN                                                                               40       0      0     0   0                                     RICE JAPONICA  30       0      0     0   0                                     RICE INDICA    20       0      0     0   0                                     ______________________________________                                         CMPD 56                                                                        RATE = G/HA    125    64      32   16     8                                    ______________________________________                                         BARNYARDGRASS  80     30       0   0      0                                    WATERCHESTNUT  95     85      75   0      0                                    ARROWHEAD      90     90      70   0      0                                    SCIRPUS        100    98      --   0      0                                    YELLOW NUTSEDGE                                                                               40      0       0   0      0                                    WATER PLAINTAIN                                                                               100    90      100  80     40                                   RICE JAPONICA  60     20      10   0      0                                    RICE INDICA    50     20      10   0      0                                    ______________________________________                                         CMPD 61                                                                        RATE = G/HA     64     32      16   8     4                                    ______________________________________                                         BARNYARDGRASS   70     50       0   0     0                                    WATERCHESTNUT   80     80       0   0     0                                    SCIRPUS         100    100     80   40    0                                    YELLOW NUTSEDGE 100    90      80   75    70                                   WATER PLAINTAIN 100    100     100  95    90                                   RICE JAPONICA   55     45      30   0     0                                    RICE INDICA     20     10      10   0     0                                    ______________________________________                                         CMPD 64                                                                        RATE = G/HA     64     32       16  8     4                                    ______________________________________                                         BARNYARDGRASS   65     60       30   0    0                                    WATERCHESTNUT   90     90       70  70    --                                   SCIRPUS         100    100      85  70    0                                    YELLOW NUTSEDGE 95     90       50  40    0                                    WATER PLAINTAIN 100    100      85   0    0                                    RICE JAPONICA   50     40       30  10    10                                   RICE INDICA     25     20       10  10    10                                   ______________________________________                                    

Test F

For the postemergence phase of the test, crop and weed species were planted in a Sassafras sandy loam soil (approximately 1% organic matter) one to three weeks before application so that they were present as young plants at the time of treatment. Alterntively, for postemergence tests, plants were grown in a 50:50 mixture of commercially available potting mix and Sassafras soil. Plantings for the preemergence phase were made in a Tama silt loam soil (approximately 3% organic matter) the day before, or the day of treatment. Approximate planting depths were corn and soybeans--3 to 4 cm; morningglory, cocklebur, and nutsedge--2.5 to 3 cm; velvetleaf, sicklepot, and sesbania--2cm; all other species--0.5 cm.

The test chemicals were dissolved/suspended in a nonphytotoxic solvent in concentrations required to obtain the desired rate of application. The solutions or suspensions were then applied as soil/foliage sprays to the young plants (postemergence phase) and to the soil surfaces of the freshly planted containers (preemergence phase). Application was made utilizing an automatic spray machine at a spray volume of 374 liters per hectare. Immediately after treatment, the containers were transferred to a greenhouse and subsequently watered on a demand basis, taking care not to wet the foliage of the plants in the postemergence phase of the test.

The following species were included in the test:

    ______________________________________                                                                     APPROXIMATE                                                                    GROWTH                                                                         STAGE                                                                          AT POST                                            PLANT SPECIES                                                                              SCIENTIFIC NAME APPLICATION                                        ______________________________________                                         Grass Weeds                                                                    Barnyardgrass                                                                              Echinochloa crus-galli                                                                         2-3 leaves                                         Giant foxtail                                                                              Setaria faberi  2-3 leaves                                         Green foxtail                                                                              Setaris viridis 2-3 leaves                                         Johnsongrass                                                                               Sorghum halepense                                                                              2-3 leaves                                         Fall panicum                                                                               Panicum dichotomiflorum                                                                        2-3 leaves                                         Purple nutsedge                                                                            Cyperus rotundus                                                                               5-6 leaves                                         Signalgrass Brachiaria platyphylla                                                                         2-3 leaves                                         Crabgrass   Digitaria sanguinalis                                                                          2-3 leaves                                         Velvetleaf  Abutilon theophrasti                                                                           2-3 leaves                                         Jimsonweed  Datura stramonium                                                                              1-2 true leaves                                    Hemp sesbania                                                                              Sesbania exaltata                                                                              1st true leaf                                      Sicklepod   Cassia obtusifolia                                                                             1st true leaf                                      Cocklebur   Xanthium pensylvanicum                                                                         2nd true leaf                                      Ivyleaf     Ipomoea hederacea                                                                              1-2 true leaves                                    morningglory                                                                   Ladysthumb  Polygonum persicaria                                                                           3-4 leaves                                         smartweed                                                                      Pigweed     Amaranthus retroflexus                                                                         4-5 leaves                                         Lambsquarters                                                                              Chenopodium album                                                                              4-5 leaves                                         Teaweed     Sida spinosa    2-3 leaves                                         Eastern black-                                                                             Solanum ptycanthum                                                                             2nd true leaf                                      nightshade                                                                     Corn (Funk  Zea mays        2-3 leaves                                         G4646)                                                                         Soybeans    Glycine max     1st trifoliate                                     (Williams)                                                                     ______________________________________                                    

Visual plant response ratings were made approximately two and four weeks after treatment for the post- and pre-emergence phases, respectively. The ratings were made on a percentage scale of 0 to 200, where 0=no injury, and 100=death of plants. Plant response ratings are summarized in Table F.

                  TABLE F                                                          ______________________________________                                         CMPD 28                                                                        RATE GM/H     250      125     64   32   16                                    ______________________________________                                         PREEMERGENCE                                                                   SOYBEANS      40       0       0    0    0                                     CORN          20       10      10   0    0                                     VELVETLEAF    60       50      40   20   0                                     JIMSONWEED    70       70      40   0    0                                     SICKLEPOD     40       20      0    0    0                                     HEMP SESBANIA 40       20      0    0    0                                     COCKLEBUR     75       50      30   0    0                                     IVY MORNINGLORY                                                                              50       50      30   0    0                                     REDROOT PIGWEED                                                                              95       90      75   60   30                                    LAMBSQUARTER  100      80      60   50   40                                    PRICKLY SIDA  40       20      0    0    0                                     BARNYARDGRASS 50       20      0    0    0                                     GIANT FOXTAIL 20       0       0    0    0                                     GREEN FOXTAIL 0        0       0    0    0                                     JOHNSONGRASS  30       0       0    0    0                                     FALL PANICUM  40       20      0    0    0                                     LARGE CRABGRASS                                                                              0        0       0    0    0                                     BRDLF SGNLGRASS                                                                              0        0       0    0    0                                     PURPLE NUTSEDGE                                                                              80       70      60   40   20                                    LADY SMARTWEED                                                                               85       75      60   40   20                                    BLACK NIGHTSHAD                                                                              75       50      30   0    0                                     ______________________________________                                         CMPD 34                                                                        RATE GM/H     125     64     32    16   8    4                                 ______________________________________                                         POSTEMERGENCE                                                                  SOYBEANS      20      0      0     0    0    0                                 CORN          40      30     0     0    0    0                                 VELVETLEAF    80      70     50    40   30   20                                JIMSONWEED    80      60     50    40   30   20                                SICKLEPOD     50      30     0     0    0    0                                 HEMP SESBANIA 98      90     70    40   20   0                                 COCKLEBUR     100     100    70    60   50   40                                IVY MORNINGLORY                                                                              100     100    100   100  70   50                                REDROOT PIGWEED                                                                              98      90     80    70   40   20                                LAMBSQUARTER  50      30     20    0    0    0                                 PRICKLY SIDA  0       0      0     0    0    0                                 BARNYARDGRASS 50      40     30    0    0    0                                 GIANT FOXTAIL 30      0      0     0    0    0                                 GREEN FOXTAIL 30      0      0     0    0    0                                 JOHNSONGRASS  50      30     0     0    0    0                                 FALL PANICUM  30      0      0     0    0    0                                 LARGE CRABGRASS                                                                              0       0      0     0    0    0                                 BRDLF SGNLGRASS                                                                              50      30     0     0    0    0                                 PURPLE NUTSEDGE                                                                              80      70     60    50   0    0                                 BLACK NIGHTSHAD                                                                              95      85     80    20   0    0                                 ______________________________________                                    

Test G

The species below were planted.

    ______________________________________                                         Name            Genus Species   Size (cm)                                      ______________________________________                                         Blackgrass, Stage II                                                                           Alopecurus myosuroides                                                                         14.0                                           Lambsquarters, Common                                                                          Chenopodium album                                                                              4.0                                            Catchweed Beadstraw                                                                            Galium aparine  9.0                                            Russian Thistle Salsoa kali     6.0                                            Black Nightshade, Eastern                                                                      Solanum nigrum  2.0                                            Field Pennycress                                                                               Thlaspi arvense 2.5                                            Ivyleaf Speedwell                                                                              Veronica hederaefolia                                                                          5.0                                            Field Speedwell, Common                                                                        Veronica persica                                                                               6.0                                            Field Pansy     Viola arvensis  1.5                                            ______________________________________                                    

Two days later, a second series were planted using the following species.

    ______________________________________                                         Name          Genus Species   Size (cm)                                        ______________________________________                                         Blackgrass, Stage I                                                                          Alopecurus myosuroides                                                                         6.0                                              Wild Oat Stage II                                                                            Avena fatua     22.0                                             Sugar Beet    Beta vulgaris   8.0                                              Oilseed Rape  Brassica napus  13.0                                             Kochia        Kochia scoparia 5.0                                              Mayweed, Scentless                                                                           Matricaria inodora                                                                             4.0                                              Annual Bluegrass                                                                             Poa annua       7.0                                              Wild Buckwheat                                                                               Polygonum convolvulus                                                                          7.0                                              ______________________________________                                    

Seven days following the first planting, a third pot was prepared with the following species.

    ______________________________________                                         Name            Genus Species Size (cm)                                        ______________________________________                                         Jointed Goatgrass                                                                              Aegilops cylindrica                                                                          12.0                                             Wild Oat Stage I                                                                               Avena fatua   15.0                                             Cheatgrass      Bromus secalinus                                                                             8.0                                              Winter Barley `cv. Igri`                                                                       Hordeum vulgare                                                                              18.0                                             Spring Barley `cv. Klages`                                                                     Hordeum vulgare                                                                              24.0                                             Annual Ryegrass Lolium multiflorum                                                                           11.0                                             Green Foxtail   Setaria virdis                                                                               6.0                                              Winter Wheat `cv. Centurk`                                                                     Triticum aestivum                                                                            23.0                                             Spring Wheat `cv. Era`                                                                         Triticum aestivum                                                                            16.0                                             Downy Brome     Bromus tectorum                                                                              8.0                                              ______________________________________                                    

All postemergence plantings were grown in the greenhouse until herbicide application. Preemergence treaments were prepared immediately before herbicide application in the same manner as described for the postemergence treatments. Application of the herbicide was accomplished by first diluting the technical material in a nonphytotoxic solvent and applying over the surface of the plants and soil of all six components using a belt sprayer.

After treatment, all components were removed to the greenhouse where they were maintained for 21 days at temperatures of 19° C. night and 30° C. day with a 16-hour photoperiod and a relative humidity of 45 to 80 percent. At this time, all species were rated using a visual scale of 0 representing no control and 100 representing complete control. Test results are summarized in Table G.

    TABLE G            CMPD CMPD 1 CMPD 5 CMPD 6 CMPD 8 CMPD 9 11 RATE G/HA 32 16 8 4 2      64 32 16 8 4 125 64 32 16 125 64 32 27 8 4 64 32 16 8 4 2 125        PREEMERGENCE SPRING WHEAT 30 10 0 0 0 0 0 0 0 0 10 0 0 0 20 10 0 0 0 0 3      0 20 10 0 0 0 0 WINTER WHEAT 30 20 0 0 0 0 0 0 0 0 0 0 0 0 20 20 10 0 0      0 30 10 0 0 0 0 10 SPRING BARLEY 60 60 40 20 0 0 0 0 0 0 10 0 0 0 30 10      0 0 0 0 50 40 30 10 0 0 10 WINTER BARLEY 80 40 30 10 0 10 0 0 0 0 10 0 0      0 50 50 20 10 0 0 50 50 20 10 0 0 20 WILD OATS 20 10 0 0 0 0 0 0 0 0 20      0 0 0 20 10 0 0 0 0 30 20 10 0 0 0 10 DOWNY BROME 20 20 0 0 0 0 0 0 0 0      10 0 0 0 50 30 10 0 0 0 40 40 20 10 0 0 10 CHEAT GRASS 20 10 10 0 0 0 0      0 0 0 0 0 0 0 80 50 30 10 0 0 60 50 30 20 10 0 20 BLACKGRASS 80 60 60 30      10 30 10 0 0 0 40 10 10 0 80 80 70 50 20 10 90 90 80 70 70 40 80 ANN.      BLUEGRASS 90 90 50 40 20 40 10 0 0 0 30 30 20 0 70 70 60 50 40 40 70 70      60 40 30 10 70 ANNUAL RYEGRASS 20 10 0 0 0 30 10 0 0 0 20 20 0 0 20 10 0      0 0 0 30 10 10 0 0 0 40 JOINT GOATGRASS 0 0 0 0 0 20 20 0 0 0 10 0 0 0      20 10 0 0 0 0 20 20 10 0 0 0 30 GREEN FOXTAIL 100 50 20 10 0 10 0 0 0 0      20 0 0 0 90 70 70 30 0 0 60 60 60 40 30 0 70 RAPE 100 100 100 90 70 80      80 70 40 20 100 100 100 80 100 100 90 90 80 70 100 100 100 90 90 80 100      CTCHWD BEDSTRAW 80 70 50 40 20 70 60 40 0 0 90 90 30 20 90 70 40 40 20 0      70 70 50 40 40 20 90 WILD BUCKWHEAT 70 70 70 60 40 90 70 50 30 0 100 100      90 70 90 80 70 50 10 0 90 90 80 70 50 40 100 KOCHIA 60 60 40 20 0 20 0 0      0 0 50 50 30 0 50 20 20 0 0 0 40 0 0 0 0 0 30 SNTLS MAYWEED 90 90 80 70      30 70 50 30 0 0 90 40 30 10 80 80 70 70 60 40 90 90 90 80 60 40 100      BLACK NIGHTSHAD 70 60 60 40 30 40 10 0 0 0 90 80 60 10 70 70 60 50 30 20      50 50 50 50 30 20 60 FIELD SPEEDWELL 50 50 40 30 0 30 30 0 0 0 40 30 20      0 60 50 50 40 40 30 50 50 40 30 30 20 70 IVYLF SPEEDWELL 100 90 80 60 30      100 80 70 40 10 100 100 60 30 70 50 40 20 0 0 40 30 0 0 0 0 100 SUGARBEET       100 100 100 90 80 100 100 100 90 90 100 100 100 100 90 80 80 80 70 60      100 90 90 90 80 70 100 LAMBSQUARTER 100 90 80 80 60 80 70 40 20 0 100 90      90 70 100 90 90 80 70 50 100 90 80 80 60 40 90 FIELD PENNYCRES 100 100      80 70 40 70 20 10 0 0 100 100 80 50 100 100 100 90 80 70 100 100 100 90      90 70 100 FIELD VIOLET 100 90 90 70 50 100 100 90 80 40 100 100 90 70 70      70 60 60 50 40 70 50 40 40 20 0 80 POSTEMERGENCE SPRING WHEAT 20 -- 0 0      0 0 0 0 0 0 0 0 0 0 20 10 10 0 0 0 0 0 0 0 0 0 10 WINTER WHEAT 10 0 0 0      0 0 0 0 0 0 0 0 0 0 10 10 0 0 0 0 0 0 0 0 0 0 20 SPRING BARLEY 10 0 0 0      0 0 0 0 0 0 0 0 0 0 20 10 10 0 0 0 20 10 0 0 0 0 20 WINTER BARLEY 30 20      10 10 0 0 0 0 0 0 0 0 0 0 60 30 30 10 10 0 40 30 20 10 0 0 20 WILD OATS      0 0 0 0 0 0 0 0 0 0 0 0 0 0 10 10 0 0 0 0 20 0 0 0 0 0 0 WILD OATS STG 2      0 0 0 0 0 10 0 0 0 0 0 0 0 0 0 10 10 0 0 0 0 0 0 0 0 0 0 DOWNY BROME 30      30 10 0 0 0 0 0 0 0 10 0 0 0 20 10 0 0 0 0 20 10 0 0 0 0 0 CHEAT GRASS      40 30 30 0 0 0 0 0 0 0 0 0 0 0 50 50 50 30 20 10 30 10 0 0 0 0 0      BLACKGRASS 50 40 20 20 0 0 0 0 0 0 0 0 0 0 70 70 50 40 20 10 60 60 50 40      20 0 10 BLACKGRASS STG2 40 40 30 30 0 30 20 0 0 0 0 0 0 0 80 70 60 50 20      0 70 60 50 20 0 0 30 ANN. BLUEGRASS 0 0 0 0 0 0 0 0 0 0 0 0 0 0 20 20 10      10 0 0 60 50 30 10 0 0 20 ANNUAL RYEGRASS 10 0 0 0 0 0 0 0 0 0 0 0 0 0      40 40 20 20 10 0 50 50 30 10 0 0 20 JOINT GOATGRASS 0 0 0 0 0 0 0 0 0 0      0 0 0 0 40 40 20 20 10 0 50 50 30 10 0 0 20 GREEN FOXTAIL 0 0 0 0 0 30 0      0 0 0 20 20 0 0 70 70 50 30 20 0 40 40 20 10 0 0 40 RAPE 100 100 100 100      100 100 100 100 90 80 100 100 100 100 100 100 100 100 100 100 100 100      100 100 100 90 100 CTCHWD BEDSTRAW 90 60 40 20 0 10 10 0 0 0 80 70 30 20      90 70 60 50 30 20 70 40 30 10 0 0 80 WILD BUCKWHEAT 70 60 40 40 20 80 80      60 40 30 100 100 90 80 70 70 40 40 30 20 60 60 40 20 0 0 100 KOCHIA 70      40 30 20 0 90 80 60 40 10 70 50 40 0 70 40 30 30 10 0 60 40 20 0 0 0 60      SNTLS MAYWEED 90 80 70 60 40 100 80 70 50 30 100 100 80 60 100 100 100      100 90 90 100 100 90 80 70 70 100 BLACK NIGHTSHAD 60 50 50 40 30 70 60      30 20 0 80 70 60 40 60 50 40 30 30 0 50 50 40 30 10 0 70 FIELD SPEEDWELL      0 0 0 0 0 20 0 0 0 0 10 0 0 0 20 0 0 0 0 0 20 10 0 0 0 0 30 IVYLF      SPEEDWELL 60 30 0 0 0 0 0 0 0 0 70 60 40 0 60 30 10 0 0 0 30 0 0 0 0 0      80 SUGARBEET 100 100 100 100 100 100 100 100 70 70 100 100 100 100 100      100 100 90 90 60 90 80 80 60 40 30 100 LAMBSQUARTER 20 10 0 0 0 80 80 70      70 40 100 100 70 60 70 70 40 40 20 20 70 70 60 20 0 0 70 FIELD PENNYCRES      100 100 100 90 40 100 90 90 60 20 100 80 70 50 100 100 100 100 100 100      100 100 100 100 100 100 100 FIELD VIOLET 60 40 20 0 0 30 20 0 0 0 90 60      20 0 30 10 0 0 0 0 40 10 0 0 0 0 50        CMPD 11  CMPD 12 CMPD 13 CMPD 29 CMPD 31 RATE G/HA 64 32 16 8 4 125 64 3      2 16 8 4 125 64 32 16 8 4 125 64 32 16 8 4 125 64 32 16        PREEMERGENCE SPRING WHEAT 0 0 0 0 0 30 10 0 0 0 0 0 0 0 0 0 0 10 0 0 0 0       0 40 30 10 0 WINTER WHEAT 0 0 0 0 0 0 0 0 0 0 0 10 0 0 0 0 0 20 0 0 0 0      0 40 20 10 0 SPRING BARLEY 0 0 0 0 0 10 0 0 0 0 0 10 10 0 0 0 0 30 10 0      0 0 0 50 40 30 20 WINTER BARLEY 20 10 10 0 0 20 10 0 0 0 0 10 0 0 0 0 0      30 20 10 10 0 0 60 40 30 20 WILD OATS 0 0 0 0 0 20 10 0 0 0 0 0 10 10 0      0 0 40 10 0 0 0 0 50 30 20 0 DOWNY BROME 10 0 0 0 0 10 0 0 0 0 0 0 0 0 0      0 0 30 20 0 0 0 0 60 40 40 20 CHEAT GRASS 20 20 10 0 0 30 10 0 0 0 0 0 0      0 0 0 0 40 20 20 0 0 0 70 70 50 40 BLACKGRASS 70 60 40 30 20 40 30 30 10      0 0 30 0 0 0 0 0 90 90 60 40 10 0 80 80 70 60 ANN. BLUEGRASS 60 50 50 30      20 50 50 30 20 0 0 30 20 0 0 0 0 80 80 60 50 20 10 70 60 50 40 ANNUAL      RYEGRASS 20 10 0 0 0 40 10 0 0 0 0 10 10 0 0 0 0 50 40 20 10 10 0 40 30      30 20 JOINT GOATGRASS 10 10 0 0 0 40 10 0 0 0 0 20 10 0 0 0 0 50 30 10 0      0 0 30 20 20 10 GREEN FOXTAIL 70 50 30 20 0 40 10 0 0 0 0 50 10 0 0 0 0      90 70 50 40 20 0 100 80 50 30 RAPE 100 100 100 90 90             100 100      90 90 90 90 100 100 100 100 CTCHWD BEDSTRAW 70 70 50 50 10 70 60 50 50      30 10 100 60 60 50 50 20 90 80 60 50 30 0 80 80 60 50 WILD BUCKWHEAT 100      100 90 90 40 100 100 100 100 90 60 90 90 90 90 70 60 100 100 100 90 60      30 90 80 80 70 KOCHIA 20 20 0 0 0 80 60 50 30 20 20 70 40 40 30 20 0 50      50 50 40 10 0 70 50 40 20 SNTLS MAYWEED 100 90 70 40 10 100 90 90 70 70      40 90 90 70 30 20 0 100 90 60 50 30 10 100 100 90 90 BLACK NIGHTSHAD 60      50 40 40 20 80 80 70 70 60 50 90 70 70 -- 30 20 60 50 50 40 20 0 70 70      50 40 FIELD SPEEDWELL 70 70 50 40 30 90 90 80 80 40 30 40 40 30 30 10 0      90 90 70 60 40 20 90 90 80 70 IVYLF SPEEDWELL 70 50 40 20 0 80 80 70 40      20 10 100 60 30 0 0 0 100 90 90 70 40 20 100 80 80 50 SUGARBEET 100 90      90 90 90 100 100 100 100 100 90 100 100 100 100 90 90 100 100 100 100 90      90 100 90 90 80 LAMBSQUARTER 90 80 70 70 50 100 90 90 80 80 60 90 90 90      90 70 60 100 90 90 60 30 10 100 90 80 80 FIELD PENNYCRES 100 100 90 80      60 100 100 90 80 30 20 90 80 80 70 70 40 100 80 70 50 20 0 90 90 80 80      FIELD VIOLET 50 40 40 30 10 100 90 90 80 50 40 90 90 70 60 50 40 100 100      90 90 80 60 100 100 80 60 ALTEX RAPE      100 100 90 80 80 50 100 100 90      90 80 70 POSTEMERGENCE SPRING WHEAT 10 0 0 0 0 10 0 0 0 0 0 0 0 0 0 0 0      0 0 0 0 0 0 0 0 0 0 WINTER WHEAT 10 10 0 0 0 20 10 0 0 0 0 0 0 0 0 0 0      10 0 0 0 0 0 10 0 0 0 SPRING BARLEY 10 0 0 0 0 10 0 0 0 0 0 0 0 0 0 0 0      10 0 0 0 0 0 10 0 0 0 WINTER BARLEY 10 10 0 0 0 10 0 0 0 0 0 0 0 0 0 0 0      10 10 0 0 0 0 20 10 0 0 WILD OATS 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0      0 0 0 0 20 0 0 0 WILD OATS STG 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0      0 0 0 20 10 0 0 DOWNY BROME 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 40 0 0 0 0      0 0 0 0 0 CHEAT GRASS 0 0 0 0 0 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 30      30 20 0 BLACKGRASS 0 0 0 0 0 20 10 0 0 0 0 0 0 0 0 0 0 50 40 20 10 0 0      80 80 70 50 BLACKGRASS STG2 20 20 0 0 0 30 10 0 0 0 0 0 0 0 0 0 0 70 50      40 30 20 0 80 70 70 40 ANN. BLUEGRASS 20 10 0 0 0 30 10 0 0 0 0 0 0 0 0      0 0 30 10 0 0 0 0 10 10 0 0 ANNUAL RYEGRASS 0 0 0 0 0 20 0 0 0 0 0 0 0 0      0 0 0 0 0 0 0 0 0 10 0 0 0 JOINT GOATGRASS 10 0 0 0 0 30 10 0 0 0 0 20 0      0 0 0 0 20 10 0 0 0 0 30 10 0 0 GREEN FOXTAIL 20 0 0 0 40 20 20 0 0 0 20      0 0 0 0 0 0 50 50 40 30 20 0 60 60 30 20 RAPE 100 100 100 100 100      100 100 100 100 100 80 100 100 100 100 100 100 100 100 100 100 CTCHWD      BEDSTRAW 50 50 40 40 20 90 80 80 50 50 40 90 90 70 60 50 30 70 50 50 30      10 0 80 60 40 40 WILD BUCKWHEAT 100 70 50 30 10 90 90 90 80 80 70 70 70      50 40 20 0 100 100 80 60 50 40 100 100 90 80 KOCHIA 50 30 10 0 0 70 70      60 40 20 10 80 50 40 20 0 0 100 100 90 90 80 50 70 40 30 10 SNTLS      MAYWEED 80 70 50 40 20 90 70 60 40 20 0 100 100 80 70 40 30 100 100 100      90 90 70 100 100 80 60 BLACK NIGHTSHAD 70 60 50 50 40 70 70 50 40 20 20      80 60 50 50 40 30 70 40 40 30 30 10 50 30 20 20 FIELD SPEEDWELL 30 30 20      10 0 50 50 20 20 10 0 20 0 0 0 0 0 50 50 30 20 0 0 20 10 0 0 IVYLF      SPEEDWELL 70 20 10 0 0 60 20 0 0 0 0 0 0 0 0 0 0 60 60 50 30 10 0 0 0 0      0 SUGARBEET 100 100 80 60 60 100 100 100 100 100 90 100 100 100 100 100      90 100 100 100 100 100 100 100 90 70 60 LAMBSQUARTER 70 70 50 20 20 70      70 60 60 30 10 90 90 90 90 30 0 80 70 70 60 40 10 40 30 10 0 FIELD      PENNYCRES 100 100 90 100 40 100 100 100 100 100 80 100 100 100 100 80 60      100 100 80 70 60 50 100 100 100 80 FIELD VIOLET 30 10 0 0 0 50 50 50 40      10 10 10 0 0 0 0 0 90 90 70 50 30 0 30 0 0 0 ALTEX RAPE      100 100 100      100 100 90        CMPD      31 CMPD 35 CMPD 36 CMPD 55 CMPD 56 CMPD 61 RATE G/HA 8 125      64 32 16 8 4 125 64 32 16 8 125 64 32 16 8 4 125 64 32 32 16 8 4      2         PREEMERGENCE SPRING WHEAT 0 10 0 0 0 0 10 0 0 0 0 0 0 -- 0 0 0 0       60 40 20 20 10 0 0 0 WINTER WHEAT 0 0 0 0 0 0 0 20 10 0 0 0 0 0 0 0 0 0      50 30 20 40 30 10 0 0 SPRING BARLEY 10 30 10 0 0 0 0 10 10 0 0 0 10 10 0      0 0 0 20 10 0 40 30 10 0 0 WINTER BARLEY 10 40 20 20 10 0 0 30 20 10 10      0 30 20 10 0 0 0 40 20 0 20 10 0 0 0 WILD OATS 0 20 10 0 0 0 0 30 10 0 0      0 30 10 0 0 0 0 20 20 0 0 0 0 0 0 DOWNY BROME 0 20 10 10 0 0 0 20 0 0 0      0 30 10 0 0 0 0 80 70 40 30 10 0 0 0 CHEAT GRASS 20 40 40 30 20 0 0 20      20 10 0 0 40 40 20 10 0 0 80 80 50 80 60 60 40 20 BLACKGRASS 40 80 70 40      20 0 0 40 40 30 30 20 60 60 60 40 20 10 70 70 50 20 20 20 10 0 ANN.      BLUEGRASS 20 60 60 50 50 40 30 50 50 40 40 20 60 60 50 30 0 0 70 60 40      30 20 20 10 0 ANNUAL RYEGRASS 10 40 40 30 20 20 0 40 20 10 0 0 60 50 50      30 0 0 20 0 0 30 30 20 0 0 JOINT GOATGRASS 0 30 30 10 0 0 0 20 20 0 0 0      10 0 0 0 0 0 10 0 0 30 30 20 0 0 GREEN FOXTAIL 20 50 50 30 10 0 0 30 20      10 0 0 60 70 30 20 0 0 60 50 30 70 40 20 0 0 RAPE 90 100 100 100 100 100      90 100 100 100 100 100 100 100 100 100 70 70 100 100 90 100 100 100 100      90 CTCHWD BEDSTRAW 30 80 80 70 70 50 50 90 80 80 60 50 80 60 60 50 40 10      60 50 40 100 80 60 50 40 WILD BUCKWHEAT 40 100 90 90 70 50 30 90 90 90      80 70 100 100 90 70 70 40 80 80 40 80 80 70 60 60 KOCHIA 0 80 80 50 40      20 0 70 70 50 30 20 90 80 70 50 30 10 60 30 20 70 50 30 0 0 SNTLS      MAYWEED 80 100 100 80 70 50 30 100 100 90 90 70 100 90 70 70 60 20 80 70      70 100 100 100 90 80 BLACK NIGHTSHAD 20 70 60 50 40 20 0 80 80 70 50 50      70 70 50 50 0 0 100 100 100 70 60 50 50 30 FIELD SPEEDWELL 50 100 90 90      90 80 70 70 70 60 60 50 80 80 80 70 50 30 70 40 30 70 60 50 0 0 IVYLF      SPEEDWELL 30 100 100 100 100 100 90 100 100 80 60 40 100 90 80 80 60 40      70 60 20 70 50 30 50 40 SUGARBEET 70 100 100 100 100 100 100 100 100 100      100 90 100 100 100 100 90 80 100 90 90 100 90 90 0 0 LAMBSQUARTER 60 100      90 80 80 60 50 90 80 80 60 50 90 90 90 80 70 60 90 70 70 90 90 80 90 90      FIELD PENNYCRES 60 100 90 90 90 80 70 100 100 90 80 60 100 90 80 60 10 0      90 90 80 100 90 80 80 70 FIELD VIOLET 30 100 100 80 70 50 20 100 100 90      70 50 100 100 90 70 60 20 20 0 0 80 60 60 70 60 RUSSIAN THISTLE               100 100 100 60 30 20 50 40 POSTEMERGENCE SPRING WHEAT 0 10 0 0      0 0 0 0 0 0 0 0 0 0 0 0 0 0 30 10 10 0 0 0 0 0 WINTER WHEAT 0 20 10 0 0      0 0 0 0 0 0 0 0 0 0 0 0 0 30 10 10 10 10 0 0 0 SPRING BARLEY 0 20 10 0 0      0 0 0 0 0 0 0 10 0 0 0 0 0 10 10 10 0 0 0 0 0 WINTER BARLEY 0 10 0 0 0 0      0 0 0 0 0 0 0 0 0 0 0 0 20 10 10 20 20 10 0 0 WILD OATS 0 0 0 0 0 0 0 0      0 0 0 0 0 0 0 0 0 0 30 10 20 0 0 0 0 0 WILD OATS STG 2 0 0 0 0 0 0 0 20      0 0 0 0 10 0 0 0 0 0 40 10 10 0 0 0 0 0 DOWNY BROME 0 0 0 0 0 0 0 0 0 0      0 0 0 0 0 0 0 0 60 60 20 10 0 0 0 0 CHEAT GRASS 0 0 0 0 0 0 0 0 0 0 0 0      0 0 0 0 0 0 90 70 40 30 10 0 0 0 BLACKGRASS 30 70 60 40 20 0 0 30 20 0 0      0 100 60 60 30 10 0 90 70 60 0 0 0 0 0 BLACKGRASS STG2 20 70 50 50 30 10      0 30 20 10 0 0 90 70 40 10 -- 0 90 60 30 30 30 0 0 0 ANN. BLUEGRASS 0 20      10 10 0 0 0 10 0 0 0 0 20 20 20 0 0 0 50 0 20 0 0 0 0 0 ANNUAL RYEGRASS      0 20 20 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 20 0 0 0 0 0 0 0 JOINT GOATGRASS      0 20 10 0 0 0 0 0 0 0 0 0 10 0 0 0 0 0 70 30 10 0 0 0 0 0 GREEN FOXTAIL      0 20 0 0 0 0 0 0 0 0 0 0 20 10 0 0 0 0 20 0 0 20 20 10 0 0 RAPE 80 100      100 100 100 100 90 100 100 100 100 80 100 100 100 100 100 100 100 100      100 100 100 100 100 90 CTCWD BEDSTRAW 20 90 80 70 50 30 10 70 60 40 20 0      60 60 60 40 40 10 80 40 20 80 80 50 10 0 WILD BUCKWHEAT 60 100 100 80 60      30 20 100 100 90 70 50 100 90 90 90 70 60 60 40 20 60 60 30 0 0 KOCHIA 0      70 70 50 30 10 0 50 40 30 10 0 100 100 80 80 70 50 90 40 20 70 60 60 50      30 SNTLS MAYWEED 40 100 100 90 80 70 50 100 90 80 70 40 100 100 100 80      80 60 90 90 60 100 100 100 100 70 BLACK NIGHTSHAD 10 40 30 10 0 0 0 70      40 20 10 0 70 70 50 10 0 0 0 0 0 30 10 0 0 0 FIELD SPEEDWELL 0 70 50 40      20 0 0 0 0 0 0 0 100 100 100 100 60 40 50 40 10 30 30 30 0 0 IVYLF      SPEEDWELL 0 50 30 20 0 0 0 0 0 0 0 0 100 100 100 60 40 0 60 30 10 30 30      20 0 0 SUGARBEET 40 100 100 100 100 90 70 100 100 90 90 60 100 100 100      100 100 100 100 100 100 100 100 100 100 90 LAMBSQUARTER 0 70 40 30 10 0      0 20 0 0 0 0 100 100 80 60 40 20 60 50 60 20 10 0 0 0 FIELD PENNYCRES 60      100 100 100 80 60 50 100 100 90 90 70 90 90 80 60 40 30 100 100 90 100      100 100 100 100 FIELD VIOLET 0 60 50 40 20 0 0 10 0 0 0 0 100 100 90 90      50 30 0 0 0 20 20 10 0 0 RUSSIAN THISTLE             -- 100 100 -- 100      100 100 100 100        CMPD 62 CMPD 64 CMPD 65 CMPD 66 RATE G/HA 8 4 2 1 125 64 32 16 8 4 2 1 1      25 64 32 16 8 4 2 1 125 64 32 16 8 4 2        PREEMERGENCE SPRING WHEAT 10 0 0 0 50 30 10 0 0 0 0 0 10 0 0 0 0 0 0 0 1      0 10 0 0 0 0 0 WINTER WHEAT 20 10 0 0 40 20 20 10 0 0 0 0 20 10 0 0 0 0      0 0 0 0 0 0 0 0 0 SPRING BARLEY 40 40 30 0 60 60 50 20 0 0 0 0 70 50 30      20 0 0 0 0 30 0 0 0 0 0 0 WINTER BARLEY 10 0 0 0 70 60 60 50 30 0 0 0 70      50 30 30 0 0 0 0 30 20 20 10 10 0 0 WILD OATS 0 0 0 0 30 20 10 0 0 0 0 0      20 20 10 0 0 0 0 0 20 20 10 10 10 10 10 DOWNY BROME 0 0 0 0 30 10 10 0 0      0 0 0 50 20 10 0 0 0 0 0 40 10 0 0 0 0 0 CHEAT GRASS 30 10 0 0 80 60 50      30 10 0 0 0 60 40 30 0 0 0 0 0 20 10 0 0 0 0 0 BLACKGRASS 10 10 0 0 50      30 10 0 0 0 0 0 90 90 80 80 40 40 0 0 50 40 30 30 30 20 20 ANN. BLUEGRASS       30 10 0 0 70 60 30 30 10 0 0 0 60 60 50 40 40 20 10 0 40 40 30 30 20 10      10 ANNUAL RYEGRASS 30 10 0 0 70 40 40 30 10 10 0 0 60 50 50 40 40 20 10      0 30 20 20 10 10 10 0 JOINT GOATGRASS 20 10 0 0 40 30 30 0 0 0 0 0 50 40      30 30 20 10 0 0 10 10 0 0 0 0 0 GREEN FOXTAIL 40 10 0 0 100 80 60 40 30      0 0 0 90 80 80 40 30 10 0 0 60 50 30 20 20 10 0 RAPE 100 100 100 90 100      100 100 100 100 100 100 90 100 100 100 90 90 80 80 80 100 100 100 100 70      70 60 CTCHWD BEDSTRAW 20 20 0 0 100 100 100 90 70 60 40 40 100 100 90 80      80 60 60 60 90 90 90 90 70 50 40 WILD BUCKWHEAT 70 70 60 40 100 90 90 80      70 70 60 50 100 90 90 90 80 70 70 60 90 90 90 80 60 50 30 KOCHIA 60 20      10 0 90 80 80 70 70 60 40 20 90 80 80 60 60 70 70 60 90 90 90 80 60 50      30 SNTLS MAYWEED 100 90 80 70 100 100 90 90 90 80 70 60 100 100 100 90      90 70 70 60 90 90 90 80 80 70 70 BLACK NIGHTSHAD 70 40 30 10 80 80 70 60      60 50 30 20 80 80 70 70 60 50 20 10 70 50 40 30 30 30 30 RUSSIAN THISTLE      80 80 50 40 100 90 80 50 50 20 0 0 90 90 90 70 70 60 60 40 10 0 0 0 0 0      0 FIELD SPEEDWELL 70 60 30 20 100 90 80 70 70 60 40 10 100 90 80 80 80      70 60 30 60 60 50 50 50 40 40 IVYLF SPEEDWELL 70 30 10 0 100 90 90 80 60      60 30 10 100 90 90 70 70 50 40 30 90 70 70 70 70 70 0 SUGARBEET 100 100      70 70 100 100 100 100 100 90 90 80 100 100 100 100 100 100 80 80 100 100      100 90 90 90 70 LAMBSQUARTER 90 90 80 70 100 100 100 80 80 70 70 30 100      100 90 90 80 60 60 40 100 90 90 40 40 30 20 FIELD PENNYCRES 100 90 60 60      100 100 100 90 80 80 70 30 100 100 100 90 90 90 40 30 80 80 80 70 60 40      30 FIELD VIOLET 50 40 20 20 90 80 70 70 60 40 20 0 100 100 100 100 100      90 70 40 100 100 90 90 60 60 30 POSTEMERGENCE SPRING WHEAT 40 30 10 0 0      0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10 0 0 0 0 0 0 WINTER WHEAT 30 10 0 0 20      10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 SPRING BARLEY 40 20 0 0 10      10 0 0 0 0 0 0 10 10 0 0 0 0 0 0 30 20 10 10 10 10 10 WINTER BARLEY 30      10 0 0 0 0 0 0 0 0 0 0 20 10 0 0 0 0 0 0 10 10 10 10 0 0 0 WILD OATS 0 0      0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 WILD OATS STG 2 20 10      0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10 10 0 0 0 0 0 DOWNY BROME 0 0 0 0      10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CHEAT GRASS 50 40 0 0 30      20 0 0 0 0 0 0 20 10 0 0 0 0 0 0 10 10 0 0 0 0 0 BLACKGRASS 0 0 0 0 20      10 0 0 0 0 0 0 40 20 0 0 0 0 0 0 30 30 10 10 10 10 10 BLACKGRASS STG2 40      10 0 0 20 0 0 0 0 0 0 0 80 60 60 50 10 0 0 0 20 20 10 0 0 0 0 ANN.      BLUEGRASS 30 20 0 0 20 10 0 0 0 0 0 0 40 30 10 0 0 0 0 0 10 10 10 10 0 0      0 ANNUAL RYEGRASS 10 0 0 0 0 0 0 0 0 0 0 0 20 20 20 0 0 0 0 0 10 10 0 0      0 0 0 JOINT GOATGRASS 20 20 0 0 40 10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 20 20      10 0 0 0 0 GREEN FOXTAIL 20 20 0 0 30 30 10 0 0 0 0 0 40 30 0 0 0 0 0 0      40 30 10 0 0 0 0 RAPE 100 100 100 90 100 100 100 100 90 90 90 70 100 100      100 100 100 100 90 50 100 100 100 90 90 70 50 CTCWD BEDSTRAW 50 30 0 0      100 100 70 70 50 20 0 0 90 90 80 80 30 10 0 0 100 100 100 60 50 30 10      WILD BUCKWHEAT 60 30 20 0 100 100 70 60 40 40 20 0 90 80 80 70 30 10 0 0      90 80 80 60 50 50 10 KOCHIA 70 40 40 10 80 80 60 60 50 40 30 20 100 100      90 70 60 60 40 0 60 60 40 40 40 20 0 SNTLS MAYWEED 80 80 60 60 100 100      100 70 50 30 20 0 100 100 100 100 90 90 60 20 90 90 80 80 70 60 50 BLACK      NIGHTSHAD 60 20 10 0 40 30 20 20 10 0 0 0 80 40 40 40 10 0 0 0 80 50 50      20 10 10 10 FIELD SPEEDWELL 20 0 0 0 20 20 0 0 0 0 0 0 80 60 50 30 10 0      0 0 0 0 0 0 0 0 0 IVYLF SPEEDWELL 30 10 0 0 100 80 40 20 0 0 0 0 80 50      50 30 0 0 0 0 70 60 60 50 40 40 20 SUGARBEET 100 100 90 90 100 100 100      100 100 100 90 70 100 100 100 100 100 90 90 70 100 100 100 100 90 90 60      LAMBSQUARTER 20 10 0 0 70 40 20 20 0 0 0 0 50 30 20 10 0 0 0 0 60 40 40      0 0 0 0 FIELD PENNYCRES 100 100 90 50 100 100 100 100 100 100 100 20 100      100 100 100 100 100 80 20 90 90 90 80 80 20 20 FIELD VIOLET 60 10 0 0 30      10 0 0 0 0 0 0 80 50 50 40 20 0 0 0 80 40 0 0 0 0 0 RUSSIAN THISTLE                     50 50 50 50 50 30 0 

What is claimed is:
 1. A compound having the formula ##STR42## wherein J is selected from ##STR43## E is a single bond or --CH₂ --; Q¹ is --C(T¹)═N--O--Alk;T¹ is selected from CN, F, Cl, Br, SCN, N₃, C₁ to C₂ alkoxy, C₁ to C₂ thioalkyl, NH(C₁ to C₂ alkyl), N(C₁ to C₂ alkyl)₂, N(OCH₃)CH₃ and N(CH₂)₃ or 4 ; Alk is selected from C₁ to C₃ alkyl, optionally substituted with CN, OCH₃ SCH₃ or halogen; and CH₂ CH═CH₂ ; Q² is --C(T²)═N--O--Alk; T² is selected from H; C₁ to C₃ alkyl optionally substituted with CN, OCH₃, SCH₃ or halogen; cyclopropyl; F; Cl, Br; CN; SCN; N₃ ; C₁ to C₂ alkoxy; C₁ to C₂ thioalkyl; NH(C₁ to C₂ alkyl); N(C₁ to C₂ alkyl)₂ ; N(OCH₃)CH₃ and N(CH₂)₃ or 4 ; R¹ is selected from H, C₁ to C₃ alkyl, C₁ to C₃ haloalkyl, halogen, CN, nitro, C₁ to C₃ alkoxy, C₁ to C₃ haloalkoxy, C₁ to C₃ alkylthio, C₁ to C₃ alkylsulfinyl, C₁ to C₃ alkylsulfonyl, SCF₂ H, NH₂, NHCH₃, N(CH₃)₂ or C₁ to C₂ alkyl substituted with one C₁ to C₂ alkoxy, C₁ to C₂ haloalkoxy, SH, SCH₃, CN or OH; R² is selected from H, F, Cl, Br, C₁ to C₂ alkyl, C₁ to C₂ haloalkyl or C₁ to C₂ alkoxy; R³ is selected from H, C₁ to C₃ alkyl, C₁ to C₂ haloalkyl, C₃ to C₄ alkenyl, C₃ to C₄ alkynyl, CH₂ CN, phenyl and phenyl substituted by F, Cl, CH₃ or OCH₃ ; n is 0 or 1; R is H or CH₃ ; W is O or S; A is selected from ##STR44## X is selected from H, C₁ to C₄ alkyl, C₁ to C₄ alkoxy, C₁ to C₄ haloalkoxy, C₁ to C₄ haloalkyl, C₁ to C₄ haloalkylthio, C₁ to C₄ alkylthio, halogen, C₂ to C₅ alkoxyalkyl, C₂ to C₅ alkoxyalkoxy, amino, C₁ to C₃ alkylamino, di(C₁ to C₃ alkyl)amino or C₃ to C₅ cycloalkyl; Y is selected from H, C₁ to C₄ alkyl, C₁ to C₄ alkoxy, C₁ to C₄ haloalkoxy, C₁ to C₄ haloalkylthio, C₁ to C₄ alkylthio, C₂ to C₅ alkoxyalkyl, C₂ to C₅ alkoxyalkoxy, amino, C₁ to C₃ alkylamino, di(C₁ to C₃ alkyl)amino, C₃ to C₄ alkenyloxy, C₃ to C₄ alkynyloxy, C₂ to C₅ alkylthioalkyl, C₁ to C₄ haloalkyl, C₂ to C₄ alkynyl, azido, cyano, C₂ to C₅ alkylsulfinylalkyl, C₂ to C₅ alkylsulfonylalkyl, ##STR45## and N(OCH₃)CH₃ ; m is 2 or 3; L₁ and L₂ are independently O or S; R_(a) is H or C₁ to C₃ alkyl; R_(b) and R_(c) are independently C₁ to C₃ alkyl; and Z is CH provided that(i) when X is Cl, F, Br or I, then Y is OCH₃, OC₂ H₅, N(OCH₃)CH₃, NHCH₃, N(CH₃)₂ or OCF₂ H; (ii) when W is S, then R is H and Y is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, C₂ H₅, CF₃, SCH₃, OCH₂ CH.tbd.CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH(OCH₃)₂ or 1,3-dioxolan-2-yl; (iii) when the total number of carbons of X and Y is greater than four, the number of carbon atoms of Q¹ or Q² is less than or equal to four; and (iv) when J is J-6, J-7, J-8 or J-9, and X and Y are haloalkoxy or haloalkylthio, then T₂ is F, Cl, Br, CN, SCN, N₃, C₁ to C₂ alkoxy, C₁ to C₂ thioalkyl, NH(C₁ to C₂ alkyl), N(C₁ to C₂ alkyl)₂, N(OCH₃)CH₃ or N(CH₂)₃ or
 4. 2. A compound according to claim 1 wherein:E is a single bond; and W is O.
 3. A compound according to claim 1 wherein:E is CH₂ or J is J-6; and W is O.
 4. A compound according to claim 3, wherein:R¹ is selected from H, F, Cl, Br, CH₂ CN, CH₃, OCH₃, SCH₃ and OCF₂ H; R² is selected from H, F, Cl, Br or CH₃ ; R³ is selected from H, C₁ to C₃ alkyl, phenyl, CH₂ CF₃ and CH₂ CH═CH₂ ; X is selected from C₁ to C₂ alkyl, C₁ to C₂ alkoxy, cyclopropyl, Cl, F, Br, I, OCF₂ H, CH₂ F, CF₃, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃, CH₂ Cl and CH₂ Br; Y is selected from H, C₁ to C₂ alkyl, C₁ to C₂ alkoxy, CH₂ OCH₃, CH₂ OCH₂ CH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C═CH, OCH₂ CH₂ OCH₃, CH₂ SCH₃, ##STR46## OCF₂ H, OCF₂ Br, SCF₂ H, C.tbd.CH and C.tbd.CCH₃ ; and R_(b) and R_(c) are C₁ to C₂ alkyl.
 5. A compound according to claim 4 wherein:A is A-1; n is 0; X is selected from cyclopropyl, CH₃, OCH₃, OCH₂ CH₃, Cl and OCF₂ H; and Y is selected from CH₃, OCH₃, C₂ H₅, CH₂ OCH₃, NHCH₃ and CH(OCH₃)₂.
 6. A compound according to claim 5 wherein:R is H; T¹ is selected from CN, Cl and C₁ to C₂ alkoxy; and T² is selected from H, C₁ to C₃ alkyl, cyclopropyl, Cl, CN and C₁ to C₂ alkoxy.
 7. A compound according to claim 6 wherein J is J-1 to J-5 and J-7 to J-13.
 8. A compound according to claim 7 wherein J is J-1.
 9. A compound according to claim 7 wherein J is J-2.
 10. A compound according to claim 7 wherein J is J-3.
 11. A compound according to claim 7 wherein J is J-4.
 12. A compound according to claim 7 wherein J is J-5.
 13. A compound according to claim 7 wherein J is J-7.
 14. A compound according to claim 7 wherein J is J-8.
 15. A compound according to claim 7 wherein J is J-9.
 16. A compound according to claim 7 wherein J is J-10.
 17. A compound according to claim 7 wherein J is J-11.
 18. A compound according to claim 7 wherein J is J-12.
 19. A compound according to claim 7 wherein J is J-13.
 20. A compound according to claim 8: 2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-N-methoxybenzenecarboximidoyl chloride.
 21. A compound according to claim 8: 2-[(cyano)(methoxyimino)methyl]-N-[[(4-methoxy-6-methyl-2-pyrimidinyl)amino]carbonyl]benzenesulfonamide.
 22. A herbicidal composition comprising a compound according to any one of claims 1 to 21 and an agriculturally suitable carrier therefor.
 23. A method for controlling weeds comprising applying to the locus of the weed, preemergence or postemergence, a herbicidally effective amount of a compound according to any one of claims 1 to
 21. 